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公开(公告)号：US07670478B2
公开(公告)日：2010-03-02
申请号：US11266727
申请日：2005-11-03
申请人： George A. Swan, III , Rustom M. Billimoria , Rathna P. Davuluri , Steven S. Lowenthal , Todd R. Steffens , Christopher G. Smalley
发明人： George A. Swan, III , Rustom M. Billimoria , Rathna P. Davuluri , Steven S. Lowenthal , Todd R. Steffens , Christopher G. Smalley
CPC分类号： C10G11/187 , B01F5/20 , B01J4/002 , B01J8/1818 , B01J8/1827 , B01J8/1872 , B01J19/26 , C10G11/18
摘要： This invention relates to an apparatus and process for injecting a petroleum feed. More particularly, a liquid petroleum feed is atomized with a nozzle assembly apparatus in which the apparatus has injection nozzles that produce a generally flat spray pattern of finely dispersed feed. The injection nozzles are each designed such that the overall effect of the different spray patterns from the individual nozzles provides a more uniform feed coverage across the catalyst stream.
摘要翻译： 本发明涉及一种用于注入石油进料的设备和方法。 更具体地，液体石油进料用喷嘴组装设备雾化，其中该设备具有喷嘴，该注射喷嘴产生大致平坦的细分散进料的喷雾图案。 注射喷嘴各自被设计成使得来自各个喷嘴的不同喷雾图案的总体效果提供了跨越催化剂流的更均匀的进料覆盖。
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公开(公告)号：US07407572B2
公开(公告)日：2008-08-05
申请号：US11145102
申请日：2005-06-03
CPC分类号： B01J4/002 , B01J8/1809 , B01J8/1827 , B01J19/26 , B05B1/04 , C10G11/18 , C10G11/187
摘要： This invention relates to an apparatus and process for atomizing a petroleum feed. More particularly, a liquid petroleum feed is atomized with an atomization apparatus in which the apparatus has an orifice that produces a generally flat spray pattern of finely dispersed feed prior to contacting catalyst in a fluid catalytic cracking zone. The orifice has a general aspect ratio greater than 1.0 and a ratio of perimeter length-to-cross-sectional area greater than 1.5 relative to a perimeter-to-cross-sectional area ratio of a circular orifice of equivalent area. The apparatus can be used to atomize feed injected into the cracking zone of a fluid catalytic cracker.
摘要翻译： 本发明涉及一种用于雾化石油原料的装置和方法。 更具体地，液体石油进料用雾化装置雾化，其中装置具有孔口，其在催化剂在流化催化裂化区域中接触之前产生细分散进料的大致平坦的喷雾图案。 孔口具有大于1.0的总体纵横比和相对于等效面积的圆形孔口的周长与横截面积比的周长长度与横截面积的比率大于1.5。 该装置可用于雾化注入流化催化裂化器裂化区的原料。
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公开(公告)号：US07594993B2
公开(公告)日：2009-09-29
申请号：US10574796
申请日：2004-10-29
申请人： Dean C. Draemel , Todd R. Steffens
发明人： Dean C. Draemel , Todd R. Steffens
IPC分类号： C10G11/18
CPC分类号： C10G11/05 , B01J8/004 , B01J8/1827 , B01J8/1872 , B01J2208/00752 , C10G11/18
摘要： This invention relates to the feed injection zone of a FCC. The feed injection zone is non-circular in shape allows for optimal penetration between feed and catalyst in the feed injection zone.
摘要翻译： 本发明涉及FCC的进料注射区。 进料注射区是非圆形的，允许进料和进料区域中的进料和催化剂之间的最佳渗透。
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4.发明授权Process for selectively producing C3 olefins in a fluid catalytic cracking process with recycle of a C4 fraction to a secondary reaction zone separate from a dense bed stripping zone 失效在流化催化裂化过程中选择性生产C3烯烃的方法，其中将C4馏分再循环到与致密床层汽提区分开的第二反应区公开(公告)号：US07374660B2
公开(公告)日：2008-05-20
申请号：US10993057
申请日：2004-11-19
IPC分类号： C10G51/02 , C10G51/04 , C10G55/04 , C10G55/06 , C10G57/00 , C10G9/00 , C10G15/00 , C10G47/00
摘要： A process for selectively producing C3 olefins from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone containing a dense phase, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to about 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, and are then recycled to the reaction zone. Overhead products from the reaction zone are passed to a fractionation zone where a stream of C3 products is recovered and a stream rich in C4 olefins is recycled to a dilute phase reaction zone in the stripping zone separate from the dense phase of the stripping zone. The olefins can be further processed and polymerized to form a variety of polymer materials.
摘要翻译： 本文公开了从催化裂化或热裂解的石脑油流中选择性地生产C 3 O 3烯烃的方法。 将石脑油流引入由反应区，含有密相的汽提区，催化剂再生区和分馏区组成的工艺单元中。 石脑油原料流在反应区中与含有约10至约50wt。 ％的平均孔径在反应条件下小于约0.7纳米的结晶沸石。 蒸气产物被顶部收集，催化剂颗粒在通向催化剂再生区的途中通过汽提区。 挥发物在汽提区中用蒸汽汽提，催化剂颗粒被送到催化剂再生区，在该区域，焦炭从催化剂中燃烧，然后再循环到反应区。 将来自反应区的开销产物通入分馏区，在该分馏区中回收C 3 3产物流，将富含C 4 O 3烯烃的物流循环至稀相反应 汽提区域与汽提区的密相分离。 烯烃可以进一步加工和聚合以形成各种聚合物材料。
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公开(公告)号：US6114265A
公开(公告)日：2000-09-05
申请号：US213347
申请日：1994-03-15
申请人： Todd R. Steffens , Paul K. Ladwig
发明人： Todd R. Steffens , Paul K. Ladwig
CPC分类号： C10G11/182 , B01J38/20 , C10G11/187 , Y10S502/514
摘要： Disclosed is a process for controlling combustion in a fluid catalytic cracking regenerator. More specifically, afterburning which occurs during the combustion process is controlled by adjusting oxygen concentration in at least one of two combustion streams which is injected into a fluid catalytic cracking regenerator. Preferably, the combustion streams used in the invention are asymmetrically injected into a dense phase catalyst bed within the regenerator.
摘要翻译： 公开了一种用于控制流化催化裂化再生器中的燃烧的方法。 更具体地，在燃烧过程中发生的后燃烧通过调节注入流化催化裂化再生器的两个燃烧流中的至少一个中的氧浓度来控制。 优选地，本发明中使用的燃烧流不对称地注入到再生器内的致密相催化剂床中。
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6.发明授权
公开(公告)号：US5348642A
公开(公告)日：1994-09-20
申请号：US16398
申请日：1993-02-11
CPC分类号： C10G11/18
摘要： A catalytic cracking process and apparatus wherein particles of cracking catalyst circulate continuously between a reaction zone and a regeneration zone and hot regenerated catalyst from the regeneration zone contacts hydrocarbon feed in the reaction zone to produce cracked hydrocarbon products and spent catalyst. The spent catalyst is recovered and subjected to stripping in a stripping zone to remove strippable material therefrom. The stripped spent catalyst is circulated to the regeneration zone for oxidative exothermic regeneration. Some hot regenerated catalyst is passed directly from the regenerator to the stripping zone via a conduit provided for this purpose. Another hydrocarbon stream is passed into contact with the hot regenerated catalyst in this conduit. The said other hydrocarbon stream is converted to products of enhanced value (e.g., olefins) during contact with catalyst in the conduit, and the said products are recovered. The heat for the conversion is abstracted from the catalyst particles passing via the pipe to the stripping zone. The hot catalyst particles entering the stripping zone from the pipe increase the temperature in the stripping zone, thereby improving the stripping in the stripping zone.
摘要翻译： 一种催化裂化方法和装置，其中裂化催化剂颗粒在反应区和再生区之间连续循环，再生区再热催化剂与反应区中的烃进料接触，产生裂化烃产物和废催化剂。 将废催化剂回收并在汽提区中进行汽提以从其中除去可剥离材料。 汽提的废催化剂循环到再生区进行氧化放热再生。 一些热再生催化剂通过为此目的提供的导管从再生器直接通入汽提区。 使另一种烃流与该导管中的热再生催化剂接触。 所述其它烃流在与导管中的催化剂接触期间被转化为具有增强价值的产物（例如烯烃），并且回收所述产物。 用于转化的热量从通过管道的催化剂颗粒抽吸到汽提区。 从管道进入汽提区的热催化剂颗粒增加汽提区的温度，从而改善汽提区的汽提。
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7.发明授权Method for maintaining heat balance in a fluidized bed catalytic cracking unit 失效在流化床催化裂化装置中保持热平衡的方法公开(公告)号：US06558531B2
公开(公告)日：2003-05-06
申请号：US09804721
申请日：2001-03-13
申请人： Todd R. Steffens , Paul K. Ladwig , George Melfi , John E. Asplin
发明人： Todd R. Steffens , Paul K. Ladwig , George Melfi , John E. Asplin
IPC分类号： C10G1100
CPC分类号： C10G11/18 , C10G11/182
摘要： The invention relates to a process for maintaining heat balance in a fluidized bed catalytic cracking unit. More specifically, the invention relates to a combustion control method capable of maintaining or restoring heat balance by conducting, under appropriate conditions, fuel and an oxygen-containing gas to a transfer line. The transfer line conducts effluent including spent catalyst and combustion products to the unit's catalyst regeneration zone.
摘要翻译： 本发明涉及一种维持流化床催化裂化装置中的热平衡的方法。 更具体地，本发明涉及一种能够通过在适当条件下将燃料和含氧气体传导到传输线来维持或恢复热平衡的燃烧控制方法。 输送管线将包括废催化剂和燃烧产物的废水排放到设备的催化剂再生区。
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公开(公告)号：US06455750B1
公开(公告)日：2002-09-24
申请号：US09437408
申请日：1999-11-10
申请人： Todd R. Steffens , Paul K. Ladwig
发明人： Todd R. Steffens , Paul K. Ladwig
IPC分类号： C07C406
CPC分类号： C10G11/05 , C10G51/023 , C10G57/02 , C10G2400/20
摘要： The invention is related to a catalyst and a process for selectively producing light (i.e., C2-C4) olefins from a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions. The catalysts do not require steam activation.
摘要翻译： 本发明涉及一种催化剂和从催化裂化或热裂解的石脑油流中选择性地生产光（即C 2 -C 4）烯烃的方法。 将石脑油流与含有约10至50wt。 ％的平均孔径在反应条件下小于约0.7纳米的结晶沸石。 催化剂不需要蒸汽活化。
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公开(公告)号：US07452838B2
公开(公告)日：2008-11-18
申请号：US11070607
申请日：2005-03-02
IPC分类号： B01J20/34
摘要： This invention relates to efficiently regenerating catalyst particles by minimizing the formation of localized “hot spots” and “cold spots” in a regeneration zone. In one embodiment, the invention includes mixing spent catalyst from a reactor and cold catalyst from a catalyst cooler in a mixing zone and directing the mixed catalyst to the regeneration zone in a fluidized manner with a fluidizing medium. In the regeneration zone, the mixed catalyst contacts an oxygen-containing regeneration medium under conditions effective to regenerate the spent catalyst contained therein.
摘要翻译： 本发明涉及通过最小化再生区中局部“热点”和“冷点”的形成来有效地再生催化剂颗粒。 在一个实施方案中，本发明包括将来自反应器的废催化剂和来自混合区域中的催化剂冷却器的冷催化剂混合并将流化介质以流化方式引导至再生区。 在再生区中，混合催化剂在有效地再生其中所含的废催化剂的条件下与含氧再生介质接触。
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公开(公告)号：US06602403B1
公开(公告)日：2003-08-05
申请号：US09437161
申请日：1999-11-10
申请人： Todd R. Steffens , Paul K. Ladwig
发明人： Todd R. Steffens , Paul K. Ladwig
IPC分类号： C10G1105
CPC分类号： C10G51/023 , C10G35/095 , C10G57/02 , C10G63/04 , C10G2400/20
摘要： This invention is related to a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500° C. to about 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. The resulting product is a high octane naphtha.
摘要翻译： 本发明涉及催化裂化或热裂解的石脑油流。 将石脑油流与含有约10至50wt。 在包括约500℃至约650℃的温度和约10至40psia的烃分压的反应条件下具有平均孔径小于约0.7纳米的结晶沸石的％。 所得产物是高辛烷值的石脑油。
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