Method of manufacturing sealed rechargeable batteries
    3.
    发明授权
    Method of manufacturing sealed rechargeable batteries 失效
    密封充电电池的制造方法

    公开(公告)号:US5131920A

    公开(公告)日:1992-07-21

    申请号:US713286

    申请日:1991-06-11

    IPC分类号: H01M4/38 H01M10/34

    摘要: The invention relates to a new method of manufacturing a sealed rechargeable alkaline battery including metal oxides as positive electrode active materials and a hydrogen absorbing alloy as a negative electrode material. The basic principle of the method is that, instead of the conventional electrochemical formation, the property of a hydrogen absorbing alloy is utilized to cause the negative electrode to absorb hydrogen to thereby achieve precharged portions within the negative electrode having a relatively larger capacity as compared with the positive electrode. Regardless of the kind of positive electrode, the method of the invention insures a broad freedom in the capacity appropriation between the positive and negative electrodes.

    摘要翻译: 本发明涉及一种包括金属氧化物作为正极活性物质和作为负极材料的吸氢合金的密封可充电碱性电池的新方法。 该方法的基本原理是,代替常规的电化学形成,利用吸氢合金的性质使负极吸收氢,从而在具有相对较大容量的负极内实现预充电部分,与 正电极。 无论正极的种类如何,本发明的方法确保了正极和负极之间的容量容限的广泛的自由度。

    Hydrogen storage alloy electrode
    4.
    发明授权
    Hydrogen storage alloy electrode 失效
    氢存储合金电极

    公开(公告)号:US5149383A

    公开(公告)日:1992-09-22

    申请号:US677572

    申请日:1991-03-29

    IPC分类号: H01M4/38

    CPC分类号: H01M4/383 Y10S420/90

    摘要: The present invention provides a hydrogen storage alloy electrode made of a pentanary or higher multi-component hydrogen storage alloy or a hydride thereof where the alloy comprises at least Zr, Mn, Cr, Ni, and M where M is one or more elements selected from V an Mo, and a major component of the alloy phase is C.sub.15 (MgCu.sub.2) type Laves phase. This hydrogen storage alloy electrode may be enhanced in its performance by subjecting the alloy after the production thereof to a homogenizing heat-treatment at a temperature of 900.degree. to 1300.degree. C. in vacuum or in an inert gaseous atmosphere.

    Method of producing hydrogen storage alloy for battery
    6.
    发明授权
    Method of producing hydrogen storage alloy for battery 失效
    电池用储氢合金的制造方法

    公开(公告)号:US5837317A

    公开(公告)日:1998-11-17

    申请号:US813889

    申请日:1997-03-07

    摘要: The present invention provides a method of producing a hydrogen storage alloy low in cobalt content which can restrains a decrease in cycle life characteristic and preservation characteristic of an alkaline storage battery when the alloy is used as a negative electrode. The method includes the following steps. An Mm-Ni system hydrogen storage alloy which has a crystal structure of CaCu.sub.5 and contains 15 atom % or less of cobalt is powdered to have an average particle diameter of 10-100 .mu.m. Then, the powdered alloy is immersed in a treatment solution at 80.degree.-130.degree. C., the treatment solution comprising an alkaline aqueous solution containing 10 g/l or more of lithium hydroxide and having a specific gravity of 1.1 or higher, and cobalt ions which is contained in the alkaline aqueous solution, thereby forming a layer containing nickel and cobalt in higher concentration than in the bulk of the powdered alloy onto the alloy surface.

    摘要翻译: 本发明提供一种低合金含量的储氢合金的制造方法,其能够抑制在将该合金用作负极时碱性蓄电池的循环寿命特性和保存特性的降低。 该方法包括以下步骤。 将具有CaCu 5的晶体结构并含有15原子%以下的钴的Mm-Ni体系的储氢合金粉碎成平均粒径为10〜100μm。 然后,将粉末状合金浸入80〜130℃的处理液中,处理液含有10g / l以上的氢氧化锂,比重为1.1以上的碱性水溶液,钴 离子,其包含在碱性水溶液中,从而在合金表面上形成含有比在粉末状合金中高的浓度的含有镍和钴的层。

    Method of producing hydrogen-storing alloy and electrode making use of
the alloy
    7.
    发明授权
    Method of producing hydrogen-storing alloy and electrode making use of the alloy 失效
    使用该合金制备储氢合金和电极的方法

    公开(公告)号:US5281390A

    公开(公告)日:1994-01-25

    申请号:US870224

    申请日:1992-04-20

    摘要: In the method of the present invention for producing a hydrogen-storing alloy, part or whole of single substance of Zr as a starting material is replaced with a ferrozirconium or a zircalloy. This method enables production of a hydrogen-storing alloy at reduced material and production costs and with high efficiency and safety of work. The alloy produced by this method has high homogeneity with no segregation. It is thus possible to obtain a hydrogen-storing alloy superior in hydrogen-storing characteristics such as hydrogen storage capacity, reaction speed, and electrode reaction efficiency in an electrolyte. It is also possible to obtain, by using this alloy, a nickel-hydrogen storage battery having a large storage capacity and capable of performing quick charging and discharging, while exhibiting longer life and higher economy.

    摘要翻译: PCT No.PCT / JP89 / 01319 Sec。 371日期1990年8月2日第 102(e)1990年8月2日PCT PCT 1989年12月28日PCT公布。 公开号WO90 / 07585 日本1990年7月12日。在本发明的制备储氢合金的方法中,作为起始原料的Zr的单一物质的一部分或全部被铁氟化锆或锆合金代替。 该方法能够以减少的材料和生产成本以及高效率和安全的工作生产储氢合金。 通过该方法制造的合金具有高均匀性,没有偏析。 因此,可以获得在电解液中的储氢能力,反应速度,电极反应效率等储氢特性优异的储氢合金。 通过使用这种合金,也可以获得具有大存储容量并能够进行快速充放电的镍氢蓄电池,同时具有更长的寿命和更高的经济性。

    Method of producing hydrogen-storing alloy from a zirconium-tin starting
material
    8.
    发明授权
    Method of producing hydrogen-storing alloy from a zirconium-tin starting material 失效
    从锆锡原料制备储氢合金的方法

    公开(公告)号:US5268143A

    公开(公告)日:1993-12-07

    申请号:US796819

    申请日:1991-11-25

    IPC分类号: C01B3/00 H01M4/38 C22C16/00

    摘要: In the method of the present invention for producing a hydrogen-storing alloy, part or whole of single substance of Zr as a starting material is replaced with a ferrozirconium or a zircalloy. This method enables production of a hydrogen-storing alloy at reduced material and production costs and with high efficiency and safety of work. The alloy produced by this method has high homogeneity with no segregation. It is thus possible to obtain a hydrogen-storing alloy superior in hydrogen-storing characteristics such as hydrogen storage capacity, reaction speed, and electrode reaction efficiency in an electrolyte. It is also possible to obtain, by using this alloy, a nickel-hydrogen storage battery having a large storage capacity and capable of performing quick charging and discharging, while exhibiting longer life and higher economy.

    摘要翻译: 在用于制造储氢合金的本发明的方法中,作为原料的Zr的单一物质的一部分或全部被铁氟化锆或锆合金代替。 该方法能够以减少的材料和生产成本以及高效率和安全的工作生产储氢合金。 通过该方法制造的合金具有高均匀性,没有偏析。 因此,可以获得在电解液中的储氢能力,反应速度,电极反应效率等储氢特性优异的储氢合金。 通过使用这种合金,也可以获得具有大存储容量并能够进行快速充放电的镍氢蓄电池,同时具有更长的寿命和更高的经济性。

    Method of producing hydrogen-storing alloy and electrode making use of
the alloy
    9.
    发明授权
    Method of producing hydrogen-storing alloy and electrode making use of the alloy 失效
    使用该合金制备储氢合金和电极的方法

    公开(公告)号:US5490970A

    公开(公告)日:1996-02-13

    申请号:US261305

    申请日:1994-06-16

    IPC分类号: C01B3/00 C22C1/02 H01M4/38

    摘要: In the method of the present invention for producing a hydrogen-storing alloy, part or whole of single substance of Zr as a starting material is replaced with a ferrozirconium or a zircalloy. This method enables production of a hydrogen-storing alloy at reduced material and production costs and with high efficiency and safety of work. The alloy produced by this method has high homogeneity with no segregation. It is thus possible to obtain a hydrogen-storing alloy superior in hydrogen-storing characteristics such as hydrogen storage capacity, reaction speed, and electrode reaction efficiency in an electrolyte. It is also possible to obtain, by using this alloy, a nickel-hydrogen storage battery having a large storage capacity and capable of performing quick charging and discharging, while exhibiting longer life and higher economy.

    摘要翻译: 在用于制造储氢合金的本发明的方法中,作为原料的Zr的单一物质的一部分或全部被铁氟化锆或锆合金代替。 该方法能够以减少的材料和生产成本以及高效率和安全的工作生产储氢合金。 通过该方法制造的合金具有高均匀性,没有偏析。 因此,可以获得在电解液中的储氢能力,反应速度,电极反应效率等储氢特性优异的储氢合金。 通过使用这种合金,也可以获得具有大存储容量并能够进行快速充放电的镍氢蓄电池,同时具有更长的寿命和更高的经济性。