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公开(公告)号：US20050143610A1
公开(公告)日：2005-06-30
申请号：US10748418
申请日：2003-12-30
CPC分类号： B01J29/44 , B01J2229/183 , B01J2229/20 , B01J2229/42 , C07C2/00 , C07C15/02 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/12 , C07C2523/42 , C07C2529/44
摘要： Aromatization of alkanes having one to four carbon atoms per molecule to aromatics, such as benzene, toluene and xylenes (BTX), uses a catalyst of a crystalline zeolite on which platinum has been deposited, specifically a platinum-containing ZSM-5. A byproduct of the process is a light gas fraction of methane and ethane. The use of a platinum-containing ZSM-5 catalyst in an alkane aromatization process, such as the Cyclar process, suppresses the formation of methane and increases selectivity to BTX. The high content of ethane relative to methane in the light gas fraction allows this process effluent to be a feedstream for a cracker.
摘要翻译： 每分子具有1-4个碳原子的烷烃芳族化合物，例如苯，甲苯和二甲苯（BTX）等芳族化合物，使用已沉积铂的结晶沸石催化剂，特别是含铂的ZSM-5。 该方法的副产物是甲烷和乙烷的轻质气体馏分。 在烷烃芳构化方法（如Cyclar法）中使用含铂的ZSM-5催化剂可抑制甲烷的形成，并增加对BTX的选择性。 轻质气体馏分中乙烷相对于甲烷的高含量使得该工艺流出物成为裂解器的进料流。
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2.发明申请Catalyst for aromatization of alkanes, process of making and process of using thereof 有权用于烷烃芳构化的催化剂，其制备方法及其使用方法公开(公告)号：US20050197515A1
公开(公告)日：2005-09-08
申请号：US10792319
申请日：2004-03-03
申请人： Gopalakrishnan Juttu , Robert Smith
发明人： Gopalakrishnan Juttu , Robert Smith
CPC分类号： B01J29/87 , B01J23/42 , B01J2229/20 , C07C2/76 , C07C2529/44 , C10G2400/30
摘要： A catalyst of a gallium zeolite on which platinum (Pt/Ga-ZSM-5) has been deposited may be used for aromatization of alkanes having two to six carbon atoms per molecule, such as ethane, propane, butane, etc., to aromatics, such as benzene, toluene and xylenes (BTX). The gallium zeolite contains gallium and silicon in the framework of the zeolite structure. The zeolite structure may be of MFI, FAU, TON, MFL, VPI, MEL, AEL, AFI, MWW or MOR, but preferably, the zeolite has a MFI structure, more preferably is ZSM-5 MFI zeolite. According to the IUPAC recommendations, an example of the sodium form of the zeolite would be represented as: |Nax·(H2O)z|[GaxSiyO2y+3x/2]−MFI where x=0.1-25; y=60-100; and z=0.1-10. Platinum may be deposited on the gallium zeolite by ion exchange or impregnation.
摘要翻译： 可以使用其上沉积有铂（Pt / Ga-ZSM-5）的镓沸石的催化剂用于将每分子具有2-6个碳原子的烷烃如乙烷，丙烷，丁烷等芳构化成芳族化合物 ，如苯，甲苯和二甲苯（BTX）。 镓沸石在沸石结构的框架中含有镓和硅。 沸石结构可以是MFI，FAU，TON，MFL，VPI，MEL，AEL，AFI，MWW或MOR，但优选沸石具有MFI结构，更优选ZSM-5MFI沸石。 根据IUPAC的建议，沸石钠形式的一个例子可以表示为：<？in-line-formula description =“In-line Formulas”end =“lead”？> | Na x （H 2 O 2）z H 2 y + 2 x 3 x O 2 x 3 / 2] - MFI <？in-line-formula description =“In-line Formulas”end =“tail”？>其中x = 0.1-25; y = 60-100; z = 0.1-10。 铂可以通过离子交换或浸渍沉积在镓沸石上。
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公开(公告)号：US20060140854A1
公开(公告)日：2006-06-29
申请号：US11023100
申请日：2004-12-27
CPC分类号： C01B39/06 , B01J29/04 , B01J2229/20 , C01B39/38 , C01B39/40 , Y10S423/22
摘要： This invention relates to a process for making a germanium-zeolite without using fluoride compounds. The zeolite is preferably a MFI-type structure, most preferably a ZSM-5 MFI zeolite. The germanium-zeolite is synthesized essentially in the absence of fluoride compounds from an aqueous gel containing a silica source, a germanium source, an aluminum source and a structure directing agent in the presence of an acid which does not contain fluorine, such as sulfuric acid, acetic acid, nitric acid, phosphoric acid hydrochloric acid or formic acid.
摘要翻译： 本发明涉及不使用氟化物的锗 - 沸石的制造方法。 沸石优选为MFI型结构，最优选为ZSM-5MFI沸石。 锗 - 沸石基本上在不含氟化合物的情况下由含有二氧化硅源，锗源，铝源和结构导向剂的含水凝胶中在不含氟的酸存在下合成，例如硫酸 ，乙酸，硝酸，磷酸盐酸或甲酸。
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公开(公告)号：US20050239635A1
公开(公告)日：2005-10-27
申请号：US10831729
申请日：2004-04-23
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/37 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A method of modifying a zeolite catalyst to increase para-xylene selectivity of the zeolite catalyst in toluene methylation reactions is provided. The method includes forming a slurry of a ZSM-5-type zeolite and an aqueous solution of a phosphorus compound. Water is removed from the slurry to provide a non-steamed, phosphorus treated ZSM-5 zeolite catalyst without deposition of phosphorus onto the catalyst by organophosphorus vapor deposition. The resulting non-steamed, phosphorus treated ZSM-5 zeolite catalyst has a pore volume of from 0.2 ml/g or less and provides greater than 80% para-xylene selectivity of mixed xylenes when used in toluene methylation.
摘要翻译： 提供了一种改进沸石催化剂以提高沸石催化剂在甲苯甲基化反应中的对二甲苯选择性的方法。 该方法包括形成ZSM-5型沸石的浆料和磷化合物的水溶液。 从浆液中除去水，以提供不经蒸煮的磷处理的ZSM-5沸石催化剂，而不通过有机磷气相沉积将磷沉积在催化剂上。 所得非蒸馏磷处理的ZSM-5沸石催化剂的孔体积为0.2ml / g或更低，当用于甲苯甲基化时，其混合二甲苯的对二甲苯选择性大于80％。
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公开(公告)号：US20090036723A1
公开(公告)日：2009-02-05
申请号：US11876259
申请日：2007-10-22
IPC分类号： C07C2/68
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/37 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A method of modifying a zeolite catalyst to increase para-xylene selectivity of the zeolite catalyst in toluene methylation reactions is provided. The method includes forming a slurry of a ZSM-5-type zeolite and an aqueous solution of a phosphorus compound. Water is removed from the slurry to provide a non-steamed, phosphorus treated ZSM-5 zeolite catalyst without deposition of phosphorus onto the catalyst by organophosphorus vapor deposition. The resulting non-steamed, phosphorus treated ZSM-5 zeolite catalyst has a pore volume of from 0.2 ml/g or less and provides greater than 80% para-xylene selectivity of mixed xylenes when used in toluene methylation.
摘要翻译： 提供了一种改进沸石催化剂以提高沸石催化剂在甲苯甲基化反应中的对二甲苯选择性的方法。 该方法包括形成ZSM-5型沸石的浆料和磷化合物的水溶液。 从浆液中除去水，以提供不经蒸煮的磷处理的ZSM-5沸石催化剂，而不通过有机磷气相沉积将磷沉积在催化剂上。 所得非蒸馏磷处理的ZSM-5沸石催化剂的孔体积为0.2ml / g或更低，当用于甲苯甲基化时，其混合二甲苯的对二甲苯选择性大于80％。
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公开(公告)号：US07560608B2
公开(公告)日：2009-07-14
申请号：US11876259
申请日：2007-10-22
IPC分类号： C07C2/66
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/37 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A method of modifying a zeolite catalyst to increase para-xylene selectivity of the zeolite catalyst in toluene methylation reactions is provided. The method includes forming a slurry of a ZSM-5-type zeolite and an aqueous solution of a phosphorus compound. Water is removed from the slurry to provide a non-steamed, phosphorus treated ZSM-5 zeolite catalyst without deposition of phosphorus onto the catalyst by organophosphorus vapor deposition. The resulting non-steamed, phosphorus treated ZSM-5 zeolite catalyst has a pore volume of from 0.2 ml/g or less and provides greater than 80% para-xylene selectivity of mixed xylenes when used in toluene methylation.
摘要翻译： 提供了一种改进沸石催化剂以提高沸石催化剂在甲苯甲基化反应中的对二甲苯选择性的方法。 该方法包括形成ZSM-5型沸石的浆料和磷化合物的水溶液。 从浆液中除去水，以提供不经蒸煮的磷处理的ZSM-5沸石催化剂，而不通过有机磷气相沉积将磷沉积在催化剂上。 所得非蒸馏磷处理的ZSM-5沸石催化剂的孔体积为0.2ml / g或更低，当用于甲苯甲基化时，其混合二甲苯的对二甲苯选择性大于80％。
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公开(公告)号：US07285511B2
公开(公告)日：2007-10-23
申请号：US10831729
申请日：2004-04-23
IPC分类号： B01J29/06
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/37 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A method of modifying a zeolite catalyst to increase para-xylene selectivity of the zeolite catalyst in toluene methylation reactions is provided. The method includes forming a slurry of a ZSM-5-type zeolite and an aqueous solution of a phosphorus compound. Water is removed from the slurry to provide a non-steamed, phosphorus treated ZSM-5 zeolite catalyst without deposition of phosphorus onto the catalyst by organophosphorus vapor deposition. The resulting non-steamed, phosphorus treated ZSM-5 zeolite catalyst has a pore volume of from 0.2 ml/g or less and provides greater than 80% para-xylene selectivity of mixed xylenes when used in toluene methylation.
摘要翻译： 提供了一种改进沸石催化剂以提高沸石催化剂在甲苯甲基化反应中的对二甲苯选择性的方法。 该方法包括形成ZSM-5型沸石的浆料和磷化合物的水溶液。 从浆液中除去水，以提供不经蒸煮的磷处理的ZSM-5沸石催化剂，而不通过有机磷气相沉积将磷沉积在催化剂上。 所得非蒸馏磷处理的ZSM-5沸石催化剂的孔体积为0.2ml / g或更低，当用于甲苯甲基化时，其混合二甲苯的对二甲苯选择性大于80％。
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公开(公告)号：US07060644B2
公开(公告)日：2006-06-13
申请号：US10753742
申请日：2004-01-08
CPC分类号： B01J29/46 , B01J29/064 , B01J29/42 , B01J37/16 , B01J37/18 , B01J2229/26 , B01J2229/42 , C07C2/864 , C07C2529/40 , C07C2529/44 , C07C2529/46 , Y02P20/52 , C07C15/08
摘要： A catalyst for use in aromatic alkylation, such as toluene alkylation with methanol, is comprised of a zeolite with pore size from about 5.0 to about 7.0 Å containing a hydrogenating metal. The catalyst may be used in preparing an alkyl aromatic product by providing the catalyst within a reactor. The catalyst may be contacted with an aromatic hydrocarbon and an alkylating agent in the presence of hydrogen under reaction conditions suitable for aromatic alkylation. The catalyst may also be treated to further increase its stability. This is accomplished by heating the hydrogenating metal loaded zeolite catalyst in the presence of a reducing agent prior to use in an aromatic alkylation reaction to a temperature of from about 400° C. to about 500 ° C. for about 0.5 to about 10 hours.
摘要翻译： 用于芳族烷基化的催化剂，例如用甲醇进行甲苯烷基化，由含有氢化金属的孔径为约5.0至约7.0的沸石组成。 催化剂可用于通过在反应器内提供催化剂来制备烷基芳族化合物。 催化剂可以在芳烃和烷基化剂的存在下，在适合于芳族烷基化的反应条件下与氢气接触。 还可以处理催化剂以进一步提高其稳定性。 这是通过在还原剂存在下在负载芳族烷基化反应中加热加氢金属负载的沸石催化剂至约400℃至约500℃的温度进行约0.5至约10小时来完成的。
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公开(公告)号：US07244869B2
公开(公告)日：2007-07-17
申请号：US11369385
申请日：2006-03-07
IPC分类号： C07C2/66
CPC分类号： B01J29/46 , B01J29/064 , B01J29/42 , B01J37/16 , B01J37/18 , B01J2229/26 , B01J2229/42 , C07C2/864 , C07C2529/40 , C07C2529/44 , C07C2529/46 , Y02P20/52 , C07C15/08
摘要： A catalyst for use in aromatic alkylation, such as toluene alkylation with methanol, is comprised of a zeolite with pore size from about 5.0 to about 7.0 Å containing a hydrogenating metal. The catalyst may be used in preparing an alkyl aromatic product by providing the catalyst within a reactor. The catalyst may be contacted with an aromatic hydrocarbon and an alkylating agent in the presence of hydrogen under reaction conditions suitable for aromatic alkylation. The catalyst may also be treated to further increase its stability. This is accomplished by heating the hydrogenating metal loaded zeolite catalyst in the presence of a reducing agent prior to use in an aromatic alkylation reaction to a temperature of from about 400° C. to about 500° C. for about 0.5 to about 10 hours.
摘要翻译： 用于芳族烷基化的催化剂，例如用甲醇进行甲苯烷基化，由含有氢化金属的孔径为约5.0至约7.0的沸石组成。 催化剂可用于通过在反应器内提供催化剂来制备烷基芳族化合物。 催化剂可以在芳烃和烷基化剂的存在下，在适合于芳族烷基化的反应条件下与氢气接触。 还可以处理催化剂以进一步提高其稳定性。 这是通过在还原剂存在下在负载芳族烷基化反应中加热加氢金属负载的沸石催化剂至约400℃至约500℃的温度进行约0.5至约10小时来完成的。
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公开(公告)号：US20060155155A1
公开(公告)日：2006-07-13
申请号：US11369385
申请日：2006-03-07
申请人： Ashim Ghosh , Gopalakrishnan Juttu , Pamela Harvey
发明人： Ashim Ghosh , Gopalakrishnan Juttu , Pamela Harvey
IPC分类号： C07C15/067 , C07C2/68
CPC分类号： B01J29/46 , B01J29/064 , B01J29/42 , B01J37/16 , B01J37/18 , B01J2229/26 , B01J2229/42 , C07C2/864 , C07C2529/40 , C07C2529/44 , C07C2529/46 , Y02P20/52 , C07C15/08
摘要： A catalyst for use in aromatic alkylation, such as toluene alkylation with methanol, is comprised of a zeolite with pore size from about 5.0 to about 7.0 Å containing a hydrogenating metal. The catalyst may be used in preparing an alkyl aromatic product by providing the catalyst within a reactor. The catalyst may be contacted with an aromatic hydrocarbon and an alkylating agent in the presence of hydrogen under reaction conditions suitable for aromatic alkylation. The catalyst may also be treated to further increase its stability. This is accomplished by heating the hydrogenating metal loaded zeolite catalyst in the presence of a reducing agent prior to use in an aromatic alkylation reaction to a temperature of from about 400° C. to about 500° C. for about 0.5 to about 10 hours.
摘要翻译： 用于芳族烷基化的催化剂，例如用甲醇进行甲苯烷基化，由含有氢化金属的孔径为约5.0至约7.0的沸石组成。 催化剂可用于通过在反应器内提供催化剂来制备烷基芳族化合物。 催化剂可以在芳烃和烷基化剂的存在下，在适合于芳族烷基化的反应条件下与氢气接触。 还可以处理催化剂以进一步提高其稳定性。 这是通过在还原剂存在下在负载芳族烷基化反应中加热加氢金属负载的沸石催化剂至约400℃至约500℃的温度进行约0.5至约10小时来完成的。
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