Hydrotreating process using noble metal supported catalysts
    1.
    发明授权
    Hydrotreating process using noble metal supported catalysts 失效
    使用贵金属负载催化剂的加氢处理方法

    公开(公告)号:US5152885A

    公开(公告)日:1992-10-06

    申请号:US631301

    申请日:1990-12-18

    IPC分类号: B01J23/89 B01J37/08 C10G45/10

    摘要: A process for removing heteroatoms from a hydrocarbonaceous feedstock using a catalyst composition comprised of: about 0.005 to 5.0 wt. % noble metal, about 0.5 to 5 wt. % of at least one Group VIII metal, and about 3 to 18 wt. % of a Group VI metal, and a refractory support, wherein the noble metal is incorporated into the refractory support by use of a precursor represented by ML.sub.2 when the noble metal is Pt or Pd, and ML.sub.3, when the noble metal is Rh or Ir, where M is the noble metal and L is a ligand selected from the dithiocarbamates, dithiophosphates, dithiophosphinates, xanthates, thioxanthates, and further wherein L has organo groups having a sufficient number of carbon atoms to render the noble metal complex soluble in oil.

    摘要翻译: 一种使用催化剂组合物从烃原料中除去杂原子的方法,所述催化剂组合物包含:约0.005-5.0wt。 %贵金属,约0.5〜5wt。 %的至少一种第Ⅷ族金属,和约3至18wt。 %的VI族金属和耐火载体,其中当贵金属为Pt或Pd时,使用由ML2表示的前体和ML3将贵金属掺入耐火载体中,当贵金属为Rh或Ir 其中M是贵金属,L是选自二硫代氨基甲酸盐,二硫代磷酸盐,二硫代磷酸盐,黄原酸盐,硫代黄酸盐的配体,并且其中L具有足够数目的碳原子的有机基团,以使贵金属络合物溶于油。

    Novel noble metal supported hydrotreating catalysts
    3.
    发明授权
    Novel noble metal supported hydrotreating catalysts 失效
    新型贵金属负载型加氢处理催化剂

    公开(公告)号:US5086027A

    公开(公告)日:1992-02-04

    申请号:US631303

    申请日:1990-12-18

    IPC分类号: B01J23/89 B01J37/08

    CPC分类号: B01J23/8993 B01J37/086

    摘要: A catalyst composition comprised of: about 0.005 to 5.0 wt. % noble metal, about 0.5 to 5 wt. % of at least one Group VIII metal, and about 3 to 18 wt. % of a Group VI metal, and a refractory support, wherein the noble metal is incorporated into the refractory support by use of a precursor represented by ML.sub.2 when the noble metal is Pt or Pd and ML.sub.3, when the noble metal is Rh or Ir, where M is the noble metal and L is a ligand selected from the dithiocarbamates, dithiophosphates, dithiophosphinates, xanthates, thioxanthates, and further wherein L has organo groups having a sufficient number of carbon atoms to render the noble metal complex soluble in oil.

    摘要翻译: 催化剂组合物包含:约0.005至5.0wt。 %贵金属,约0.5〜5wt。 %的至少一种第Ⅷ族金属,和约3至18wt。 %的VI族金属和耐火载体,其中当贵金属为Pt或者Pd和ML3时,当贵金属为Rh或Ir时,使用由ML2表示的前体将贵金属掺入耐火载体中, 其中M是贵金属,L是选自二硫代氨基甲酸盐,二硫代磷酸盐,二硫代磷酸盐,黄原酸盐,硫代黄酸盐的配体,并且其中L具有足够数目的碳原子的有机基团以使贵金属络合物可溶于油。

    Process for selectively removing lower molecular weight naphthenic acids
from acidic crudes
    4.
    发明授权
    Process for selectively removing lower molecular weight naphthenic acids from acidic crudes 失效
    从酸性原油中选择性除去较低分子量环烷酸的方法

    公开(公告)号:US5897769A

    公开(公告)日:1999-04-27

    申请号:US920420

    申请日:1997-08-29

    IPC分类号: C10G45/08 C10G17/00

    CPC分类号: C10G45/08

    摘要: A process for selectively removing lower molecular weight naphthenic acids from an acidic crude by treating the crude with a small pore hydrotreating catalyst at temperatures of from about 200.degree. to 370.degree. C. Removing these lower molecular weight naphthenic acids reduces the corrosive nature of acidic crudes.

    摘要翻译: 通过在约200℃至370℃的温度下用小孔加氢处理催化剂处理粗品,从酸性粗制物中选择性除去较低分子量的环烷酸的方法。去除这些较低分子量的环烷酸降低了酸性原油的腐蚀性质 。

    Three-stage process for producing ultra-clean distillate products
    5.
    发明授权
    Three-stage process for producing ultra-clean distillate products 失效
    生产超清洁馏分产品的三阶段工艺

    公开(公告)号:US5198099A

    公开(公告)日:1993-03-30

    申请号:US743958

    申请日:1991-08-12

    IPC分类号: C10G65/12

    CPC分类号: C10G65/12

    摘要: A process for producing ultra clean distillate and naphtha products wherein a distillate boiling range stream which contains heteroatoms and aromatics to subjected to three stage processing. The first stage is conventional hydrotreating, wherein the resulting effluent is further hydrotreated, but with a noble metal zeolite catalyst which is typically used for hydrocracking. The effluent from this second stage, which is now substantially free of heteroatoms, is passed to a third stage. This third stage is a hydrocracking stage, the severity of which will determine if the ultimate product will be a distillate or a naphtha.

    摘要翻译: 一种生产超清洁馏出物和石脑油产品的方法,其中含有杂原子和芳族化合物进行三段加工的馏出物沸程流。 第一阶段是常规加氢处理,其中所得流出物进一步加氢处理,但是使用通常用于加氢裂化的贵金属沸石催化剂。 现在基本上不含杂原子的来自该第二阶段的流出物被传送到第三阶段。 第三阶段是加氢裂化阶段,其严重程度将决定最终产品是馏出物还是石脑油。