N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides, their use,
process for their preparation, and the intermediates
2,4-dichlorothiazole-sulphonyl chloride and
2-amino-4-chloro-thiazole-sulphonamides
    2.
    发明授权
    N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides, their use, process for their preparation, and the intermediates 2,4-dichlorothiazole-sulphonyl chloride and 2-amino-4-chloro-thiazole-sulphonamides 失效
    N-磺基化的2-氨基-4-氯 - 噻唑磺酰胺,它们的用途及其制备方法,和中间体2,4-二氯噻唑 - 磺酰氯和2-氨基-4-氯 - 噻唑 - 磺酰胺

    公开(公告)号:US4906650A

    公开(公告)日:1990-03-06

    申请号:US308180

    申请日:1989-02-08

    摘要: The fungicidally active N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another denote hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, aryl, aralkyl or an aromatic or a non-aromatic heterocyclic radical andR.sup.3 and R.sup.4 independently of one another stand for hydrogen, alkyl, cycloalkyl, aryl or aralkyl or for the dichlorohalogenomethyl-sulphenyl radical --S--CCl.sub.2 X, in which X denotes fluorine, chlorine or bromine, and where furthermore one of the pairs of substituents R.sup.1 and R.sup.3 or R.sup.2 andR.sup.4 together with the nitrogen atom which they substitute can denote morpholino or thiomorpholino, with at least one of the radicals R.sup.3 and R.sup.4 standing for the radical --S--CCl.sub.2 X,can be prepared in a process in which, in a first step, 2,4-dichloro-thiazole is reacted with chlorosulphonic acid to give 2,4-dichloro-thiazole-sulphonyl chloride, in which, in a second step, the 2,4-dichloro-thiazole-sulphonyl chloride is reacted with primary amines or with a primary and a secondary amine to give 2-amino-4-chloro-thiazole-sulphonamides, and in which, in a third step, the sulphonamides mentioned are reacted with dichlorohalogenomethylsulphenyl chlorides to give the substances of the formula (I).

    摘要翻译: 式(I)的杀真菌活性N-磺基化2-氨基-4-氯 - 噻唑 - 磺酰胺其中R 1和R 2彼此独立地表示氢,烷基,烯基,炔基,环烷基,芳基,芳烷基或 芳族或非芳香族杂环基,R 3和R 4彼此独立地代表氢,烷基,环烷基,芳基或芳烷基或二氯卤代甲基 - 磺酰基-S-CCl 2 X,其中X表示氟,氯或溴,以及 此外,取代基R 1和R 3或R 2和R 4中的一个与它们所取代的氮原子一起可以表示吗啉代或硫代吗啉基,其中R3和R4中至少一个代表基团-S-CCl 2,可以是 其中在第一步中将2,4-二氯 - 噻唑与氯磺酸反应,得到2,4-二氯 - 噻唑 - 磺酰氯,其中在第二步中,2,4-二氯 - 二氯 - 噻唑 - 磺酰氯与伯胺反应 胺或与伯胺和仲胺反应,得到2-氨基-4-氯 - 噻唑 - 磺酰胺,其中在第三步中,所述磺酰胺与二氯卤代甲基亚磺酰氯反应,得到式(I)的物质, 。

    Herbicidal thiazolecarboxamide derivatives
    4.
    发明授权
    Herbicidal thiazolecarboxamide derivatives 失效
    除草噻唑甲酰胺衍生物

    公开(公告)号:US5057142A

    公开(公告)日:1991-10-15

    申请号:US587283

    申请日:1990-09-24

    CPC分类号: C07D277/56 A01N43/78

    摘要: Herbicidal thiazolecarboxamide derivatives of the formula ##STR1## in which n represents the numbers 0 or 1,A represents in each case optionally substituted alkyl, aryl, heteroaryl, arylamino or heteroarylamino,R.sup.1 represents hydrogen, halogen or alkyl,R.sup.2 represents hydrogen, halogen or alkyl,R.sup.3 represents hydrogen, halogen, alkyl or halogenoalkyl,R.sup.4 represents hydrogen, halogen, alkyl or halogenoalkyl,R.sup.5 represents hydrogen, halogen, alkyl, nitro or amino,R.sup.6 represents hydrogen, halogen, alkyl halogenoalkyl, alkoxy, halogenoalkoxy, alkylthio, halogenoalkylthio or alkoxycarbonyl, andR.sup.7 represents hydrogen, halogen, alkyl, nitro or amino

    摘要翻译: 芳基,杂芳基,芳基氨基或杂芳基氨基,R 1表示氢,卤素或烷基,R 2表示氢原子,其中n表示数字0或1, 卤素,烷基或卤代烷基,R 5代表氢,卤素,烷基,硝基或氨基,R 6表示氢,卤素,烷基卤代烷基,烷氧基,卤代烷氧基, 烷硫基,卤代烷硫基或烷氧基羰基,R7表示氢,卤素,烷基,硝基或氨基

    Fluorinated tertiary butylamines
    5.
    发明授权
    Fluorinated tertiary butylamines 失效
    氟化叔丁胺

    公开(公告)号:US5019654A

    公开(公告)日:1991-05-28

    申请号:US27705

    申请日:1987-03-19

    CPC分类号: C07C211/15

    摘要: New fluorinated tertiary butylamines of the formula ##STR1## are prepared from halogenated pivalic acid halides by a reaction sequence which comprises preparing the fluorinated pivalic acid and decomposition of the azide to the corresponding isocyanate. The isocyanate can be converted to the fluorinated tertiary butylamine acid addition salt by acid hydrolysis or directly to the amine by treatment with base. In addition, the present amines can be prepared by reaction of a pivalic acid amide with hypochlorite. The new butylamines can be used in the preparation of benzoic acid amides having insecticidal action.

    摘要翻译: 通过包括制备氟化新戊酸和将叠氮化物分解成相应的异氰酸酯的反应顺序由卤代新戊酸卤化物制备式“IMAGE”的新的氟化叔丁胺。 异氰酸酯可以通过酸水解转化为氟化叔丁胺酸加成盐,或通过用碱处理直接转化成胺。 此外,本发明的胺可以通过新戊酸酰胺与次氯酸盐的反应来制备。 新的丁胺可用于制备具有杀虫作用的苯甲酸酰胺。

    Substituted benzimidazoles
    10.
    发明授权
    Substituted benzimidazoles 失效
    取代的苯并咪唑

    公开(公告)号:US5863933A

    公开(公告)日:1999-01-26

    申请号:US822565

    申请日:1997-03-19

    摘要: The invention relates to new substituted benzimidazole of the general formula (I) ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkoxy or optionally substituted aryl,R.sup.2 represents hydroxyl, cyano or in each case optionally substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkinyloxy, alkylthio, amino, aminocarbonyl, alkylcarbonyl, alkoxycarbonyl, alkoxycarbonyloxy, dialkoxyphosphonyl, (hetero)aryl, (hetero)arylcarbonyl, (hetero)aryloxycarbonyl, (hetero)arylcarbonyloxy or (hetero)arylaminocarbonylaminocarbonyloxy, andR.sup.3 represents fluoroalkyl,X.sup.1, X.sup.2, X.sup.3 and X.sup.4 independently of one another in each case represent hydrogen, halogen, cyano, nitro, in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl or cycloalkyl, optionally substituted, fused dioxyalkylene, or represent hydroxycarbonyl, alkylcarbonyl, alkoxycarbonyl or cycloalkyloxycarbonyl, in each case optionally substituted amino or aminocarbonyl or in each case optionally substituted aryl, aryloxy, arylthio, arylsulphinyl, arylsulphonyl, arylsulphonyloxy, arylcarbonyl, aryloxycarbonyl, arylazo or arylthiomethylsulphonyl, but where at least one of the substituents X.sup.1, X.sup.2, X.sup.3 or X.sup.4 represents halogenoalkyl, with the exception of the chloromethyl radical, halogenoalkoxy, halogenoalkylthio, halogenoalkylsulphinyl, halogenoalkylsulphonyl or alkylsulphonyl, optionally substituted, fused dioxyalkylene, or represent hydroxycarbonyl, alkylcarbonyl, alkoxycarbonyl or cycloalkyloxycarbonyl, in each case optionally substituted amino or aminocarbonyl, or in each case optionally substituted aryl, arylthio, arylsulphinyl, arylsulphonyl, arylsulphonyloxy, arylcarbonyl, aryloxycarbonyl, arylazo or arylthiomethylsulphonyl,their preparation and use as pesticides, and intermediates for their preparation.

    摘要翻译: 本发明涉及通式(I)的新取代的苯并咪唑,其中R 1表示氢,烷基,烷氧基或任选取代的芳基,R 2表示羟基,氰基或在各种情况下任选取代的烷基,烯基,炔基 (杂)芳基羰基,(杂)芳基羰基氧基或(杂)芳基氨基羰基氨基羰基氧基,R3代表氟代烷基,芳基羰氧基, 在各种情况下,X1,X2,X3和X4彼此独立地表示氢,卤素,氰基,硝基,在各种情况下均为任选取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基或环烷基,任选取代的稠合二氧亚烷基,或代表羟基羰基 ,烷基羰基,烷氧基羰基或环烷氧基羰基,在每种情况下均为任选取代的氨基或氨基羰基,或在每种情况下任选取代 芳基,芳氧基,芳硫基,芳基亚磺酰基,芳基磺酰基,芳基磺酰氧基,芳基羰基,芳氧基羰基,芳基偶氮或芳基硫代甲基磺酰基,但其中至少一个取代基X1,X2,X3或X4表示卤代烷基,除了氯甲基,卤代烷氧基,卤代烷硫基 ,卤代烷基亚磺酰基,卤代烷基磺酰基或烷基磺酰基,任选取代的稠合的二氧亚烷基,或代表羟基羰基,烷基羰基,烷氧基羰基或环烷氧基羰基,在各种情况下均为任选取代的氨基或氨基羰基,或在每种情况下均为任选取代的芳基,芳硫基,芳基亚磺酰基,芳基磺酰基,芳基磺酰氧基,芳基羰基, 芳氧基羰基,芳基偶氮或芳基硫代甲基磺酰基,它们的制备和用作农药,以及其制备中间体。