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公开(公告)号：US20060155071A1
公开(公告)日：2006-07-13
申请号：US10532686
申请日：2003-11-03
申请人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
发明人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
IPC分类号： C08L23/00
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2≦; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译： 本发明涉及含有高达40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比r1r2的产物= e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。
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公开(公告)号：US07943717B2
公开(公告)日：2011-05-17
申请号：US10532686
申请日：2003-11-03
申请人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
发明人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
IPC分类号： C08F10/04 , C08F10/14 , C08F110/04 , C08F110/14 , C08F4/44 , C08L23/00 , C08L23/04
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2≦2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译： 本发明涉及含有至多40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比r1·r2＆nlE; 2的产物; e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。
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公开(公告)号：US20110136981A1
公开(公告)日：2011-06-09
申请号：US13014216
申请日：2011-01-26
申请人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
发明人： Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale , Daniele Bigiavi , Anteo Pelliconi , Enea Garagnani , Pietro Baita
IPC分类号： C08L23/20 , C08F210/08
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived units characterized by the following properties: d) Product of the reactivity ratios r1·r2≦2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译： 本发明涉及含有至多40摩尔％乙烯和/或丙烯衍生单元的丁烯-1共聚物，其特征在于以下性质：d）反应性比r1·r2＆nlE; 2的产物; e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。
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公开(公告)号：US20080004409A1
公开(公告)日：2008-01-03
申请号：US11665630
申请日：2005-10-12
申请人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
发明人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/15 , C08F210/14 , C08F210/16 , C08F210/06
摘要： Butene-1 (co)polymers characterized by the following properties: content of butene-1 units in the form of isotactic pentads (mmmm) from 25 to 55%; intrinsic viscosity [η] measured in tetraline at 135° C. from 1 to 3 dL/g; content of xylene insoluble fraction at 0° C. from 3 to 60%; and a ratio ES2/ES1>1, where ES1 is the boiling diethyl ether soluble fraction determined on the polymer as such and ES2 is the boiling diethyl ether soluble fraction determined after milling the polymer. The butene-1 (co)polymers show a good balance between processability and elastomeric behavior.
摘要翻译： 丁烯-1（共）聚合物，其特征在于以下性质：全同立构五单元形式的丁烯-1单元的含量（mmmm）为25至55％; 在135℃的四氢化萘中测量的特性粘度η为1至3dL / g; 0℃下二甲苯不溶级分含量为3〜60％; 和ES ES 2 / ES 1比1，其中ES 1是在聚合物上测定的沸腾二乙醚可溶级分，ES为ES 沸点二乙醚可溶级分是在研磨聚合物之后测定的。 丁烯-1（共）聚合物在加工性和弹性体性能之间显示出良好的平衡。
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公开(公告)号：US07776986B2
公开(公告)日：2010-08-17
申请号：US11665630
申请日：2005-10-12
申请人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Silvia Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
发明人： Dino Bacci , Friederike Morhard , Fabrizio Piemontesi , Maria Silvia Tonti , Gianni Vitale , Giampiero Morini , Anteo Pelliconi
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/15 , C08F210/14 , C08F210/16 , C08F210/06
摘要： Butene-1 (co)polymers characterized by the following properties: content of butene-1 units in the form of isotactic pentads (mmmm) from 25 to 55%; intrinsic viscosity [η] measured in tetraline at 135° C. from 1 to 3 dL/g; content of xylene insoluble fraction at 0° C. from 3 to 60%; and a ratio ES2/ES1≧1, where ES1 is the boiling diethyl ether soluble fraction determined on the polymer as such and ES2 is the boiling diethyl ether soluble fraction determined after milling the polymer. The butene-1 (co)polymers show a good balance between processability and elastomeric behavior.
摘要翻译： 丁烯-1（共）聚合物，其特征在于以下性质：全同立构五单元形式的丁烯-1单元的含量（mmmm）为25至55％; 在135℃下在四氢萘中测量的特性粘度为1至3dL / g; 0℃下二甲苯不溶级分含量为3〜60％; 和ES2 /ES1≥1的比例，其中ES1是在聚合物上测定的沸点二乙醚可溶性级分，ES2是在研磨聚合物之后测定的沸点二乙醚可溶性级分。 丁烯-1（共）聚合物在加工性和弹性体性能之间显示出良好的平衡。
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6.发明授权Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 有权二氯化镁 - 醇加合物和由其获得的催化剂组分公开(公告)号：US07482413B2
公开(公告)日：2009-01-27
申请号：US10550986
申请日：2004-03-09
申请人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
发明人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F4/65
摘要： The present invention relates to MgCl2.(EtOH),m(ROH)n(H2O)p adduct in which R is a C1-C15 hydrocarbon group different from ethyl, n and m are indexes, higher than 0, satisfying the equations (n+m)≧0.7 and 0.05≦n/(n+m)≦0.95 and p is a number ranging from 0 to 0.7 with the proviso that when R is methyl and (n+m) is in the range of 0.7 to 1, the value of n/(n+m) ranges from 0.05 to 0.45. The catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译： 本发明涉及MgCl 2（EtOH），m（ROH）n（H 2 O）p加合物，其中R是不同于乙基的C 1 -C 15烃基，n和m是指数，高于0，满足等式（n + m）> = 0.7和0.05 <= n /（n + m）<= 0.95，p为0至0.7的数，条件是当R为甲基且（n + m）为0.7 为1，n /（n + m）的值为0.05〜0.45。 从本发明的加合物得到的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。
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7.发明申请Magnesium Chloride-Based Adducts And Catalyst Components Obtained Therefrom 审中-公开氯化镁基加合物和其中获得的催化剂组分公开(公告)号：US20070282147A1
公开(公告)日：2007-12-06
申请号：US10594780
申请日：2005-03-03
申请人： Yuri Gulevich , Isabella Comurati , Antonio Cristofori , Tiziano Dall'Occo , Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale
发明人： Yuri Gulevich , Isabella Comurati , Antonio Cristofori , Tiziano Dall'Occo , Giampiero Morini , Fabrizio Piemontesi , Gianni Vitale
IPC分类号： C08F110/06 , C07F3/02 , C08F4/651
CPC分类号： C07F3/003 , C07F7/003 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/15 , C08F2500/12 , C08F2500/17
摘要： Lewis base adducts comprising MgCln(OR)2-n, and an aprotic Lewis base that are in molar ratios to each other defined by the formula MgCln(OR)2-nLBp in which n is from 0.1 to 1.9, p is higher than 0.4, and R is a C1-C15 hydrocarbon group. The adducts of the present invention are particularly useful as precursors of Ziegler-Natta catalyst components for the polymerization of olefins.
摘要翻译： 包含MgCl 3（OR）2-n N的路易斯碱加成物和彼此以摩尔比计的摩尔比为非离子路易斯碱，由式MgCl n 其中n为0.1至1.9，p高于0.4，R为C1-C15烃基。 本发明的加合物特别可用作烯烃聚合的齐格勒 - 纳塔催化剂组分的前体。
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8.发明授权公开(公告)号：US07592286B2
公开(公告)日：2009-09-22
申请号：US10557933
申请日：2004-05-07
申请人： Giampiero Morini , Tiziano Dall'Occo , Fabrizio Piemontesi , Rosa Spoto , Paolo Vincenzi , Gianni Vitale
发明人： Giampiero Morini , Tiziano Dall'Occo , Fabrizio Piemontesi , Rosa Spoto , Paolo Vincenzi , Gianni Vitale
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6367 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F4/6555 , C08F4/6492 , C08F4/6545 , C08F4/6565
摘要： A process for preparing a catalyst component, comprising a Mg compound a Ti compound and an electron donor compound (ED) selected from alcohol, glycols, esters, ketones, amines, amides, nitrites, alkoxysilanes and aliphatic ethers as essential compounds, comprising two or more steps of reaction involving the use of at least one of said essential compounds as fresh reactant alone or in a mixture in which it constitutes the main component, said process being characterized by the fact that in the last of said one or more reaction steps the essential compound used as a fresh reactant is the ED compound.
摘要翻译： 一种制备催化剂组分的方法，包括Mg化合物，Ti化合物和选自醇，二醇，酯，酮，胺，酰胺，亚硝酸盐，烷氧基硅烷和脂族醚作为必需化合物的电子给体化合物（ED），包括两个或 更多的反应步骤涉及使用至少一种所述必需化合物作为新鲜反应物或其构成主要组分的混合物，所述方法的特征在于在所述一个或多个反应步骤的最后一个步骤中， 用作新鲜反应物的必需化合物是ED化合物。
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9.发明申请公开(公告)号：US20070021295A1
公开(公告)日：2007-01-25
申请号：US10557933
申请日：2004-05-07
申请人： Giampiero Morini , Tiziano Dall'Occo , Fabrizio Piemontesi , Rosa Spoto , Paolo Vincenzi , Gianni Vitale
发明人： Giampiero Morini , Tiziano Dall'Occo , Fabrizio Piemontesi , Rosa Spoto , Paolo Vincenzi , Gianni Vitale
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6367 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F4/6555 , C08F4/6492 , C08F4/6545 , C08F4/6565
摘要： A process for preparing a catalyst component, comprising a Mg compound a Ti compound and an electron donor compound (ED) selected from alcohol, glycols, esters, ketones, amines, amides, nitrites, alkoxysilanes and aliphatic ethers as essential compounds, comprising two or more steps of reaction involving the use of at least one of said essential compounds as fresh reactant alone or in a mixture in which it constitutes the main component, said process being characterized by the fact that in the last of said one or more reaction steps the essential compound used as a fresh reactant is the ED compound.
摘要翻译： 一种制备催化剂组分的方法，包括Mg化合物，Ti化合物和选自醇，二醇，酯，酮，胺，酰胺，亚硝酸盐，烷氧基硅烷和脂族醚作为必需化合物的电子给体化合物（ED），包括两个或 更多的反应步骤涉及使用至少一种所述必需化合物作为新鲜反应物或其构成主要组分的混合物，所述方法的特征在于在所述一个或多个反应步骤的最后一个步骤中， 用作新鲜反应物的必需化合物是ED化合物。
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10.发明申请Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 有权二氯化镁 - 醇加合物和由其获得的催化剂组分公开(公告)号：US20060217261A1
公开(公告)日：2006-09-28
申请号：US10550986
申请日：2004-03-09
申请人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
发明人： Giampiero Morini , Giulio Balbontin , Fabrizio Piemontesi , Maria Fusto , Gianni Vitale , Giansiro Prini
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F4/65
摘要： The present invention relates to MgCl2.(EtOH),m(ROH)n(H20)p adduct in which R is a C1-C15 hydrocarbon group different from ethyl, n and m are indexes, higher than 0, satisfying the equations (n+m)≧0.7 and 0.05≦n/(n+m)≦0.95 and p is a number ranging from 0 to 0.7 with the proviso that when R is methyl and (n+m) is in the range of 0.7 to 1, the value of n/(n+m) ranges from 0.05 to 0.45. The catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译： 本发明涉及MgCl 2（EtOH），（II），（H 2 O）2（H 2 O） 其中R是不同于乙基的C 1 -C 15烃基的加合物，n和m是指数，高于0，满足式（n + m）= 0.7和0.05 <= n / （n + m）<= 0.95，p为0〜0.7的数，条件是当R为甲基且（n + m）为0.7〜1时，n /（n + m） ）为0.05〜0.45。 从本发明的加合物得到的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。
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