公开(公告)号：US09362542B2

公开(公告)日：2016-06-07

申请号：US14492365

申请日：2014-09-22

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC

Inventor： Ion C. Halalay ,  Timothy J. Fuller ,  Zicheng Li

IPC: H01M2/16 ,  H01M4/62 ,  H01M2/14 ,  H01M10/0525 ,  H01M10/0585 ,  H01M10/42

CPC classification number: H01M2/1686 ,  H01M2/145 ,  H01M2/1653 ,  H01M4/628 ,  H01M10/0525 ,  H01M10/0585 ,  H01M10/4235 ,  Y02E60/122

Abstract: One example of a lithium ion battery component is a lithium ion battery separator including a planar microporous polymer membrane and a chelating agent bonded to the planar microporous polymer membrane through a linking group. The chelating agent is bonded such that the permanent dipole moment of the chelating agent is oriented perpendicular to the plane of the planar microporous polymer membrane.

Abstract translation: 锂离子电池组件的一个实例是包括平面微孔聚合物膜和通过连接基团结合到平面微孔聚合物膜的螯合剂的锂离子电池隔板。 键合螯合剂使得螯合剂的永久偶极矩垂直于平面微孔聚合物膜的平面取向。

公开(公告)号：US10581119B2

公开(公告)日：2020-03-03

申请号：US15644422

申请日：2017-07-07

Applicant: GM Global Technology Operations LLC

Inventor： Ion C. Halalay ,  Zicheng Li ,  Timothy J. Fuller ,  Bob R. Powell, Jr.

IPC: H01M10/42 ,  H01M10/0567 ,  H01M10/052 ,  H01M4/13 ,  B01J39/04 ,  B01J39/18 ,  C08J5/22 ,  H01M10/0525 ,  H01M10/0568 ,  H01M4/587 ,  H01M2/16 ,  H01M4/36 ,  H01M4/62

Abstract: Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing dendrite formation are provided. The electrochemical cells include a positive electrode, a negative electrode, and a separator disposed therebetween. At least one transition metal ion-trapping moiety, including one or more polymers functionalized with one or more trapping groups, may be included within the electrochemical cell as a coating, pore filler, substitute pendant group, or binder. The one or more trapping groups may be selected from the group consisting of: crown ethers, siderophores, bactins, ortho-phenanthroline, iminodiacetic acid dilithium salt, oxalates malonates, fumarates, succinates, itaconates, phosphonates, and combinations thereof, and may bind to metal ions found within the electrochemical cell to minimize or suppress formation of dendrite protrusions on the negative electrode.

公开(公告)号：US20140242452A1

公开(公告)日：2014-08-28

申请号：US13778968

申请日：2013-02-27

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC

Inventor： Nicholas P. W. Pieczonka ,  Junghyun Kim ,  Zicheng Li ,  Timothy J. Fuller ,  Nicholas P. Irish ,  Bob R. Powell, JR. ,  Ion C. Halalay

IPC: H01M4/62

CPC classification number: H01M4/622 ,  C08L33/02 ,  H01M4/131 ,  H01M4/136 ,  H01M10/052

Abstract: A lithium-ion cell has a positive electrode comprising at least one active material comprising a lithium transition metal compound in a binder comprising at least one binder material with functional groups selected from alkali and alkaline earth salts of acid groups and hydroxyl groups, amine groups, isocyanate groups, urethane groups, urea groups, amide groups, and combinations of these; a negative electrode comprising metallic lithium or a lithium host material with appropriately low operation voltage vs. metallic lithium; a nonaqueous solution of a lithium salt; and an electrically nonconductive, ion-pervious separator positioned between the electrodes.

Abstract translation: 锂离子电池具有包括至少一种包含锂过渡金属化合物的活性材料的正极，所述活性材料在包含至少一种选自酸基和羟基的碱金属和碱土金属盐的官能团的至少一种粘合剂材料的粘合剂中，胺基， 异氰酸酯基，氨基甲酸酯基，脲基，酰胺基和它们的组合; 负极包含金属锂或具有合适的低操作电压的金属锂的锂主体材料; 锂盐的非水溶液; 以及位于电极之间的非导电的，离子可透过的分离器。

公开(公告)号：US20190013551A1

公开(公告)日：2019-01-10

申请号：US15644422

申请日：2017-07-07

Applicant: GM Global Technology Operations LLC

Inventor： Ion C. Halalay ,  Zicheng Li ,  Timothy J. Fuller ,  Bob R. Powell, JR.

IPC: H01M10/42 ,  B01J39/04 ,  B01J39/18 ,  C08J5/22 ,  H01M10/0525 ,  H01M10/0568 ,  H01M4/587

CPC classification number: H01M10/4235 ,  B01J39/04 ,  B01J39/18 ,  C08J5/2206 ,  C08J2300/00 ,  H01M2/1646 ,  H01M2/1653 ,  H01M2/166 ,  H01M2/1686 ,  H01M4/13 ,  H01M4/366 ,  H01M4/587 ,  H01M4/622 ,  H01M4/628 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M2220/20

Abstract: Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing dendrite formation are provided. The electrochemical cells include a positive electrode, a negative electrode, and a separator disposed therebetween. At least one transition metal ion-trapping moiety, including one or more polymers functionalized with one or more trapping groups, may be included within the electrochemical cell as a coating, pore filler, substitute pendant group, or binder. The one or more trapping groups may be selected from the group consisting of: crown ethers, siderophores, bactins, ortho-phenanthroline, iminodiacetic acid dilithium salt, oxalates malonates, fumarates, succinates, itaconates, phosphonates, and combinations thereof, and may bind to metal ions found within the electrochemical cell to minimize or suppress formation of dendrite protrusions on the negative electrode.

公开(公告)号：US09799916B2

公开(公告)日：2017-10-24

申请号：US14492303

申请日：2014-09-22

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC

Inventor： Ion C. Halalay ,  Timothy J. Fuller ,  Zicheng Li

IPC: H01M10/052 ,  H01M10/0525 ,  H01M4/131 ,  H01M4/136 ,  H01M4/62

CPC classification number: H01M10/0525 ,  H01M4/131 ,  H01M4/136 ,  H01M4/622 ,  H01M4/625

Abstract: A lithium ion battery includes a positive electrode and a negative electrode. In an example, a positive electrode for the lithium ion battery includes a lithium transition metal oxide-based active material and a high surface area carbon. The positive electrode further includes a reactive binder having a macrocycle bonded thereto.

公开(公告)号：US20170155175A1

公开(公告)日：2017-06-01

申请号：US14956038

申请日：2015-12-01

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC

Inventor： Ion C. Halalay ,  Timothy J. Fuller ,  Zicheng Li ,  Mark W. Verbrugge

IPC: H01M10/42 ,  H01M4/62 ,  H01M2/16 ,  H01M10/0525

CPC classification number: H01M10/4235 ,  H01M2/1653 ,  H01M2/1686 ,  H01M4/622 ,  H01M10/0525 ,  H01M10/0567

Abstract: A lithium ion battery is provided that includes: a positive electrode; a negative electrode; a microporous polymer separator soaked in an electrolyte solution, the microporous polymer separator disposed between the positive electrode and the negative electrode; and a transition metal cation trap which is i) incorporated as a binder in any of the positive electrode or the negative electrode, ii) deposited onto a surface of any of the positive electrode or the negative electrode, iii) incorporated into the microporous polymer separator, iv) deposited onto a surface of the microporous polymer separator, or v) included as an additive in the electrolyte solution. The transition metal cation trap is a siderophore.

公开(公告)号：US10243241B2

公开(公告)日：2019-03-26

申请号：US14956038

申请日：2015-12-01

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC

Inventor： Ion C. Halalay ,  Timothy J. Fuller ,  Zicheng Li ,  Mark W. Verbrugge

IPC: H01M2/16 ,  H01M4/62 ,  H01M10/42 ,  H01M10/0525 ,  H01M10/0567

Abstract: A lithium ion battery is provided that includes: a positive electrode; a negative electrode; a microporous polymer separator soaked in an electrolyte solution, the microporous polymer separator disposed between the positive electrode and the negative electrode; and a transition metal cation trap which is i) incorporated as a binder in any of the positive electrode or the negative electrode, ii) deposited onto a surface of any of the positive electrode or the negative electrode, iii) incorporated into the microporous polymer separator, iv) deposited onto a surface of the microporous polymer separator, or v) included as an additive in the electrolyte solution. The transition metal cation trap is a siderophore.

公开(公告)号：US20150093639A1

公开(公告)日：2015-04-02

申请号：US14492303

申请日：2014-09-22

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC

Inventor： Ion C. Halalay ,  Timothy J. Fuller ,  Zicheng Li

IPC: H01M4/62 ,  H01M4/485 ,  H01M10/0525 ,  H01M4/131

CPC classification number: H01M10/0525 ,  H01M4/131 ,  H01M4/136 ,  H01M4/622 ,  H01M4/625

Abstract: A lithium ion battery includes a positive electrode and a negative electrode. In an example, a positive electrode for the lithium ion battery includes a lithium transition metal oxide-based active material and a high surface area carbon. The positive electrode further includes a reactive binder having a macrocycle bonded thereto.

Abstract translation: 锂离子电池包括正极和负极。 在一个实例中，用于锂离子电池的正电极包括锂过渡金属氧化物基活性材料和高表面积碳。 正极还包括具有与其结合的大环的反应性粘合剂。

公开(公告)号：US20150093628A1

公开(公告)日：2015-04-02

申请号：US14492365

申请日：2014-09-22

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC

Inventor： Ion C. Halalay ,  Timothy J. Fuller ,  Zicheng Li

IPC: H01M2/16 ,  H01M2/14 ,  H01M4/62

CPC classification number: H01M2/1686 ,  H01M2/145 ,  H01M2/1653 ,  H01M4/628 ,  H01M10/0525 ,  H01M10/0585 ,  H01M10/4235 ,  Y02E60/122

Abstract: One example of a lithium ion battery component is a lithium ion battery separator including a planar microporous polymer membrane and a chelating agent bonded to the planar microporous polymer membrane through a linking group. The chelating agent is bonded such that the permanent dipole moment of the chelating agent is oriented perpendicular to the plane of the planar microporous polymer membrane.

Abstract translation: 锂离子电池组件的一个实例是包括平面微孔聚合物膜和通过连接基团结合到平面微孔聚合物膜的螯合剂的锂离子电池隔板。 键合螯合剂使得螯合剂的永久偶极矩垂直于平面微孔聚合物膜的平面取向。