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    Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts
    1.
    发明授权
    Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts 失效
    芳香胺的氢化生成它们的环氢化对应物

    公开(公告)号：US06140540A

    公开(公告)日：2000-10-31

    申请号：US43646

    申请日：1993-04-06

    申请人： Gamini Ananda Vedage ,  Richard Scott Myers ,  John Nelson Armor

    发明人： Gamini Ananda Vedage ,  Richard Scott Myers ,  John Nelson Armor

    IPC分类号： B01J23/89 ,  C07C209/72 ,  C07C209/00

    CPC分类号： B01J23/8913 ,  C07C209/72

    摘要： This invention relates to an improved hydrogenation and isomerization process wherein aromatic amines are hydrogenated to their ring hydrogenated counterparts and substantially isomerized to their thermodynamic form. These aromatic amines are presented by the formulas: ##STR1## wherein R is hydrogen or C.sub.1-6 alkyl, R1 and R2 are hydrogen or C.sub.1-6 aliphatic, A is C.sub.1-4 or NH; n is 0-2, x is 1-3 and y is 0 to 2 except the sum of the y groups must be at least 1.

    摘要翻译： 本发明涉及改进的氢化和异构化方法，其中芳族胺被氢化成它们的环氢化对应物并基本上异构化成它们的热力学形式。 这些芳族胺由下式表示：其中R是氢或C 1-6烷基，R 1和R 2是氢或C 1-6脂族基，A是C 1-4或NH; n为0-2，x为1-3且y为0至2，除了y基团之和必须至少为1。

    Isomerization of cyclohexylamines to produce their thermodynamic isomeric form
    4.
    发明授权
    Isomerization of cyclohexylamines to produce their thermodynamic isomeric form 失效
    异构化环己胺产生其热力学异构体形式

    公开(公告)号：US6121493A

    公开(公告)日：2000-09-19

    申请号：US40311

    申请日：1993-03-30

    申请人： Gamini Ananda Vedage ,  John Nelson Armor

    发明人： Gamini Ananda Vedage ,  John Nelson Armor

    IPC分类号： B01J23/89 ,  C07C209/72 ,  C07C209/00

    CPC分类号： C07C209/72 ,  B01J23/8913

    摘要： This invention relates to an isomerization process wherein hydrogenated aromatic amines are substantially isomerized to their thermodynamic form. These hydrogenated aromatic amines are presented by the formulas: ##STR1## wherein R is hydrogen or C.sub.1-6 aliphatic, R1 and R2 are hydrogen or C.sub.1-6 aliphatic, A is C.sub.1-4 or NH; n is 0-2, x is 1-3 and y is 1 to 2 except the sum of the y groups in Formula I may be 1.The improvement in the process comprises using a catalytic system comprising cobalt preferably in combination with another Group VIII metal selected from rhodium, ruthenium, platinum, and palladium and the metal, copper. Preferably the catalyst comprises cobalt in combination with rhodium or ruthenium wherein the weight ratio of cobalt to rhodium or ruthenium, calculated on metal content, is from about 0.2 to 100 weight parts cobalt per weight part rhodium or ruthenium and the isomerization is carried out in the presence of hydrogen.

    摘要翻译： 本发明涉及异构化方法，其中氢化芳族胺基本上异构化成其热力学形式。 这些氢化芳族胺由下式表示：其中R是氢或C 1-6脂族基，R 1和R 2是氢或C 1-6脂族基，A是C 1-4或NH; n为0-2，x为1-3且y为1至2，除了式I中的y基团的总和可以为1.该方法的改进包括使用包含钴的催化体系，优选与另一种VIII族 选自铑，钌，铂和钯的金属和金属，铜。 优选地，催化剂包括与铑或钌组合的钴，其中以金属含量计算的钴与铑或钌的重量比为每重量份铑或钌约0.2至100重量份的钴，异构化在 存在氢气。

    Metal exchanged zeolite catalysts for alcohol amination
    5.
    发明授权
    Metal exchanged zeolite catalysts for alcohol amination 失效
    用于醇胺化的金属交换沸石催化剂

    公开(公告)号：US5917092A

    公开(公告)日：1999-06-29

    申请号：US49540

    申请日：1998-03-27

    申请人： Gamini Ananda Vedage ,  Lenore Ann Emig ,  Hong-Xin Li ,  John Nelson Armor

    发明人： Gamini Ananda Vedage ,  Lenore Ann Emig ,  Hong-Xin Li ,  John Nelson Armor

    IPC分类号： C07C209/16 ,  C07C211/03 ,  C07C211/06 ,  C07C211/07 ,  C07C209/38

    CPC分类号： C07C209/16

    摘要： A process for the production of predominantly primary and secondary amines and little or no tertiary amines by the reductive amination of aliphatic alcohols using a metal exchanged crystalline aluminosilicate catalyst. The catalyst has a silica/alumina ratio ranging from about 10:1 to 40:1, contains about 1 to 10% by weight of cobalt or nickel and about 0.05 to 5% by weight of at least one other metal. High conversion rates are achieved at moderate temperatures and pressures.

    摘要翻译： 通过使用金属交换的结晶硅铝酸盐催化剂对脂族醇进行还原胺化，主要生产伯胺和仲胺以及很少或不含叔胺的方法。 催化剂的二氧化硅/氧化铝比例为约10:1至40:1，含约1至10重量％的钴或镍和约0.05至5重量％的至少一种其它金属。 在适度的温度和压力下实现高转化率。

    Hydrogenation of nitriles to tertiary amines
    6.
    发明授权
    Hydrogenation of nitriles to tertiary amines 失效
    将腈氢化成叔胺

    公开(公告)号：US5672762A

    公开(公告)日：1997-09-30

    申请号：US631280

    申请日：1996-04-12

    申请人： Gamini Ananda Vedage ,  John Nelson Armor

    发明人： Gamini Ananda Vedage ,  John Nelson Armor

    IPC分类号： C07C209/48

    CPC分类号： C07C209/48

    摘要： Improved selectivity to tertiary amine production is obtained by the addition of an aliphatic or aromatic halide to the feed during the catalytic hydrogenation of saturated or unsaturated aliphatic or cycloaliphatic nitriles.

    摘要翻译： 通过在饱和或不饱和脂族或脂环族腈的催化氢化期间向进料中加入脂族或芳族卤化物可以提高对叔胺生产的选择性。