Abstract:
Carbamido alkyl phosphinic acid alkyl esters are obtained by reacting alkyl phosphonic acid mono alkyl esters with amides of unsaturated carboxylic acids. The products are useful as insecticides and as additives for plastics which render said plastics flame retardant.
Abstract:
FIBROUS MATERIALS ESSENTIALLY CONSISTING OF MIXTURE OF POLYESTERS AND CELLULOSE ARE RENDERED FIRE-PROOF BY TREATMENT WITH THE AMMONIUM SALT OF BIS-(HYDROXYMETHYL)PHOSPHINIC ACID. THIS TREATMENT IMPROVES, FURTHERMORE, THE SOFT HANDLE OF THE GOODS.
Abstract:
Detergent mixtures comprising a) an alkylsulfonic acid deriving from a light petrol and containing a sulfonic acid group per 7 carbon atoms at most, b) a low-molecular oxalkylation product of a lower alkyl amine and c) a phosphate of alkanols of 4 to 8 carbon atoms are useful as wetting agents for alkaline baths.
Abstract:
CELLULOSE FIBER MATERIASL ARE RENDERED FLAME PROOF AND FAST TO WASHING BY (A) IMPREGNATION WITH AQUEOUS BATH CONTAINING PHOSPHORIC ACID ESTERS WITH N-METHYLOL GROUPS AND, OPTIONALLY, AMINOPLAST PRECONDENSATES AND/OR AMINOPLAST CONDENSATION CATALYSTS, AND (B) SUBSEQUENT HEAT TREATMENT.
Abstract:
A process is provided for the catalytic preparation of tertiary methylphosphine oxides which comprises mixing hydroxymethylalkylphosphines with at least 1 weight % of carbon tetrachloride or carbon tetrabromide at a temperature of from -10* to +120*C, and, after the reaction is complete, isolating the tertiary methylphosphine oxide by distilling off the carbon tetrahalide.
Abstract:
A process is provided for the catalytic preparation of bis(hydroxymethyl)-methylphosphine oxide, which comprises mixing tris-(hydroxymethyl)-phosphine with at least 1 weight % of carbon tetrachloride or carbon tetrabromide at temperatures of from 10* to +120*C, and, after completed reaction, isolating the bis(hydroxymethyl)-methylphosphine oxide so obtained by distilling off the carbon tetrahalide.
Abstract:
A process is provided for the catalytic preparation of tertiary methylphosphine oxides, which comprises mixing hydrohydroxymethyl-alkylphosphines with at least 1 weight % of a carbon tetrahalide of the formula C(Hal1)(Hal2)(Hal3), Hal4, where Hal1 is fluorine, chlorine or bromine, and Hal2, Hal3 and Hal4 each is chlorine or bromine, only three of the radicals Hal1 to Hal4 being the same at temperatures of from -10* to +120*C and, after completed reaction, isolating the methylphosphine oxide of formula (I) so obtained by distilling off the carbon tetrahalide.