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    Process for the preparation of a homogeneous, low-viscosity and long-term-stable polymer dispersion in mineral oils
    1.
    发明申请
    Process for the preparation of a homogeneous, low-viscosity and long-term-stable polymer dispersion in mineral oils 审中-公开
    在矿物油中制备均匀，低粘度和长期稳定的聚合物分散体的方法

    公开(公告)号：US20050113261A1

    公开(公告)日：2005-05-26

    申请号：US10959597

    申请日：2004-10-06

    申请人： Georg Huber ,  Gregor Keilhofer ,  Johann Plank

    发明人： Georg Huber ,  Gregor Keilhofer ,  Johann Plank

    IPC分类号： B01F3/08 ,  B01F17/00 ,  B01J13/04 ,  C04B40/00 ,  C09K8/32 ,  C09K8/36 ,  C09K8/467 ,  C09K8/502 ,  E21B43/00 ,  C09K7/00

    CPC分类号： C09K8/502 ,  B01F3/0811 ,  B01F2215/0477 ,  B01F2215/0481 ,  C04B40/0039 ,  C09K8/32 ,  C09K8/36 ,  C09K8/467 ,  C04B14/104 ,  C04B24/26 ,  C04B24/36

    摘要： This process for the preparation of homogeneous, low-viscous and long-term-stable polymer dispersion in mineral oils, in which a liquid mineral oil component, to which a water-soluble polymer and an organophilic bentonite have been added, is stirred, is distinguished by the fact that the dispersing process is carried out at speeds of ≧1000 rpm. The duration of the stirring operation should preferably be between 5 and 60 minutes, and both aromatized and/or dearomatized mineral oils and also as typical water-soluble polymers, which moreover may have a maximum water content of 25% by weight, can be used. By means of this relatively simple process, homogeneous polymer-containing mineral oil dispersions having a low viscosity and at the same time pronounced long-term stability, which are suitable in particular for use in oil and gas exploration, are obtained in very short mixing times.

    摘要翻译： 这种在其中加入水溶性聚合物和亲有机膨润土的液体矿物油组分的矿物油中均匀，低粘度和长期稳定的聚合物分散体的制备方法被搅拌， 区别在于分散过程以> = 1000rpm的速度进行。 搅拌操作的持续时间应优选为5至60分钟，并且可以使用芳族化和/或脱气矿物油以及还可以具有25重量％的最大含水量的典型的水溶性聚合物 。 通过这种相对简单的方法，可以在非常短的混合时间内获得具有低粘度和同时显着的长期稳定性的均匀的含聚合物的矿物油分散体，其特别适用于油和气体勘探 。

    Method for breaking the viscosity of polymer-thickened aqueous systems for mineral oil and natural gas exploration
    2.
    发明申请
    Method for breaking the viscosity of polymer-thickened aqueous systems for mineral oil and natural gas exploration 审中-公开
    用于破坏矿物油和天然气勘探的聚合物增稠水性体系的粘度的方法

    公开(公告)号：US20080194432A1

    公开(公告)日：2008-08-14

    申请号：US11706058

    申请日：2007-02-14

    申请人： Jurgen Heidlas ,  Allen Gossen ,  Johann Plank ,  Peter Lange ,  Gregor Keilhofer ,  Georg Huber

    发明人： Jurgen Heidlas ,  Allen Gossen ,  Johann Plank ,  Peter Lange ,  Gregor Keilhofer ,  Georg Huber

    IPC分类号： C09K3/00

    CPC分类号： C09K8/12 ,  C09K8/508 ,  C09K8/602 ,  C09K8/604 ,  C09K8/68 ,  C09K8/74 ,  C09K8/88 ,  C09K2208/26

    摘要： A novel method for breaking the viscosity of an aqueous phase thickened with preferably hydrophilic polymers in the exploration and production of mineral oil and/or natural gas is proposed. For this purpose, the breaking is carried out via the formation of a low-viscosity emulsion, with water as the continuous phase, this emulsion being formed by the addition of at least one surface-active component to a system which consists of the thickened drilling fluid and an oil phase which is crude oil present in the reservoir and/or oil introduced into the reservoir. Solubilizers between oil phase and water phase and in particular non-ionic surfactants, cationic surfactants and/or amphoteric surfactants are used as a preferred surface-active component. In addition to the surface-active component, it is possible to use further components, which are demulsifiers, non-emulsifiers, co-surfactants or surface tension modifiers. With the aid of this method, with the simultaneous presence of an oil phase, the aqueous phase can be displaced as a low-viscosity system and finally discharged at the surface, extremely effective cleaning of the well being associated therewith. With regard to the cost-efficiency and from an environmental point of view, the use of chemicals can be completely dispensed with.

    摘要翻译： 提出了一种在勘探和生产矿物油和/或天然气中破坏优选亲水聚合物增稠的水相粘度的新方法。 为此目的，通过形成低粘度乳液进行断裂，以水为连续相，该乳液通过将至少一种表面活性组分加入到由增稠的钻孔 流体和油相，其是存在于储存器中的原油和/或引入储存器的油。 油相和水相之间的增溶剂，特别是非离子表面活性剂，阳离子表面活性剂和/或两性表面活性剂被用作优选的表面活性组分。 除了表面活性组分之外，还可以使用其它组分，这些组分是破乳剂，非乳化剂，辅助表面活性剂或表面张力调节剂。 借助该方法，同时存在油相，水相可以作为低粘度体系移位，最后在表面排出，极其有效地清洗与其相关的井。 关于成本效益和从环境的角度来看，化学品的使用可以完全免除。

    Additive for drilling fluids
    3.
    发明申请
    Additive for drilling fluids 失效

    公开(公告)号：US20060166833A1

    公开(公告)日：2006-07-27

    申请号：US11316325

    申请日：2005-12-22

    申请人： Johann Huber ,  Johann Plank ,  Jurgen Heidlas ,  Gregor Keilhofer ,  Peter Lange

    发明人： Johann Huber ,  Johann Plank ,  Jurgen Heidlas ,  Gregor Keilhofer ,  Peter Lange

    IPC分类号： C09K8/00 ,  E21B43/00

    CPC分类号： C09K8/035 ,  C09K8/506 ,  C09K8/508 ,  C09K2208/12

    摘要： Subject matter of the present invention is a drilling fluid additive based on sulfonated asphalt, which comprises a water soluble and anionic polymer component in quantities of 0.1 to 20 wt. %, with respect to the total additive in addition to the asphalt component. With this additive the water solubility of sulfonated asphalt can be markedly increased. This additive, whose polymer component is thermally highly stable, is utilized primarily in water- and/or oil-based drilling fluids and in particular in the exploration of subterraneous petroleum and natural gas deposits. Typical polymer components to consider are representatives of polycondensation products, such as phenol resins, ketone resins and sulfonated naphthalene, acetone and amino plasticizer resins (for example urea and melamine resins).

    Method of using high-alumina cements for rheology control of liquid phases
    5.
    发明申请
    Method of using high-alumina cements for rheology control of liquid phases 审中-公开
    使用高氧化铝水泥进行液相流变控制的方法

    公开(公告)号：US20070227404A1

    公开(公告)日：2007-10-04

    申请号：US11590660

    申请日：2006-10-30

    申请人： Johann Plank ,  Gregor Keilhofer ,  Jurgen Heidlas ,  Peter Lange

    发明人： Johann Plank ,  Gregor Keilhofer ,  Jurgen Heidlas ,  Peter Lange

    IPC分类号： C04B28/06 ,  C04B14/00

    CPC分类号： C09K8/16 ,  C09K8/265 ,  C09K8/36

    摘要： Rheological control of liquid phases is provided with a composition comprising a high-alumina cement component a) for controlling the rheology of liquid phases based on a clay component b). Component a) is preferably a calcium aluminate cement and component b) is preferably a clay of the smectite variety. The compositions comprise at least 20% by weight representative of the calcium aluminate cement and is preferably used for rheology control of water- or oil-based systems.

    摘要翻译： 液相的流变控制提供有包含高铝水泥组分a）的组合物，用于基于粘土组分b）控制液相的流变性。 组分a）优选是铝酸钙水泥，组分b）优选是蒙脱石品种的粘土。 组合物包含至少20重量％的代表铝酸钙水泥，并且优选用于水基或油基体系的流变学控制。

    GRAFT COPOLYMER, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF
    6.
    发明申请
    GRAFT COPOLYMER, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 审中-公开
    GRAFT共聚物，其生产方法及其用途

    公开(公告)号：US20130203951A1

    公开(公告)日：2013-08-08

    申请号：US13796097

    申请日：2013-03-12

    申请人： Roland Reichenbach-Klinke ,  Johann Plank ,  Peter Lange ,  Gregor Keilhofer

    发明人： Roland Reichenbach-Klinke ,  Johann Plank ,  Peter Lange ,  Gregor Keilhofer

    IPC分类号： C08F30/08

    CPC分类号： C08F30/08 ,  C04B40/0039 ,  C04B2103/46 ,  C08F2/44 ,  C08F292/00 ,  C09K8/487 ,  C04B14/062 ,  C04B24/163 ,  C04B24/42

    摘要： A graft copolymer based on a component a) consisting of silica which has been reacted with an unsaturated silane, and a polymer component b) containing sulphonic acid is proposed. The silica used is preferably a nanosilica and the unsaturated silane is an ethylenically unsaturated alkoxysilane. The component b) is represented by a copolymer based on AMPS and a further ethylenically unsaturated monomer. The polymer according to the invention, which as a rule is a nanocomposite, is outstandingly suitable as an additive in construction chemistry applications and in the development, exploitation and completion of underground mineral oil and natural gas deposits, its effect as a water retention agent being particularly advantageous at high salinities and increased temperatures.

    摘要翻译： 提出了一种基于由与不饱和硅烷反应的二氧化硅组成的组分a）和含有磺酸的聚合物组分b）的接枝共聚物。 所使用的二氧化硅优选为纳米二氧化硅，不饱和硅烷为烯属不饱和烷氧基硅烷。 组分b）由基于AMPS和另外的烯属不饱和单体的共聚物表示。 根据本发明的聚合物，其通常是纳米复合材料，其在建筑化学应用中的添加剂以及地下矿物油和天然气沉积物的开发，开发和完井中非常适用，其作为保水剂的作用 在高盐度和升高的温度下特别有利。

    GRAFT COPOLYMERS, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF
    7.
    发明申请
    GRAFT COPOLYMERS, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 审中-公开
    GRAFT共聚物，其生产方法及其用途

    公开(公告)号：US20110118382A1

    公开(公告)日：2011-05-19

    申请号：US12990346

    申请日：2008-05-21

    申请人： Roland Reichenbach-Klinke ,  Johann Plank ,  Peter Lange ,  Gregor Keilhofer

    发明人： Roland Reichenbach-Klinke ,  Johann Plank ,  Peter Lange ,  Gregor Keilhofer

    IPC分类号： C09K8/42 ,  C08G77/455 ,  C08L83/10 ,  B82Y30/00

    CPC分类号： C08F30/08 ,  C04B40/0039 ,  C04B2103/46 ,  C08F2/44 ,  C08F292/00 ,  C09K8/487 ,  C04B14/062 ,  C04B24/163 ,  C04B24/42

    摘要： A graft copolymer based on a component a) consisting of silica which has been reacted with an unsaturated silane, and a polymer component b) containing sulphonic acid is proposed. The silica used is preferably a nanosilica and the unsaturated silane is an ethylenically unsaturated alkoxysilane. The component b) is represented by a copolymer based on AMPS and a further ethylenically unsaturated monomer. The polymer according to the invention, which as a rule is a nanocomposite, is outstandingly suitable as an additive in construction chemistry applications and in the development, exploitation and completion of underground mineral oil and natural gas deposits, its effect as a water retention agent being particularly advantageous at high salinities and increased temperatures.

    摘要翻译： 提出了一种基于由与不饱和硅烷反应的二氧化硅组成的组分a）和含有磺酸的聚合物组分b）的接枝共聚物。 所使用的二氧化硅优选为纳米二氧化硅，不饱和硅烷为烯属不饱和烷氧基硅烷。 组分b）由基于AMPS和另外的烯属不饱和单体的共聚物表示。 根据本发明的聚合物，其通常是纳米复合材料，其在建筑化学应用中的添加剂以及地下矿物油和天然气沉积物的开发，开发和完井中非常适用，其作为保水剂的作用 在高盐度和升高的温度下特别有利。

    Additive for drilling fluids
    8.
    发明授权
    Additive for drilling fluids 失效
    钻井液添加剂

    公开(公告)号：US07576039B2

    公开(公告)日：2009-08-18

    申请号：US11316325

    申请日：2005-12-22

    申请人： Johann Huber ,  Johann Plank ,  Jürgen Heidlas ,  Gregor Keilhofer ,  Peter Lange

    发明人： Johann Huber ,  Johann Plank ,  Jürgen Heidlas ,  Gregor Keilhofer ,  Peter Lange

    IPC分类号： C09K8/035 ,  C09K8/12 ,  E21B43/22

    CPC分类号： C09K8/035 ,  C09K8/506 ,  C09K8/508 ,  C09K2208/12

    摘要： Subject matter of the present invention is a drilling fluid additive based on sulfonated asphalt, which comprises a water soluble and anionic polymer component in quantities of 0.1 to 20 wt. %, with respect to the total additive in addition to the asphalt component. With this additive the water solubility of sulfonated asphalt can be markedly increased. This additive, whose polymer component is thermally highly stable, is utilized primarily in water- and/or oil-based drilling fluids and in particular in the exploration of subterraneous petroleum and natural gas deposits. Typical polymer components to consider are representatives of polycondensation products, such as phenol resins, ketone resins and sulfonated naphthalene, acetone and amino plasticizer resins (for example urea and melamine resins).

    摘要翻译： 本发明的主题是基于磺化沥青的钻井液添加剂，其包含0.1至20重量％的水溶性和阴离子聚合物组分。 ％，相对于除了沥青组分之外的总添加剂。 使用这种添加剂可以显着提高磺化沥青的水溶性。 聚合物组分热稳定性高的添加剂主要用于水和/或油基钻井液中，特别是在探索地下石油和天然气矿床时。 要考虑的典型聚合物组分是缩聚产物的代表，例如酚醛树脂，酮树脂和磺化萘，丙酮和氨基增塑树脂（例如脲和三聚氰胺树脂）。

    Solids composition based on clay minerals and use thereof
    9.
    发明授权
    Solids composition based on clay minerals and use thereof 失效
    基于粘土矿物的固体组合物及其用途

    公开(公告)号：US6025303A

    公开(公告)日：2000-02-15

    申请号：US104580

    申请日：1998-06-25

    申请人： Gregor Keilhofer ,  Johann Plank

    发明人： Gregor Keilhofer ,  Johann Plank

    IPC分类号： C01B31/16 ,  C09K8/14 ,  C09K8/20 ,  C09K7/00

    CPC分类号： C09K8/206 ,  C09K8/145 ,  Y10S507/904

    摘要： A solids composition based on clay minerals and consisting of a) 40-99.8 wt. % of a clay mineral with a reduced moisture content of .ltoreq.7 wt. %, b) 0.01-30 wt. % of a mixed metal hydroxide and c) 0.01-30 wt. % of a solid base, and if necessary other additives, is described. The solids composition of the invention is an easy-to-use thickening agent for water-based drilling fluids, and has a long-term stability of at least three months.

    摘要翻译： 基于粘土矿物的固体组合物，由以下组成：a）40-99.8wt。 ％的水分含量为7重量％的粘土矿物。 ％，b）0.01-30重量％ ％的混合金属氢氧化物，和c）0.01-30重量％ ％的固体碱，并且如果需要其它添加剂被描述。 本发明的固体组合物是用于水基钻井液的易于使用的增稠剂，并且具有至少三个月的长期稳定性。