公开(公告)号：US07700514B2

公开(公告)日：2010-04-20

申请号：US11979637

申请日：2007-11-06

申请人： Gil Mabilon ,  Patrice Marecot ,  Denis Uzio ,  Catherine Especel ,  Florence Epron

发明人： Gil Mabilon ,  Patrice Marecot ,  Denis Uzio ,  Catherine Especel ,  Florence Epron

IPC分类号： B01J27/06 ,  B01J27/13 ,  B01J23/42 ,  C07C5/00

CPC分类号： B01J23/42 ,  B01J21/04 ,  B01J23/464 ,  B01J23/89 ,  B01J37/0205 ,  B01J37/06 ,  B01J37/16 ,  C07C5/31 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2527/13 ,  C10G45/62 ,  C07C9/14

摘要： A catalyst comprising at least one porous support, at least some platinum, and at least a second group VIII metal which is different from platinum and iridium, said catalyst having been prepared in accordance with a process comprising a) impregnation of the support with at least one solution containing a platinum precursor, b) activation in a neutral or oxidizing atmosphere, at a temperature of between 120 and 800° C., c) activation in a reducing medium, at a temperature of between 0 and 800° C., d1) impregnation with an aqueous solution and d2) treatment with at least one hydrogen donor compound, at a temperature of less than 200° C., e) the impregnation of the support, which has already been impregnated with the platinum, with at least one solution containing a precursor of said second group VIII metal, and f) activation in a neutral, reducing, or oxidizing atmosphere, at a temperature of between 100 and 800° C.

摘要翻译： 一种催化剂，其包含至少一种多孔载体，至少一些铂和至少一种不同于铂和铱的第Ⅷ族金属，所述催化剂是根据以下方法制备的，所述方法包括：a）至少浸渍载体 一种含有铂前体的溶液，b）在中性或氧化性气氛中在120-800℃的温度下活化，c）在还原介质中，在0和800℃之间的温度下，d1 ）用水溶液浸渍，和d2）在低于200℃的温度下用至少一种氢供体化合物进行处理，e）将已经用铂浸渍的载体浸渍至少一个 含有所述第二族VIII族金属的前体的溶液，和f）在中性，还原性或氧化性气氛中在100〜800℃的温度下进行活化。

公开(公告)号：US20080207437A1

公开(公告)日：2008-08-28

申请号：US11979637

申请日：2007-11-06

申请人： Gil Mabilon ,  Patrice Marecot ,  Denis Uzio ,  Catherine Especel ,  Florence Epron

发明人： Gil Mabilon ,  Patrice Marecot ,  Denis Uzio ,  Catherine Especel ,  Florence Epron

IPC分类号： B01J23/42 ,  B01J23/46 ,  B01J27/13 ,  C07C5/00

CPC分类号： B01J23/42 ,  B01J21/04 ,  B01J23/464 ,  B01J23/89 ,  B01J37/0205 ,  B01J37/06 ,  B01J37/16 ,  C07C5/31 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2527/13 ,  C10G45/62 ,  C07C9/14

摘要： A description is given of a catalyst comprising at least one porous support, at least some platinum, and at least a second group VIII metal which is different from platinum and iridium, said catalyst having been prepared in accordance with a process comprising a) impregnation of the support with at least one solution containing a platinum precursor, b) activation in a neutral or oxidising atmosphere, at a temperature of between 120 and 800° C., c) activation in a reducing medium, at a temperature of between 0 and 800° C., d1) impregnation with an aqueous solution and d2) treatment with at least one hydrogen donor compound, at a temperature of less than 200° C., e) the impregnation of the support, which has already been impregnated with the platinum, with at least one solution containing a precursor of said second group VIII metal, and f) activation in a neutral, reducing, or oxidising atmosphere, at a temperature of between 100 and 800° C.

摘要翻译： 给出了包含至少一种多孔载体，至少一些铂和至少一种与铂和铱不同的第Ⅷ族金属的催化剂的描述，所述催化剂是按照以下方法制备的：a）将 含有至少一种含有铂前体的溶液的载体，b）在中性或氧化性气氛中在120〜800℃的温度下活化，c）在还原介质中在0〜800℃的温度下进行活化 ℃），d1）用水溶液浸渍，和d2）在低于200℃的温度下用至少一种氢供体化合物处理，e）已经浸渍有铂的载体的浸渍 与至少一种含有所述第二族VIII族金属的前体的溶液，和f）在中性，还原性或氧化性气氛中在100至800℃的温度下活化。

公开(公告)号：US5413984A

公开(公告)日：1995-05-09

申请号：US934515

申请日：1992-10-13

申请人： Patrice Marecot ,  Jacques Barbier ,  Gil Mabilon ,  Daniel Durand ,  Michel Prigent

发明人： Patrice Marecot ,  Jacques Barbier ,  Gil Mabilon ,  Daniel Durand ,  Michel Prigent

IPC分类号： B01D53/94 ,  B01J23/38 ,  B01J23/44 ,  B01J23/46 ,  B01J23/70 ,  B01J23/89 ,  B01J37/02

CPC分类号： B01J23/38 ,  B01J23/70 ,  B01J37/0205

摘要： A method for preparing multi-metal catalysts including an active phase consisting of at least two metals, A and B, which are selected from groups VIII and IB of the periodic table, and a porous support. According to the method: firstly, at least a part of the porous support is impregnated with at least one precursor of metal A; secondly, activation is performed in a neutral or oxidizing atmosphere at a temperature of 120.degree.-800.degree. C. whereafter a treatment is carried out in a reduction medium at a temperature of 0.degree.-800.degree. C.; thirdly, at least a part of the support which was previously impregnated with the precursor of metal A is impregnated with at least one precursor of metal B; and fourthly, activation is performed in a neutral or oxidizing atmosphere at a temperature of 120.degree.-800.degree. C. The catalysts thereby obtained have improved stability, particularly when subjected to high temperatures, such as when they are used as post-combustion catalysts for exhaust gases from internal combustion engines, in which case metal A is platinum or palladium and metal B is platinum, palladium or rhodium, with the proviso that B is not the same as A.

摘要翻译： PCT No.PCT / FR91 / 00969 Sec。 371日期：1992年10月13日 102（e）日期1992年10月13日PCT 1991年12月4日PCT PCT。 出版物WO92 / 11086 日期：1992年7月9日。一种制备多金属催化剂的方法，包括由至少两种选自元素周期表Ⅷ和IB的金属A和B组成的活性相和多孔载体。 根据该方法：首先，至少一部分多孔载体用至少一种金属A的前体浸渍; 其次，在中性或氧化性气氛中在120-800℃的温度下进行活化，然后在还原介质中在0-800℃的温度下进行处理。 第三，先前用金属A的前体浸渍的载体的至少一部分用至少一种金属B的前体浸渍; 第四，在中性或氧化性气氛中，在120-800℃的温度下进行活化。由此获得的催化剂具有改善的稳定性，特别是当经受高温时，例如当它们用作后燃催化剂 来自内燃机的废气，在这种情况下，金属A为铂或钯，金属B为铂，钯或铑，条件是B与A不同。

公开(公告)号：US20090191108A1

公开(公告)日：2009-07-30

申请号：US11991856

申请日：2006-09-08

申请人： Gilbert Blanchard ,  Emmanuel Rohart ,  Yvane Lendresse ,  Frederic Tronel ,  Xavier Courtois ,  Daniel Duprez ,  Sanaa Elbouazzoui ,  Patrice Marecot

发明人： Gilbert Blanchard ,  Emmanuel Rohart ,  Yvane Lendresse ,  Frederic Tronel ,  Xavier Courtois ,  Daniel Duprez ,  Sanaa Elbouazzoui ,  Patrice Marecot

IPC分类号： B01D53/56 ,  B01J23/10 ,  B01J19/00 ,  F01N3/20

CPC分类号： B01D53/9422 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/20715

摘要： A method for treating/purification a gas containing nitrogen oxides (NOx) includes conveying same through a NOx trap containing a composition based on a catalyst for oxidizing NOx into NO2 and a compound based on zirconium oxide and praseodymium oxide in a proportion of praseodymium oxide ranging from 5 wt. % to 50 wt. % of oxide; such compound may further include cerium oxide and the subject process is useful for treating the exhaust gas of a Diesel or lean mixture gasoline internal combustion engine.

摘要翻译： 一种处理/净化含有氮氧化物（NOx）的气体的方法包括通过含有基于用于将NO x氧化的催化剂的组成的NO x捕集器输送到NO 2中，并且以氧化镨和氧化镨的比例输送氧化镨范围 5重量％ ％至50重量％ ％的氧化物; 这种化合物还可以包括氧化铈，本发明方法可用于处理柴油或贫混汽油内燃机的废气。