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公开(公告)号：US3670014A
公开(公告)日：1972-06-13
申请号：US3670014D
申请日：1969-07-16
Applicant: HOECHST AG
Inventor： FERNHOLZ HANS , SCHMIDT HANS-JOACHIM , WUNDER FRIEDRICH
IPC: B01J23/64 , C07C20060101 , C07C67/00 , C07C67/04 , C07C67/055 , C07C69/007 , C07C69/02 , C07C69/14 , C07C69/155 , C07C69/74 , C07C69/76
CPC classification number: C07C67/055 , C07C69/155
Abstract: Preparation of allyl esters of carboxylic acids in the gaseous phase by reacting propylene, oxygen and carboxylic acids at elevated temperatures in the presence of a catalyst consisting of an inert carrier and a salt of a noble metal of the 8th group of the periodic system and 0.01 to 20 per cent by weight of bismuth.
Abstract translation: 通过使丙烯，氧和羧酸在惰性载体和周期性系统的第8组的贵金属的盐存在下，在升高的温度下反应制备羧酸的烯丙酯，和0.01 至铋的20％。
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2.发明授权
公开(公告)号：US3427123A
公开(公告)日：1969-02-11
申请号：US3427123D
申请日：1967-02-24
Applicant: HOECHST AG
Inventor： FERNHOLZ HANS , SCHMIDT HANS-JOACHIM
CPC classification number: C01G55/005
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公开(公告)号：US3658888A
公开(公告)日：1972-04-25
申请号：US3658888D
申请日：1968-03-21
Applicant: HOECHST AG
Inventor： HORNIG LOTHAR , FERNHOLZ HANS , SCHMIDT HANS-JOACHIM , WUNDER FRIEDRICH , QUADFLIEG THERESE
IPC: B01J23/00 , B01J23/44 , B01J31/00 , B01J31/02 , C07B61/00 , C07C67/04 , C07C67/05 , C07C67/055 , C07C69/14 , C07C69/15 , C08F20060101
CPC classification number: C07C67/055 , C07C69/01 , C07C69/15
Abstract: VINYL ACETATE IS PREPARED FROM ETHYLENE, OXYGEN AND ACETIC ACID IN THE GASEOUS STATE IN THE PRESENCE OF PALLADIUM COMPOUNDS AND ACETATES OF METALS OF THE MAIN GROUP I AND/OR THE GROUP 2 OF THE PERIODIC TABLE BY ADDITIONALLY FEEDING TO THE REACTION ZONE SMALL AMOUNTS OF THE CATALYTICALLY ACTIVE ACETATES.
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公开(公告)号：US3468948A
公开(公告)日：1969-09-23
申请号：US3468948D
申请日：1966-01-18
Applicant: HOECHST AG
Inventor： FERNHOLZ HANS , SCHMIDT HANS-JOACHIM
IPC: A23L3/3463 , A23L3/3508 , C07C51/56 , C07C51/54
CPC classification number: C07C51/56 , A23L3/3463 , A23L3/3508 , C07C63/06 , C07C57/10
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Patent Agency Ranking5.发明授权Process for purifying and stabilizing aqueous alkali metal salt solutions of sorbic acid 失效纯化和稳定山梨酸碱金属盐水溶液的方法
公开(公告)号：US3883585A
公开(公告)日：1975-05-13
申请号：US43404274
申请日：1974-01-17
Applicant: HOECHST AG
Inventor： FERNHOLZ HANS , SCHMIDT HANS-JOACHIM , WUNDER FRIEDRICH
Abstract: Aqueous alkali metal sorbate solutions are purified and stabilized by a treatment with surface active carbon on the basis of mineral coal.
Abstract translation: 水性碱金属山梨酸盐溶液通过基于矿物煤的表面活性炭处理来纯化和稳定。
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公开(公告)号：US3865872A
公开(公告)日：1975-02-11
申请号：US32638573
申请日：1973-01-24
Applicant: HOECHST AG
Inventor： FERHOLZ HANS , SCHMIDT HANS-JOACHIM , WUNDER FRIEDRICH
Abstract: Sorbic acid is prepared by splitting the ketene/crotonic aldehyde polyester in the presence of a macro-reticulated exchange resin having a pore diameter of at least 200 A on the average and a water content of less than 20 percent by weight. The process can be carried out discontinuously or continuously with a good yield, the sorbic acid obtained having a high quality.
Abstract translation: 通过在孔径为至少200A的大网状交换树脂的存在下平均分解乙烯酮/巴豆醛聚酯并且水含量小于20重量％来制备山梨酸。 该方法可以不间断地或连续地以良好的产率进行，获得的山梨酸具有高质量。
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公开(公告)号：US3903139A
公开(公告)日：1975-09-02
申请号：US31238072
申请日：1972-12-05
Applicant: HOECHST AG
Inventor： FERNHOLZ HANS , SCHMIDT HANS-JOACHIM , WUNDER FRIEDRICH
CPC classification number: B01J31/1616 , B01J31/04 , B01J31/2234 , B01J31/2239 , B01J2231/76 , B01J2531/16 , B01J2531/56 , B01J2531/824 , C07C67/055 , Y02P20/582 , C07C69/155
Abstract: Process for the manufacture of allyl acetate in the gaseous phase from propylene, oxygen and acetic acid in the presence of a catalysts containing palladium, alkali metal acetate and a copper and/or vanadium salt of a 1,3-dicarbonyl compound.
Abstract translation: 在含有钯，碱金属乙酸盐和1,3-二羰基化合物的铜和/或钒盐的催化剂存在下，从丙烯，氧气和乙酸在气相中制造乙酸烯丙酯的方法。
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公开(公告)号：US3899539A
公开(公告)日：1975-08-12
申请号：US13794471
申请日：1971-04-27
Applicant: HOECHST AG
Inventor： FERNHOLZ HANS , WUNDER FRIEDRICH , SCHMIDT HANS-JOACHIM
Abstract: A process for the preparation of propionaldehyde by reacting carboxylic acid allyl esters in the gaseous phase, while using acid catalysts, in the presence of water.
Abstract translation: 一种通过在水相中使用酸催化剂的情况下使羧酸烯丙酯在气相中反应来制备丙醛的方法。
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公开(公告)号：US3876692A
公开(公告)日：1975-04-08
申请号：US33148573
申请日：1973-02-12
Applicant: HOECHST AG
Inventor： FERNHOLZ HANS , SCHMIDT HANS-JOACHIM , WUNDER FRIEDRICH
CPC classification number: C07C51/353 , C07C57/10
Abstract: Process for the isomerization of cis-isomeric hexadienoic acids to sorbic acid in the presence of complex compounds of the platinum metals as catalysts.
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