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公开(公告)号：US5209827A
公开(公告)日：1993-05-11
申请号：US743639
申请日：1991-08-12
申请人： Gerald E. Butler , Garrett C. Luce , Don L. Morris
发明人： Gerald E. Butler , Garrett C. Luce , Don L. Morris
IPC分类号： C07C67/54 , C07C69/675
CPC分类号： C07C67/54
摘要： Disclosed is a process for the recovery of purified hydroxypivalyl hydroxypivalate (HPHP) from a crude, HPHP containing material containing inorganic catalyst residues and low-boiling and high-boiling (with respect to the boiling point of HPHP) impurities. The purification process employs two distillation zones, a first distillation zone wherein inorganic and high-boiling impurities are removed and a second distillation zone wherein low- and high-boiling impurities are removed.
摘要翻译： 公开了一种从含有无机催化剂残留物和低沸点和高沸点（相对于HPHP沸点）杂质的粗制含HPHP的材料中回收纯化的羟基新戊酸羟基新戊酸酯（HPHP）的方法。 净化过程使用两个蒸馏区，其中去除无机和高沸点杂质的第一蒸馏区和除去低沸点和高沸点杂质的第二蒸馏区。
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2.发明授权Continuous process for the recovery of 2 ethylhexanal and a tertiary amine from a mixture comprising 2-ethyl-2-(hydroxymethyl) hexanal, 2-ethylhexanal, tertiary amine and water 失效从包含2-乙基-2-（羟甲基）己醛，2-乙基己醛，叔胺和水的混合物中回收2-乙基己醛和叔胺的连续方法
公开(公告)号：US5177267A
公开(公告)日：1993-01-05
申请号：US886917
申请日：1992-05-22
摘要： Disclosed is a continuous process for the manufacture of 2-ethyl-2-(hydroxymethyl)hexanal wherein 2-ethylhexanal, formaldehyde and a tertiary amine are continuously fed to a reaction zone and crude product comprising an aqueous phase and an organic phase containing 2-ethyl-2-(hydroxymethyl)hexanal and 2-ethylhexanal is continuously removed from the reaction zone. Also disclosed are processes for (1) the azeotropic distillation of the organic phase of the crude product whereby unreacted 2-ethylhexanal is recovered and (2) the catalytic hydrogenation of the refined, organic phase of the crude product to produce 2-butyl-2-ethyl-1,3-propanediol.
摘要翻译： 公开了用于制备2-乙基-2-（羟甲基）己醛的连续方法，其中将2-乙基己醛，甲醛和叔胺连续加入到反应区中，粗产物包含水相和含2- 乙基-2-（羟甲基）己醛和2-乙基己醛从反应区连续除去。 还公开了（1）粗产物的有机相的共沸蒸馏的方法，由此回收未反应的2-乙基己醛和（2）粗产物的精制有机相的催化氢化，得到2-丁基-2 - 乙基-1,3-丙二醇。
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公开(公告)号：US4855515A
公开(公告)日：1989-08-08
申请号：US084716
申请日：1987-08-12
IPC分类号： C07C29/141 , C07C45/75
CPC分类号： C07C29/141 , C07C45/75
摘要： A method for producing neopentyl glycol is described using tertiaryamines as a catalyst for the condensation of isobutyraldehyde and formaldehyde followed by hydrogenation of the resulting reaction mixture using a manganese oxide promoted copper chromite catalyst.
摘要翻译： 使用叔胺作为用于缩合异丁醛和甲醛的催化剂，然后使用氧化锰促进的亚铬酸铜催化剂氢化所得反应混合物来描述新戊二醇的制备方法。
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公开(公告)号：US4316990A
公开(公告)日：1982-02-23
申请号：US201954
申请日：1980-10-29
申请人： Don L. Morris
发明人： Don L. Morris
CPC分类号： C07C45/74
摘要： In the present invention aliphatic aldehydes are condensed to form .alpha.,.beta.-unsaturated aldehydes by use of a heterogeneous catalyst. Such process uses an anatase titanium dioxide catalyst in a fixed bed process under mild temperature conditions to yield high conversions and high yields, and which also eliminates the catalyst removal steps required by conventional processes.
摘要翻译： 在本发明中，通过使用非均相催化剂将脂族醛缩合形成α，β-不饱和醛。 这种方法在温和条件下在固定床工艺中使用锐钛型二氧化钛催化剂，以产生高转化率和高产率，并且还消除了常规方法所需的催化剂去除步骤。
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5.发明授权Continuous process for the preparation of 2-ethyl-2-(hydroxymethyl) hexanal and 2-butyl-2-theyl-1,3-propanediol 失效用于制备2-乙基-2-（羟甲基）己醛和2-丁基-2-己基-1,3-丙二醇的连续方法
公开(公告)号：US5146004A
公开(公告)日：1992-09-08
申请号：US735575
申请日：1991-07-25
IPC分类号： B01J23/755 , B01J31/02 , C07B61/00 , C07C29/141 , C07C31/20 , C07C45/75 , C07C45/83 , C07C45/84 , C07C47/19
摘要： Disclosed is a continuous process for the manufacture of 2-ethyl-2-(hydroxymethyl)hexanal wherein 2-ethylhexanal, formaldehyde and a tertiary amine are continuously fed to a reaction zone and crude product comprising an aqueous phase and an organic phase containing 2-ethyl-2-(hydroxymethyl)hexanal and 2-ethylhexanal is continuously removed from the reaction zone. Also disclosed are processes for (1) the azeotropic distillation of the organic phase of the crude product whereby unreacted 2-ethylhexanal is recovered and (2) the catalytic hydrogenation of the refined, organic phase of the crude product to produce 2-butyl-2-ethyl-1,3-propanediol.
摘要翻译： 公开了用于制备2-乙基-2-（羟甲基）己醛的连续方法，其中将2-乙基己醛，甲醛和叔胺连续加入到反应区中，粗产物包含水相和含2- 乙基-2-（羟甲基）己醛和2-乙基己醛从反应区连续除去。 还公开了（1）粗产物的有机相的共沸蒸馏的方法，由此回收未反应的2-乙基己醛和（2）粗产物的精制有机相的催化氢化，得到2-丁基-2 - 乙基-1,3-丙二醇。
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公开(公告)号：US4256916A
公开(公告)日：1981-03-17
申请号：US66759
申请日：1979-08-15
IPC分类号： C07C59/125 , C07C51/00 , C07C51/235 , C07C67/00 , C07C17/26
CPC分类号： C07C51/235
摘要： Polyethylene glycols of the typeHOCH.sub.2 CH.sub.2 O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 OHwherein n is an integer of from 0 to 5, can be converted to the corresponding dicarboxylic acids of the formulaHOOCCH.sub.2 O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 COOHwherein n is as previously defined, by oxidation in an aqueous solution over a fixed bed catalyst consisting of platinum on a granular carbon support.
摘要翻译： 其中n为0至5的整数的HOCH 2 CH 2 O（CH 2 CH 2 O）n CH 2 CH 2 OH类型的聚乙二醇可以通过水溶液中的氧化转化成式HOOCCH2O（CH2CH2O）nCH2COOH的相应二羧酸，其中n如前所定义 在由颗粒碳载体上的铂组成的固定床催化剂上。
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公开(公告)号：US4131739A
公开(公告)日：1978-12-26
申请号：US814562
申请日：1977-07-11
申请人： Don L. Morris
发明人： Don L. Morris
CPC分类号： C07C51/00
摘要： Cyclic acetals are rearranged to form isomeric carboxylic acid esters according to the following formula: ##STR1## wherein R is an alkyl, alkenyl, or aromatic moiety containing 1 to 12 carbon atoms;AndR' is an alkyl or alkenyl moiety containing 1 to 12 carbon atoms;In the presence of a catalyst consisting of a metal selected from the group Ru, Rh, Pd, Os, Ir or Pt supported on carbon.
摘要翻译： 重整环状缩醛以形成根据下式的异构羧酸酯：其中R是含有1至12个碳原子的烷基，烯基或芳族部分; 且R'是含有1至12个碳原子的烷基或烯基部分; 在由碳组成的Ru，Rh，Pd，Os，Ir或Pt族中选出的金属的催化剂存在下。
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8.发明授权Continuous process for the preparation of 2-ethyl-2-(hydroxymethyl)hexanal and 2-butyl-2-ethyl-1, 3-propanediol 失效用于制备2-乙基-2-（羟甲基）己醛和2-丁基-2-乙基-1,3-丙二醇的连续方法
公开(公告)号：US5235118A
公开(公告)日：1993-08-10
申请号：US937039
申请日：1992-08-31
摘要： Disclosed is a continuous process for the manufacture of 2-ethyl-2-(hydroxymethyl)hexanal wherein 2-ethylhexanal, formaldehyde and a tertiary amine are continuously fed to a reaction zone and crude product comprising an aqueous phase and an organic phase containing 2-ethyl-2-(hydroxymethyl)hexanal and 2-ethylhexanal is continuously removed from the reaction zone Also disclosed are processes for (1) the azeotropic distillation of the organic phase of the crude product whereby unreacted 2-ethylhexanal is recovered and (2) the catalytic hydrogenation of the refined, organic phase of the crude product to produce 2-butyl-2-ethyl-1,3-propanediol.
摘要翻译： 公开了用于制备2-乙基-2-（羟甲基）己醛的连续方法，其中将2-乙基己醛，甲醛和叔胺连续加入到反应区中，粗产物包含水相和含2- 乙基-2-（羟甲基）己醛和2-乙基己醛从反应区连续除去。还公开了（1）粗产物的有机相的共沸蒸馏的方法，从而回收未反应的2-乙基己醛，（2） 催化氢化粗产物的精制有机相，生成2-丁基-2-乙基-1,3-丙二醇。
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公开(公告)号：US5041621A
公开(公告)日：1991-08-20
申请号：US413355
申请日：1989-09-27
申请人： Don L. Morris , Gary C. Luce
发明人： Don L. Morris , Gary C. Luce
IPC分类号： B01J21/02 , B01J21/06 , B01J21/10 , B01J23/02 , B01J23/34 , C07B61/00 , C07C67/44 , C07C69/675
CPC分类号： C07C67/44
摘要： Process is disclosed for the preparation of dihydroxy esters such as hydroxypivalyl hydroxypivalate from hydroxy aldehydes such as hydroxypivaldehyde by contacting said hydroxy aldehydes with low levels of at least one elemental metal selected from a defined group of metals. Reaction product is readily recovered without the need for extensive catalysts neutralization and/or removal procedures.
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10.发明授权Triethylamine catalyzed neopentyl glycol production utilizing a gas sparged reactor 失效三乙胺催化新戊二醇生产利用气体反应器
公开(公告)号：US4851592A
公开(公告)日：1989-07-25
申请号：US113049
申请日：1987-10-27
申请人： Don L. Morris
发明人： Don L. Morris
CPC分类号： C07C29/141 , C07C45/75
摘要： A process for producing neopentyl glycol is disclosed which comprises reacting isobutyraldehyde and formaldehyde in the presence of a trialkylamine catalyst to form a condensation reaction product comprising hydroxypivaldehyde, followed by hydrogenation of the hydroxypivaldehyde in a hydrogen gas sparged reactor in the presence of a Raney nickel catalyst. This process minimizes unwanted by-products, and does not have to be carried out under high pressure as do certain prior art methods.
摘要翻译： 公开了一种生产新戊二醇的方法，其包括在三烷基胺催化剂存在下使异丁醛和甲醛反应，形成包含羟基异丙醛的缩合反应产物，然后在氦氖镍催化剂存在下在氢气鼓泡反应器中氢化羟基甲醛 。 该方法使不想要的副产物最小化，并且不必像现有技术的方法一样在高压下进行。
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