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    Mixtures comprising branched oligomeric or polymeric compounds, and preparation and use thereof
    1.
    发明授权
    Mixtures comprising branched oligomeric or polymeric compounds, and preparation and use thereof 失效
    包含支链低聚物或聚合物的混合物及其制备和用途

    公开(公告)号：US08436072B2

    公开(公告)日：2013-05-07

    申请号：US12834373

    申请日：2010-07-12

    申请人： Gregor Herth ,  Monika Haberecht ,  Yulia Fogel ,  Francisco Javier Lopez Villanueva ,  Bernd Bruchmann

    发明人： Gregor Herth ,  Monika Haberecht ,  Yulia Fogel ,  Francisco Javier Lopez Villanueva ,  Bernd Bruchmann

    IPC分类号： C09K8/00 ,  C08F22/02 ,  C08F122/02 ,  C08F222/02

    CPC分类号： C04B24/165 ,  C04B24/2694 ,  C04B28/02 ,  C04B2103/0059 ,  C04B2103/0062 ,  C04B2103/465 ,  C08F283/01 ,  C08G63/676 ,  C08L33/064 ,  C08L71/02 ,  C09K8/035 ,  C09K8/50 ,  C09K8/508 ,  C09K8/5083 ,  C08F220/06 ,  C08F220/56 ,  C08L2666/04

    摘要： Mixtures comprising (A) at least one hydraulic or latently hydraulic binder, (B) at least one copolymer obtainable by reacting (α1) at least one ethylenically unsaturated comonomer having at least one functional group selected from COOH groups, sulfonic acid groups, nitrile groups, hydroxyalkyl groups and amino groups, or (α2) at least one (co)polymer of at least one ethylenically unsaturated comonomer having at least one functional group selected from COOH groups, sulfonic acid groups, nitrile groups, hydroxyalkyl groups and amino groups, with (β) at least one oligomeric or polymeric compound obtainable by reacting (a) at least one ethylenically unsaturated di- or polycarboxylic acid or anhydride or ester thereof with (b) at least one at least trifunctional alcohol and (c) at least one compound of the general formula I in which the variables are each defined as follows: R1 is selected from C1-C4-alkyl and hydrogen, A is the same or different and is selected from C2-C6-alkylene, n is in the range from 4 to 40, and (d) optionally at least one further compound having at least one COOH group or at least one alcoholic OH group per molecule.

    摘要翻译： 包含（A）至少一种液压或潜在水硬性粘合剂的混合物，（B）至少一种可通过（α1）至少一种具有至少一个选自COOH基团，磺酸基团，腈基团的官能团的烯属不饱和共聚单体 ，羟基烷基和氨基，或（α2）至少一种具有至少一个选自COOH基团，磺酸基团，腈基，羟基烷基和氨基的官能团的烯键式不饱和共聚单体的（共）聚合物， （β）至少一种低聚物或聚合物，其通过使（a）至少一种烯键式不饱和二元或多元羧酸或其酸酐或其酯与（b）至少一种至少三官能醇和（c）至少一种化合物 其中变量各自定义如下：R 1选自C 1 -C 4 - 烷基和氢，A相同或不同，并且选自C 2 -C 6 - 烷基 烯，n在4至40的范围内，和（d）任选地至少一种每分子具有至少一个COOH基团或至少一个醇OH基团的其它化合物。

    MIXTURES COMPRISING BRANCHED OLIGOMERIC OR POLYMERIC COMPOUNDS, AND PREPARATION AND USE THEREOF
    2.
    发明申请
    MIXTURES COMPRISING BRANCHED OLIGOMERIC OR POLYMERIC COMPOUNDS, AND PREPARATION AND USE THEREOF 失效
    包含分支的低聚物或聚合物的混合物，以及其制备和使用

    公开(公告)号：US20110015301A1

    公开(公告)日：2011-01-20

    申请号：US12834373

    申请日：2010-07-12

    申请人： Gregor HERTH ,  Monika Haberecht ,  Yulia Fogel ,  Francisco Javier Lopez Villanueva ,  Bernd Bruchmann

    发明人： Gregor HERTH ,  Monika Haberecht ,  Yulia Fogel ,  Francisco Javier Lopez Villanueva ,  Bernd Bruchmann

    IPC分类号： C09K8/46 ,  C08F22/02

    CPC分类号： C04B24/165 ,  C04B24/2694 ,  C04B28/02 ,  C04B2103/0059 ,  C04B2103/0062 ,  C04B2103/465 ,  C08F283/01 ,  C08G63/676 ,  C08L33/064 ,  C08L71/02 ,  C09K8/035 ,  C09K8/50 ,  C09K8/508 ,  C09K8/5083 ,  C08F220/06 ,  C08F220/56 ,  C08L2666/04

    摘要： Mixtures comprising (A) at least one hydraulic or latently hydraulic binder, (B) at least one copolymer obtainable by reacting (α1) at least one ethylenically unsaturated comonomer having at least one functional group selected from COOH groups, sulfonic acid groups, nitrile groups, hydroxyalkyl groups and amino groups, or (α2) at least one (co)polymer of at least one ethylenically unsaturated comonomer having at least one functional group selected from COOH groups, sulfonic acid groups, nitrile groups, hydroxyalkyl groups and amino groups, with (β) at least one oligomeric or polymeric compound obtainable by reacting (a) at least one ethylenically unsaturated di- or polycarboxylic acid or anhydride or ester thereof with (b) at least one at least trifunctional alcohol and (c) at least one compound of the general formula I in which the variables are each defined as follows:R1 is selected from C1-C4-alkyl and hydrogen,A is the same or different and is selected from C2-C6-alkylene,n is in the range from 4 to 40, and (d) optionally at least one further compound having at least one COOH group or at least one alcoholic OH group per molecule.

    摘要翻译： 包含（A）至少一种液压或潜在水硬性粘合剂的混合物，（B）至少一种可通过使（α1）至少一种具有选自COOH基团，磺酸基团，腈基团中的至少一个官能团的烯属不饱和共聚单体反应获得的共聚物 ，羟基烷基和氨基，或（α2）至少一种具有至少一个选自COOH基团，磺酸基团，腈基，羟基烷基和氨基的官能团的烯属不饱和共聚单体的（共）聚合物，与 （a）至少一种烯键式不饱和二元或多元羧酸或其酸酐或其酯与（b）至少一种至少三官能醇和（c）至少一种 其中变量各自定义如下：通式I的化合物：其中R 1选自C 1 -C 4烷基和氢，A相同或不同，并且选自C 2 -C 6亚烷基， n为4-40，和（d）任选地至少一种每分子具有至少一个COOH基团或至少一个醇OH基团的其它化合物。

    Highly branched polymers as cross-linking agents in microcapsule wall
    3.
    发明授权
    Highly branched polymers as cross-linking agents in microcapsule wall 有权
    高分支聚合物作为微胶囊壁中的交联剂

    公开(公告)号：US09056302B2

    公开(公告)日：2015-06-16

    申请号：US13376226

    申请日：2010-06-11

    申请人： Marc Rudolf Jung ,  Francisco Javier Lopez Villanueva ,  Tina Schroeder-Grimonpont ,  Monika Haberecht ,  Bernd Bruchmann

    发明人： Marc Rudolf Jung ,  Francisco Javier Lopez Villanueva ,  Tina Schroeder-Grimonpont ,  Monika Haberecht ,  Bernd Bruchmann

    IPC分类号： B01J13/14 ,  A61K8/11 ,  A61K8/81 ,  C09B67/02 ,  F28D20/02

    CPC分类号： B01J13/14 ,  A61K8/11 ,  A61K8/8147 ,  A61K2800/412 ,  C09B67/0097 ,  F28D20/023 ,  Y02E60/145 ,  Y10T428/2989

    摘要： The present invention relates to microcapsules comprising a capsule core and a capsule wall, obtainable by a process comprising the free-radical polymerization of an oil-in-water emulsion which comprises the following constituents: 30 to 90% by weight based on the total weight of the monomers of one or more monomers (monomers I) from the group comprising C1-C24-alkyl esters of acrylic acid and/or methacrylic acid, acrylic acid, methacrylic acid, maleic acid, fumaric acid and itaconic acid 10 to 70% by weight based on the total weight of the monomers of one or more ethylenically unsaturated crosslinkers (monomers II), where at least 10% by weight, based on the total weight of the monomers I, II and III, is a highly branched polymeric crosslinker, 0 to 30% by weight based on the total weight of the monomers of one or more monounsaturated monomers (monomer III), which are different from the monomers I, and a hydrophobic core material, to a process for their preparation and to their use.

    摘要翻译： 本发明涉及包含胶囊核心和胶囊壁的微胶囊，其通过包括以下组分的水包油乳液的自由基聚合的方法获得：基于总重量为30至90重量％ 的单体（单体I）来自包含丙烯酸和/或甲基丙烯酸的C 1 -C 24烷基酯，丙烯酸，甲基丙烯酸，马来酸，富马酸和衣康酸的单体（单体I）10至70％ 基于一种或多种烯键式不饱和交联剂（单体II）的单体的总重量，其中至少10重量％，基于单体I，II和III的总重量是高度支化的聚合物交联剂， 0〜30重量％，其与单体I不同的一种或多种单不饱和单体（单体III）和疏水性核心材料的单体的总重量相对于其制备方法及其用途。

    MICROCAPSULES HAVING HIGHLY BRANCHED POLYMERS AS CROSS-LINKING AGENTS
    4.
    发明申请
    MICROCAPSULES HAVING HIGHLY BRANCHED POLYMERS AS CROSS-LINKING AGENTS 有权
    具有高分子量聚合物作为交联剂的微胶囊

    公开(公告)号：US20120076843A1

    公开(公告)日：2012-03-29

    申请号：US13376226

    申请日：2010-06-11

    申请人： Marc Rudolf Jung ,  Francisco Javier Lopez Villanueva ,  Tina Schroeder-Grimonpont ,  Monika Haberecht ,  Bernd Bruchmann

    发明人： Marc Rudolf Jung ,  Francisco Javier Lopez Villanueva ,  Tina Schroeder-Grimonpont ,  Monika Haberecht ,  Bernd Bruchmann

    IPC分类号： B32B15/02 ,  C08L51/06 ,  A01N25/28 ,  C09D151/06 ,  C09D151/08 ,  A61K8/11 ,  C08F2/44 ,  C08L51/08

    CPC分类号： B01J13/14 ,  A61K8/11 ,  A61K8/8147 ,  A61K2800/412 ,  C09B67/0097 ,  F28D20/023 ,  Y02E60/145 ,  Y10T428/2989

    摘要： The present invention relates to microcapsules comprising a capsule core and a capsule wall, obtainable by a process comprising the free-radical polymerization of an oil-in-water emulsion which comprises the following constituents: 30 to 90% by weight based on the total weight of the monomers of one or more monomers (monomers I) from the group comprising C1-C24-alkyl esters of acrylic acid and/or methacrylic acid, acrylic acid, methacrylic acid, maleic acid, fumaric acid and itaconic acid 10 to 70% by weight based on the total weight of the monomers of one or more ethylenically unsaturated crosslinkers (monomers II), where at least 10% by weight, based on the total weight of the monomers I, II and III, is a highly branched polymeric crosslinker, 0 to 30% by weight based on the total weight of the monomers of one or more monounsaturated monomers (monomer III), which are different from the monomers I, and a hydrophobic core material, to a process for their preparation and to their use.

    摘要翻译： 本发明涉及包含胶囊核心和胶囊壁的微胶囊，其通过包括以下组分的水包油乳液的自由基聚合的方法获得：基于总重量为30至90重量％ 的单体（单体I）来自包含丙烯酸和/或甲基丙烯酸的C 1 -C 24烷基酯，丙烯酸，甲基丙烯酸，马来酸，富马酸和衣康酸的单体（单体I）10至70％ 基于一种或多种烯键式不饱和交联剂（单体II）的单体的总重量，其中至少10重量％，基于单体I，II和III的总重量是高度支化的聚合物交联剂， 0〜30重量％，其与单体I不同的一种或多种单不饱和单体（单体III）和疏水性核心材料的单体的总重量相对于其制备方法及其用途。

    Branched polyesters with sulfonate groups
    5.
    发明授权
    Branched polyesters with sulfonate groups 有权
    具有磺酸基团的支化聚酯

    公开(公告)号：US08901066B2

    公开(公告)日：2014-12-02

    申请号：US13495512

    申请日：2012-06-13

    申请人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    发明人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    IPC分类号： C11D3/37 ,  C11D1/00 ,  B08B3/04 ,  C08G63/91 ,  C02F5/10 ,  C08G63/688

    CPC分类号： C02F5/10 ,  C08G63/6884 ,  C08G63/918 ,  C11D3/378

    摘要： Branched polyesters with sulfonate groups can be obtained by reacting components A, B, optionally C, and optionally D to yield branched polyesters, then reacting these branched polyesters with hydrogen sulfite. Component A is at least one α,β-olefinically unsaturated dicarboxylic acid, component B is at least one di- or higher-functional alcohol, optional component C is at least one di- or higher-functional carboxylic acid or hydroxycarboxylic acid without an α,β-olefinically unsaturated bond, and optional component D is at least one compound of formula CH3(—O—CH2—CH2)n—OH. In reacting the branched polyesters with hydrogen sulfite, a molar amount of hydrogen sulfite is at most 95 mol %, based on an amount of α,β-olefinically unsaturated dicarboxylic acid.

    摘要翻译： 具有磺酸盐基团的支链聚酯可以通过使组分A，B，任选地C和任选的D反应得到支链聚酯，然后使这些支化聚酯与亚硫酸氢钠反应而获得。 组分A是至少一种α，β-烯属不饱和二羧酸，组分B是至少一种二官能或更高官能的醇，任选的组分C是至少一种二官能或更高官能的羧酸或羟基羧酸，没有 α，β-烯属不饱和键，任选的组分D是至少一种式CH3（-O-CH2-CH2）n-OH的化合物。 在使支化聚酯与亚硫酸氢钠反应时，基于α，α-烯属不饱和二羧酸的量，亚硫酸氢的摩尔量为至多95摩尔％。

    Alkoxylated Hyperbranched Polycarbonates for Solubilizing Poorly Soluble Active Ingredients
    6.
    发明申请
    Alkoxylated Hyperbranched Polycarbonates for Solubilizing Poorly Soluble Active Ingredients 有权
    用于溶解不良溶解活性成分的烷氧基化超支化聚碳酸酯

    公开(公告)号：US20120309629A1

    公开(公告)日：2012-12-06

    申请号：US13514332

    申请日：2010-12-03

    申请人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

    发明人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

    IPC分类号： A01N25/02 ,  A61K8/85 ,  A01P13/00 ,  C07C69/96 ,  A01P3/00 ,  A01P7/04 ,  A01P7/02 ,  A61K47/34 ,  A01P21/00

    CPC分类号： A01N25/30 ,  C08G64/0216 ,  A01N47/24

    摘要： The present invention provides a composition comprising an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, and an amphiphile comprising an alkoxylated hyperbranched polycarbonate, wherein the polycarbonate comprises an alcohol which is a trifunctional or higher polyfunctional polyetherol based on a C3-C12 alkylene oxide and an alcohol which has at least three OH groups. Likewise provided is an amphiphile comprising the polycarbonate, and a process for preparing the amphiphile. The invention further relates to the use of the amphiphile for solubilizing an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, in aqueous solutions, and a method of controlling phytopathogenic fungi and/or unwanted plant growth and/or unwanted insect or mite infestation and/or of regulating the growth of plants.

    摘要翻译： 本发明提供一种组合物，其包含其在20℃下在水中的溶解度不超过10g / L的活性成分和包含烷氧基化超支化聚碳酸酯的两亲物，其中所述聚碳酸酯包含三官能或更高官能度的醇 基于C3-C12环氧烷的聚醚类和具有至少三个OH基的醇。 同样提供包含聚碳酸酯的两亲物和制备两亲物的方法。 本发明还涉及两亲物在水溶液中溶解在20℃下在水中的溶解度不超过10g / L的活性成分的用途，以及控制植物病原真菌和/或不需要的植物生长的方法 和/或不期望的昆虫或螨虫侵袭和/或调节植物的生长。

    HIGH-FUNCTIONALITY POLYETHEROLS AND PREPARATION AND USE THEREOF
    10.
    发明申请
    HIGH-FUNCTIONALITY POLYETHEROLS AND PREPARATION AND USE THEREOF 有权
    高功能聚醚及其制备及其用途

    公开(公告)号：US20120095162A1

    公开(公告)日：2012-04-19

    申请号：US13273619

    申请日：2011-10-14

    申请人： Bernd BRUCHMANN ,  Anna Cristadoro ,  Oihana Elizalde ,  Angelika Maria Steinbrecher ,  Monika Haberecht

    发明人： Bernd BRUCHMANN ,  Anna Cristadoro ,  Oihana Elizalde ,  Angelika Maria Steinbrecher ,  Monika Haberecht

    IPC分类号： C09D179/04 ,  C08G73/06

    CPC分类号： C08G18/5063 ,  C08G18/792 ,  C09D175/08

    摘要： The present invention relates to a process for preparing high-functionality polyethers having a Hazen color number of less than 500, by converting tris(hydroxyethyl) isocyanurate (THEIC) and one or more difunctional alcohols and/or modifying reagents with the aid of acidic catalysts. The present invention further relates to high-functionality polyethers having a color number of less than 10, obtainable by such a process, and to the use of these high-functionality polyethers as adhesion promoters, thixotropic agents, rheology modifiers of polymers, in printing inks, paints and coatings, or as units for preparation of polyaddition or polycondensation polymers.

    摘要翻译： 本发明涉及通过在酸性催化剂的帮助下，通过转化三（羟乙基）异氰脲酸酯（THEIC）和一种或多种双官能醇和/或改性试剂来制备Hazen色数小于500的高官能度聚醚的方法 。 本发明还涉及通过这种方法获得的颜色数小于10的高官能度聚醚，以及这些高官能度聚醚作为粘合促进剂，触变剂，聚合物的流变改性剂在印刷油墨中的用途 ，涂料和涂料，或作为制备加聚或缩聚聚合物的单元。