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1.发明授权Synthesis and use of trans-1,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers 有权反式-1,3,3,3-四氟丙烯/偏氟乙烯共聚物的合成和应用公开(公告)号：US09532567B2
公开(公告)日：2017-01-03
申请号：US14076624
申请日：2013-11-11
IPC分类号： C09K3/18 , A01N29/02 , A01N31/00 , C08F214/22 , C09D5/16 , C09D127/16 , C08L23/08
CPC分类号： A01N29/02 , A01N31/00 , C08F214/22 , C08F214/222 , C08L23/0815 , C09D5/16 , C09D5/1668 , C09D127/16 , C08F214/182 , C08F216/1408 , C08L27/16
摘要： A copolymer comprising trans-1,3,3,3-tetrafluoropropene units and vinylidene fluoride units, and methods of making the same. A method of preventing biofouling on an article of manufacture, comprising applying such copolymer to the article of manufacture. A process of preparing a surface having a surface energy of between about 20 and about 30 mJ/m2, comprising applying such a copolymer to a support. A method of preventing accumulation of ice on an article of manufacture, comprising applying such a copolymer to an article of manufacture. A method of preparing a polymer, comprising a step of adding trans-1,3,3,3-tetrafluoropropene/vinylidene fluoride copolymer as a polymer processing additive/aid to said polymer.
摘要翻译： 包含反式-1,3,3,3-四氟丙烯单元和偏二氟乙烯单元的共聚物及其制备方法。 一种防止在制品上生物污损的方法，包括将这种共聚物应用于制品。 制备具有约20至约30mJ / m 2的表面能的表面的方法，包括将这样的共聚物施加到载体上。 一种防止在制品上积聚冰的方法，包括将这种共聚物应用于制品。 一种制备聚合物的方法，包括将反式-1,3,3,3-四氟丙烯/偏二氟乙烯共聚物作为聚合物加工添加剂/助剂添加到所述聚合物中的步骤。
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2.发明申请SYNTHESIS AND USE OF TRANS-1,3,3,3-TETRAFLUOROPROPENE/VINYLIDENE FLUORIDE COPOLYMERS 审中-公开反式-1,3,3,3-四氯丙烯/乙烯基氟化物共聚物的合成与应用公开(公告)号：US20160362511A1
公开(公告)日：2016-12-15
申请号：US15246297
申请日：2016-08-24
IPC分类号： C08F214/22 , C09D127/16 , C09D5/16
CPC分类号： A01N29/02 , A01N31/00 , C08F214/22 , C08F214/222 , C08L23/0815 , C09D5/16 , C09D5/1668 , C09D127/16 , C08F214/182 , C08F216/1408 , C08L27/16
摘要： A copolymer comprising trans-1,3,3,3-tetrafluoropropene units and vinylidene fluoride units, and methods of making the same. A method of preventing biofouling on an article of manufacture, comprising applying such copolymer to the article of manufacture. A process of preparing a surface having a surface energy of between about 20 and about 30 mJ/m2, comprising applying such a copolymer to a support. A method of preventing accumulation of ice on an article of manufacture, comprising applying such a copolymer to an article of manufacture. A method of preparing a polymer, comprising a step of adding trans-1,3,3,3-tetrafluoropropene/vinylidene fluoride copolymer as a polymer processing additive/aid to said polymer.
摘要翻译： 包含反式-1,3,3,3-四氟丙烯单元和偏二氟乙烯单元的共聚物及其制备方法。 一种防止在制品上生物污损的方法，包括将这种共聚物应用于制品。 制备具有约20至约30mJ / m 2的表面能的表面的方法，包括将这样的共聚物施加到载体上。 一种防止在制品上积聚冰的方法，包括将这种共聚物应用于制品。 一种制备聚合物的方法，包括将反式-1,3,3,3-四氟丙烯/偏二氟乙烯共聚物作为聚合物加工添加剂/助剂添加到所述聚合物中的步骤。
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公开(公告)号：US20160324151A1
公开(公告)日：2016-11-10
申请号：US15211915
申请日：2016-07-15
IPC分类号： A01N29/02
CPC分类号： A01N29/02 , A01N35/02 , A01N41/12 , A01N43/08 , A01N43/20 , A01N47/08 , A01N47/14 , A01N2300/00
摘要： Fumigation compositions and methods which utilize or comprise cis-1-chloro-3,3,3-trifluoropropene in amounts and under conditions effective to produce a substantial fumigation affect and preferably are essentially free of methyl iodide and/or are essentially free of any compound having a LD50 toxicty of less than about 50 mg/kg (oral, rat).
摘要翻译： 利用或包含顺式-1-氯-3,3,3-三氟丙烯的熏蒸组合物和方法，其量和条件有效地产生显着的熏蒸影响，优选基本上不含甲基碘和/或基本上不含任何化合物 LD50毒性小于约50mg / kg（口服，大鼠）。
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4.发明申请公开(公告)号：US20140051818A1
公开(公告)日：2014-02-20
申请号：US13789381
申请日：2013-03-07
IPC分类号： C08F4/30
CPC分类号： C08F4/30 , C08F114/185
摘要： A process of synthesizing poly(2,3,3,3-tetrafluoropropene), comprising reacting 2,3,3,3-tetrafluoropropene monomers in a reaction medium in the presence of an initiator, wherein the initiator is added to the reaction medium in multiple portions at different times during the process.
摘要翻译： 一种合成聚（2,3,3,3-四氟丙烯）的方法，包括在引发剂存在下在反应介质中使2,3,3,3-四氟丙烯单体反应，其中将引发剂加入到反应介质中 在过程中不同时间的多个部分。
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公开(公告)号：US10968298B2
公开(公告)日：2021-04-06
申请号：US15937057
申请日：2018-03-27
IPC分类号： C08F214/22 , C08F214/18
摘要： Disclosed are aqueous emulsion copolymerization processes for synthesizing 2,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers having 2,3,3,3-tetrafluoropropene as the major monomer unit. The copolymerization process is performed at temperatures of from about 55° C. to about 70° C. with at least one water soluble radical initiator, with preferred initiators including Na2S2O8, K2S2O8, (NH4)2S2O8, Fe2(S2O8)3, K2S2O8/FeSO4, (NH4)2S2O8/Fe2O4, and the like, as well as combinations thereof.
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6.发明申请公开(公告)号：US20140179887A1
公开(公告)日：2014-06-26
申请号：US14099602
申请日：2013-12-06
IPC分类号： C08F4/08
CPC分类号： C08F214/22 , C08F214/18 , C08F214/182
摘要： In accordance with the present invention, aqueous emulsion polymerization processes of synthesizing 2,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers having 2,3,3,3-tetrafluoropropene as the major monomer unit are provided.
摘要翻译： 根据本发明，提供了合成具有2,3,3,3-四氟丙烯作为主要单体单元的2,3,3,3-四氟丙烯/偏二氟乙烯共聚物的水乳液聚合方法。
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公开(公告)号：US20180371133A1
公开(公告)日：2018-12-27
申请号：US15937057
申请日：2018-03-27
IPC分类号： C08F214/22 , C08F214/18
摘要： In accordance with the present invention, aqueous emulsion polymerization processes of synthesizing 2,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers having 2,3,3,3-tetrafluoropropene as the major monomer unit are provided.
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公开(公告)号：US20180343858A1
公开(公告)日：2018-12-06
申请号：US16109001
申请日：2018-08-22
IPC分类号： A01N29/02 , C09D5/16 , C08F214/22 , C09D127/16 , C08L23/08 , A01N31/00 , C08F214/18 , C08F216/14 , C08L27/16
CPC分类号： A01N29/02 , A01N31/00 , C08F214/22 , C08F214/222 , C08L23/0815 , C09D5/16 , C09D5/1668 , C09D127/16 , C08F214/182 , C08F216/1408 , C08L27/16
摘要： A copolymer comprising trans-1,3,3,3-tetrafluoropropene units and vinylidene fluoride units, and methods of making the same. A method of preventing biofouling on an article of manufacture, comprising applying such copolymer to the article of manufacture. A process of preparing a surface having a surface energy of between about 20 and about 30 mJ/m2, comprising applying such a copolymer to a support. A method of preventing accumulation of ice on an article of manufacture, comprising applying such a copolymer to an article of manufacture. A method of preparing a polymer, comprising a step of adding trans-1,3,3,3-tetrafluoropropene/vinylidene fluoride copolymer as a polymer processing additive/aid to said polymer.
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9.发明申请公开(公告)号：US20160215081A1
公开(公告)日：2016-07-28
申请号：US15089505
申请日：2016-04-02
IPC分类号： C08F214/22
CPC分类号： C08F214/22 , C08F214/18 , C08F214/182
摘要： In accordance with the present invention, aqueous emulsion polymerization processes of synthesizing 2,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers having 2,3,3,3-tetrafluoropropene as the major monomer unit are provided.
摘要翻译： 根据本发明，提供了合成具有2,3,3,3-四氟丙烯作为主要单体单元的2,3,3,3-四氟丙烯/偏二氟乙烯共聚物的水乳液聚合方法。
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10.发明申请公开(公告)号：US20140142264A1
公开(公告)日：2014-05-22
申请号：US14163417
申请日：2014-01-24
IPC分类号： C08F214/22
CPC分类号： C08F214/22 , A01N29/02 , C09D5/1668 , A01N25/00 , A01N25/34
摘要： A copolymer comprising 2,3,3,3-tetrafluoropropene and vinylidene fluoride and having a surface energy of between about 20 and about 30 mJ/m2. A process of preparing a surface having a surface energy of between about 20 and about 30 mJ/m2, comprising a step of applying said copolymer to a support. A method of preventing biofouling on an article of manufacture comprising applying said copolymer to the article of manufacture. An article of manufacture that is at least partly covered with said copolymer.
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