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公开(公告)号：US5086027A
公开(公告)日：1992-02-04
申请号：US631303
申请日：1990-12-18
CPC分类号： B01J23/8993 , B01J37/086
摘要： A catalyst composition comprised of: about 0.005 to 5.0 wt. % noble metal, about 0.5 to 5 wt. % of at least one Group VIII metal, and about 3 to 18 wt. % of a Group VI metal, and a refractory support, wherein the noble metal is incorporated into the refractory support by use of a precursor represented by ML.sub.2 when the noble metal is Pt or Pd and ML.sub.3, when the noble metal is Rh or Ir, where M is the noble metal and L is a ligand selected from the dithiocarbamates, dithiophosphates, dithiophosphinates, xanthates, thioxanthates, and further wherein L has organo groups having a sufficient number of carbon atoms to render the noble metal complex soluble in oil.
摘要翻译： 催化剂组合物包含：约0.005至5.0wt。 ％贵金属，约0.5〜5wt。 ％的至少一种第Ⅷ族金属，和约3至18wt。 ％的VI族金属和耐火载体，其中当贵金属为Pt或者Pd和ML3时，当贵金属为Rh或Ir时，使用由ML2表示的前体将贵金属掺入耐火载体中， 其中M是贵金属，L是选自二硫代氨基甲酸盐，二硫代磷酸盐，二硫代磷酸盐，黄原酸盐，硫代黄酸盐的配体，并且其中L具有足够数目的碳原子的有机基团以使贵金属络合物可溶于油。
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公开(公告)号：US5152885A
公开(公告)日：1992-10-06
申请号：US631301
申请日：1990-12-18
CPC分类号： B01J23/8993 , B01J37/086 , C10G45/10
摘要： A process for removing heteroatoms from a hydrocarbonaceous feedstock using a catalyst composition comprised of: about 0.005 to 5.0 wt. % noble metal, about 0.5 to 5 wt. % of at least one Group VIII metal, and about 3 to 18 wt. % of a Group VI metal, and a refractory support, wherein the noble metal is incorporated into the refractory support by use of a precursor represented by ML.sub.2 when the noble metal is Pt or Pd, and ML.sub.3, when the noble metal is Rh or Ir, where M is the noble metal and L is a ligand selected from the dithiocarbamates, dithiophosphates, dithiophosphinates, xanthates, thioxanthates, and further wherein L has organo groups having a sufficient number of carbon atoms to render the noble metal complex soluble in oil.
摘要翻译： 一种使用催化剂组合物从烃原料中除去杂原子的方法，所述催化剂组合物包含：约0.005-5.0wt。 ％贵金属，约0.5〜5wt。 ％的至少一种第Ⅷ族金属，和约3至18wt。 ％的VI族金属和耐火载体，其中当贵金属为Pt或Pd时，使用由ML2表示的前体和ML3将贵金属掺入耐火载体中，当贵金属为Rh或Ir 其中M是贵金属，L是选自二硫代氨基甲酸盐，二硫代磷酸盐，二硫代磷酸盐，黄原酸盐，硫代黄酸盐的配体，并且其中L具有足够数目的碳原子的有机基团，以使贵金属络合物溶于油。
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公开(公告)号：US5910242A
公开(公告)日：1999-06-08
申请号：US920701
申请日：1997-08-29
摘要： A process for reducing the total acid number of an acidic crude by treating the crude with hydrogen treat gas in the presence of a hydrotreating catalyst wherein the treat gas also contains hydrogen sulfide.
摘要翻译： 一种通过在加氢处理催化剂存在下用氢处理气体处理粗品来降低酸性粗品的总酸值的方法，其中处理气体还含有硫化氢。
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公开(公告)号：US5406016A
公开(公告)日：1995-04-11
申请号：US73026
申请日：1993-06-07
IPC分类号： C07C6/12 , C10G35/095 , C07C5/52
CPC分类号： C10G35/095 , C07C6/126
摘要： A process for simultaneously converting benzene to predominantly methylbenzenes and reducing the concentration of C.sub.10 + alkyl aromatics in a naphtha boiling range refinery process stream containing both benzene and C.sub.10 + alkyl aromatics by contacting the stream at effective temperatures and pressures with a 12-ring zeolitic material.
摘要翻译： 一种同时将苯转化为主要甲基苯的方法，并通过在有效温度和压力下与12环沸石材料接触流，在含有苯和C 10 +烷基芳族化合物的石脑油沸程炼油厂工艺流中降低C10 +烷基芳族化合物的浓度。
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公开(公告)号：US08067331B2
公开(公告)日：2011-11-29
申请号：US12091322
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
IPC分类号： C10G45/04
CPC分类号： B01J23/888 , B01J23/002 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/202 , B01J2523/69 , B01J2523/847 , B01J2523/68 , B01J2523/56
摘要： The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.
摘要翻译： 本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。 该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属 化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。
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公开(公告)号：US06245709B1
公开(公告)日：2001-06-12
申请号：US08918531
申请日：1997-08-22
IPC分类号： B01J2340
CPC分类号： C10G73/44 , B01J21/12 , B01J23/755 , B01J35/0026 , B01J35/1019 , B01J35/1038 , C10G1/002 , C10G45/60 , C10G47/12 , C10G65/00
摘要： Nickel-copper catalysts supported on an amorphous silica-alumina acidic carrier, preferably containing a binder, and having an iso-electric point of ≧6.5 are used to hydroisomerize paraffins, particularly Fischer-Tropsch paraffins, boiling at 350° F.+ into lighter, more valuable products.
摘要翻译： 负载在无定形二氧化硅 - 氧化铝酸性载体上的镍铜催化剂，优选含有粘合剂，并且具有> = 6.5的等电点，用于将在350°F +沸腾的石蜡，特别是费 - 托石蜡加氢异构化 更轻，更有价值的产品。
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7.发明授权
公开(公告)号：US5382715A
公开(公告)日：1995-01-17
申请号：US159099
申请日：1993-11-29
申请人： Jose M. Vargas , Kenneth L. Riley
发明人： Jose M. Vargas , Kenneth L. Riley
IPC分类号： C07C29/141 , C07C29/16 , C07C31/125
CPC分类号： C07C29/16 , C07C29/141 , C07C31/125
摘要： The hydrogenation steps and hydrofinishing steps of the cobalt catalyst oxo process for preparation of the alcohols by the hydroformylation of olefin are carried out using a nickel-molybdenum catalyst on an alumina or silica alumina support which has a phosphorous content of O.1 wt. % to 1.0 wt. % phosphorus.
摘要翻译： 通过烯烃加氢甲酰化制备醇的钴催化剂羰基方法的氢化步骤和加氢精制步骤是使用镍 - 钼催化剂在氧化铝或二氧化硅氧化铝载体上进行的，该载体的磷含量为0.1重量％ ％〜1.0wt ％磷。
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8.发明授权Process for the preparation of surface impregnated dispersed cobalt metal catalysts 失效表面浸渍分散钴金属催化剂的制备方法
公开(公告)号：US4977126A
公开(公告)日：1990-12-11
申请号：US270596
申请日：1988-11-14
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/83 , B01J23/8896 , B01J23/8913 , B01J37/0232 , C07C1/0435 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/36 , C07C2523/46 , C07C2523/75 , C07C2523/83 , C07C2523/889
摘要： A process for the preparation of catalysts wherein a catalytically effective amount of cobalt is impregnated and dispersed as a film, or layer, on the peripheral outer surface of a particulate porous inorganic oxide support, notably alumina, silica, silica-alumina and titania; particularly titania. The catalysts are prepared by spraying a bed of the fluidized particulate support particles with a liquid containing a dispersed or dissolved cobalt metal compound upon the support particles. The operation is performed at specified operating conditions.
摘要翻译： 一种制备催化剂的方法，其中催化有效量的钴以颗粒状多孔无机氧化物载体，特别是氧化铝，二氧化硅，二氧化硅 - 氧化铝和二氧化钛的外围外表面浸渍和分散为膜或层; 特别是二氧化钛。 催化剂是通过将含有分散或溶解的钴金属化合物的液体喷洒在载体颗粒上的流化颗粒载体颗粒床来制备的。 操作在指定的操作条件下进行。
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公开(公告)号：US3974096A
公开(公告)日：1976-08-10
申请号：US526306
申请日：1974-11-22
摘要： Hydrogen is produced by reacting carbon monoxide with steam at a temperature of at least 200.degree.F. in the presence of a supported catalyst containing: (1) at least one alkali metal compound derived from an acid having an ionization constant below 1 .times. 10.sup..sup.-3, (2) a metallic hydrogenation-dehydrogenation material, and (3) a halogen moiety. The ratio of metal component to alkali metal compound, each calculated on the basis of the oxide thereof, ranges from 0.0001 to about 10 parts by weight per part by weight of the alkali metal compound. The halide constituent is present in amounts in excess of about 0.01 weight %, based on total catalyst. A preferred catalyst composition comprises potassium carbonate, a mixture of cobalt and molybdenum oxides and combined chlorine contained on an alumina support.
摘要翻译： 氢气是在负载型催化剂存在下，在至少200°F的温度下使一氧化碳与蒸汽反应生成的，所述催化剂包含：（1）至少一种衍生自电离常数低于1×10 5的酸的碱金属化合物， - > 3，（2）金属氢化 - 脱氢材料，和（3）卤素部分。 基于其氧化物计算的金属组分与碱金属化合物的比率为每重量份碱金属化合物0.0001-约10重量份。 基于总催化剂，卤化物组分的存在量超过约0.01重量％。 优选的催化剂组合物包含碳酸钾，钴和钼氧化物的混合物以及氧化铝载体上所含的混合氯。
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公开(公告)号：US07229548B2
公开(公告)日：2007-06-12
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译： 一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫 并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。
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