公开(公告)号：US20080039568A1

公开(公告)日：2008-02-14

申请号：US10584268

申请日：2004-12-21

申请人： Gaku Maruyama ,  Kenta Suzuki ,  Makoto Ito ,  Kazuo Katayose

发明人： Gaku Maruyama ,  Kenta Suzuki ,  Makoto Ito ,  Kazuo Katayose

IPC分类号： C08L77/06 ,  C08G69/28 ,  C08K3/32

CPC分类号： C08G69/26 ,  B60K15/03177 ,  C08K5/098 ,  C08L77/10

摘要： The present invention relates to such a polyamide resin composition that is suitably used as a material of a gasoline tank and a material of a molded article, such as a hollow molded container including a beverage bottle, a film and a sheet. A polyamide resin that is good in heat stability upon molding and suffers less increase in filter back pressure is provided by regulating a polyamide resin composition to have a phosphorus content of from 30 to 200 ppm (excluding 200 ppm), and a sodium content/phosphorus content ratio (molar ratio) of from 3 to 7 (excluding 3 and 7) or regulating it to have a phosphorus content less than 30 ppm and an alkali metal content less than 45 ppm.

摘要翻译： 本发明涉及适合用作汽油罐的材料和成型品的材料的聚酰胺树脂组合物，例如包括饮料瓶，膜和片的中空成型容器。 通过调节聚酰胺树脂组合物具有30-200ppm（不包括200ppm）的磷含量和钠含量/磷的聚酰胺树脂，其成型时的热稳定性良好且过滤背压增加较少 含量比（摩尔比）为3至7（不包括3和7）或调节为磷含量低于30ppm，碱金属含量低于45ppm。

公开(公告)号：US07687562B2

公开(公告)日：2010-03-30

申请号：US10584268

申请日：2004-12-21

申请人： Gaku Maruyama ,  Kenta Susuki ,  Makoto Ito ,  Kazuo Katayose

发明人： Gaku Maruyama ,  Kenta Susuki ,  Makoto Ito ,  Kazuo Katayose

IPC分类号： C08K3/32 ,  C08G69/26

CPC分类号： C08G69/26 ,  B60K15/03177 ,  C08K5/098 ,  C08L77/10

摘要： The present invention relates to such a polyamide resin composition that is suitably used as a material of a gasoline tank and a material of a molded article, such as a hollow molded container including a beverage bottle, a film and a sheet. A polyamide resin that is good in heat stability upon molding and suffers less increase in filter back pressure is provided by regulating a polyamide resin composition to have a phosphorus content of from 30 to 200 ppm (excluding 200 ppm), and a sodium content/phosphorus content ratio (molar ratio) of from 3 to 7 (excluding 3 and 7) or regulating it to have a phosphorus content less than 30 ppm and an alkali metal content less than 45 ppm.

摘要翻译： 本发明涉及适合用作汽油罐的材料和成型品的材料的聚酰胺树脂组合物，例如包括饮料瓶，膜和片的中空成型容器。 通过调节聚酰胺树脂组合物具有30-200ppm（不包括200ppm）的磷含量和钠含量/磷的聚酰胺树脂，其成型时的热稳定性良好且过滤背压增加较少 含量比（摩尔比）为3至7（不包括3和7）或调节为磷含量低于30ppm，碱金属含量低于45ppm。

公开(公告)号：US20070106055A1

公开(公告)日：2007-05-10

申请号：US10588652

申请日：2005-02-08

申请人： Katsuhiko Kageyama ,  Kenichi Funaki ,  Masaki Fuchikami ,  Satoru Nakagawa ,  Kazuo Katayose ,  Takahiro Nakajima ,  Naoki Watanabe ,  Fumikazu Yoshida ,  Tetsumori Atsuchi ,  Shoichi Gyobu ,  Haruo Matsumoto ,  Ryuichi Murashige ,  Gaku Maruyama ,  Yoshiko Akitomo ,  Hideki Shimizu

发明人： Katsuhiko Kageyama ,  Kenichi Funaki ,  Masaki Fuchikami ,  Satoru Nakagawa ,  Kazuo Katayose ,  Takahiro Nakajima ,  Naoki Watanabe ,  Fumikazu Yoshida ,  Tetsumori Atsuchi ,  Shoichi Gyobu ,  Haruo Matsumoto ,  Ryuichi Murashige ,  Gaku Maruyama ,  Yoshiko Akitomo ,  Hideki Shimizu

IPC分类号： C08G63/00

CPC分类号： C08G63/84 ,  C08G63/87

摘要： The invention provides a polyester produced in the presence of a polycondensation catalyst comprising at least one compound selected from a group consisting of aluminum compounds and at least one compound selected from a group consisting of phosphorus compounds and being excellent in color tone, thermal stability, and transparency and improved in terms of insoluble particles. Particularly, the invention provides a polyester in which the content of an aluminum containing insoluble particles in the polyester is 3500 ppm or lower and a polyester which has a haze value of 2% or lower when being formed into a monoaxially oriented film. The aluminum catalyst for attaining these characteristics and properties may be polyester polymerization catalyst obtained by mixing an aluminum compound and a phosphorus compound in a solvent and has specified spectral characteristics in the side measurement of 31P-NMR spectrum and 27Al-NMR spectrum.

摘要翻译： 本发明提供一种在缩聚催化剂存在下制备的聚酯，其包含至少一种选自铝化合物和至少一种选自磷化合物的化合物并且色调优异，热稳定性和 透明度和不溶性颗粒方面的改进。 特别地，本发明提供一种聚酯，其中在形成单轴取向膜时，聚酯中含有不溶性的铝的含量为3500ppm以下，聚酯的雾度值为2％以下。 用于获得这些特性和性质的铝催化剂可以是通过在溶剂中混合铝化合物和磷化合物而获得的聚酯聚合催化剂，并且在侧谱测定中具有特定的光谱特性， Al-NMR光谱。

公开(公告)号：US20080249280A1

公开(公告)日：2008-10-09

申请号：US11795556

申请日：2005-06-24

申请人： Katsuhiko Kageyama ,  Tooru Kitagawa ,  Kenichi Funaki ,  Masaki Fuchikami ,  Kazuo Katayose ,  Takahiro Nakajima ,  Toshiyuki Tsuchiya ,  Satoru Nakagawa ,  Fumikazu Yoshida ,  Haruhiko Kohyama ,  Naoki Watanabe

发明人： Katsuhiko Kageyama ,  Tooru Kitagawa ,  Kenichi Funaki ,  Masaki Fuchikami ,  Kazuo Katayose ,  Takahiro Nakajima ,  Toshiyuki Tsuchiya ,  Satoru Nakagawa ,  Fumikazu Yoshida ,  Haruhiko Kohyama ,  Naoki Watanabe

IPC分类号： C08G63/00

CPC分类号： C08G63/84 ,  C08J5/18 ,  C08J2367/02 ,  D01F6/62 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/162 ,  Y10T428/249921

摘要： This invention provides a polyester and a polyester molded product, which, while maintaining color tone, transparency, and thermal stability, can realize a high polycondensation rate, are less likely to cause the production of polycondensation catalyst-derived undesired materials, and can simultaneously meet both quality and cost effectiveness requirements, which can exhibit the characteristic features, for example, in the fields of ultrafine fibers, high transparent films for optical use, or ultrahigh transparent molded products. These advantages can be realized by using, in the production of a polyester in the presence of an aluminum compound-containing polyester polycondensation catalyst, an aluminum compound having an absorbance of not more than 0.0132 as measured in the form of an aqueous aluminum compound solution, prepared by dissolving the aluminum compound in pure water to give a concentration of 2.7 g/liter in terms of the amount of aluminum element, under conditions of cell length 1 cm and wavelength 680 nm.

摘要翻译： 本发明提供一种聚酯和聚酯成型体，其在保持色调，透明性和热稳定性的同时，可以实现高缩聚率，不太可能导致产生缩聚催化剂衍生的不需要的材料，并且可以同时满足 质量和成本效益要求，其可以表现出特征，例如在超细纤维，用于光学用途的高透明膜或超高透明模制品的领域。 这些优点可以通过在含铝化合物的聚酯缩聚催化剂的存在下制造聚酯，通过以铝化合物水溶液的形式测定的吸光度不大于0.0132的铝化合物来实现， 通过将铝化合物溶解在纯水中，在细胞长度为1cm和波长680nm的条件下，以铝元素的量计，浓度为2.7g /升。

公开(公告)号：US07868126B2

公开(公告)日：2011-01-11

申请号：US11795556

申请日：2005-06-24

申请人： Katsuhiko Kageyama ,  Tooru Kitagawa ,  Kenichi Funaki ,  Masaki Fuchikami ,  Kazuo Katayose ,  Takahiro Nakajima ,  Toshiyuki Tsuchiya ,  Satoru Nakagawa ,  Fumikazu Yoshida ,  Haruhiko Kohyama ,  Naoki Watanabe

发明人： Katsuhiko Kageyama ,  Tooru Kitagawa ,  Kenichi Funaki ,  Masaki Fuchikami ,  Kazuo Katayose ,  Takahiro Nakajima ,  Toshiyuki Tsuchiya ,  Satoru Nakagawa ,  Fumikazu Yoshida ,  Haruhiko Kohyama ,  Naoki Watanabe

IPC分类号： C08G63/00

CPC分类号： C08G63/84 ,  C08J5/18 ,  C08J2367/02 ,  D01F6/62 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/162 ,  Y10T428/249921

摘要： This invention provides a polyester and a polyester molded product, which, while maintaining color tone, transparency, and thermal stability, can realize a high polycondensation rate, are less likely to cause the production of polycondensation catalyst-derived undesired materials, and can simultaneously meet both quality and cost effectiveness requirements, which can exhibit the characteristic features, for example, in the fields of ultrafine fibers, high transparent films for optical use, or ultrahigh transparent molded products. These advantages can be realized by using, in the production of a polyester in the presence of an aluminum compound-containing polyester polycondensation catalyst, an aluminum compound having an absorbance of not more than 0.0132 as measured in the form of an aqueous aluminum compound solution, prepared by dissolving the aluminum compound in pure water to give a concentration of 2.7 g/liter in terms of the amount of aluminum element, under conditions of cell length 1 cm and wavelength 680 nm.

摘要翻译： 本发明提供一种聚酯和聚酯成型体，其在保持色调，透明性和热稳定性的同时，可以实现高缩聚率，不太可能导致产生缩聚催化剂衍生的不需要的材料，并且可以同时满足 质量和成本效益要求，其可以表现出特征，例如在超细纤维，用于光学用途的高透明膜或超高透明模制品的领域。 这些优点可以通过在含铝化合物的聚酯缩聚催化剂的存在下制造聚酯，通过以铝化合物水溶液的形式测定的吸光度不大于0.0132的铝化合物来实现， 通过将铝化合物溶解在纯水中，在细胞长度为1cm和波长680nm的条件下，以铝元素的量计，浓度为2.7g /升。