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1.发明授权
公开(公告)号：US5205985A
公开(公告)日：1993-04-27
申请号：US858366
申请日：1992-03-26
IPC分类号： H01M4/38
CPC分类号： H01M4/383 , Y10S420/90
摘要： A hydrogen storage alloy preferably used for electrodes in an alkaline storage battery is provided. The alloy is of the general formula ZrMn.sub.w V.sub.x M.sub.y Ni.sub.z which comprises C15-type Laves phases having a crystal structure similar to that of MgCu.sub.2 as a main alloy phase, where M is an element selected from the group consisting of Fe and Co; w, x, y, and z are respectively the mole ratios of Mn, V, M and Ni to Zr; the conditions 0.4.ltoreq.w.ltoreq.0.8, 0.1.ltoreq.x.ltoreq.0.3, 0.ltoreq.y.ltoreq.0.2, 1.0.ltoreq.z.ltoreq.1.5 and 2.0.ltoreq.w+x+y+z.ltoreq.2.4 are satisfied.
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公开(公告)号：US5468309A
公开(公告)日：1995-11-21
申请号：US120244
申请日：1993-09-13
CPC分类号： C01B3/0031 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： A hydrogen storage alloy electrode comprising a hydrogen storage alloy having a major phase of C15 (MgCu.sub.2) type Laves phase with a composition expressed as ZrMn.sub.w M.sub.x Cr.sub.y Ni.sub.z (where M is one or more elements selected from V and Mo), or its hydride. In this formula, one composition range is 0.6.ltoreq.w.ltoreq.0.8, 0.1.ltoreq.x.ltoreq.0.3, 0
摘要翻译： 一种储氢合金电极，其包含具有表现为ZrMnwMxCryNiz（其中M为选自V和Mo中的一种或多种元素）的组成的C15（MgCu2）型Laves相的主相的储氢合金或其氢化物。 在该公式中，一个组成范围是0.6≤x≤0.8,0.1≤x≤0.3,0≤y≤0.2,0.2≤z≤5.5，另一个 组成范围为0.6≤0.08,0.1≤x≤0.3,0≤y≤0.2,0.8≤z≤2.2。
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公开(公告)号：US5480740A
公开(公告)日：1996-01-02
申请号：US197432
申请日：1994-02-16
申请人： Hajime Seri , Yasuharu Yamamura , Yoichiro Tsuji , Naoko Owada , Tsutomu Iwaki
发明人： Hajime Seri , Yasuharu Yamamura , Yoichiro Tsuji , Naoko Owada , Tsutomu Iwaki
CPC分类号： H01M4/383 , C01B3/0031 , H01M10/345 , H01M4/00 , Y02E60/124 , Y02E60/327 , Y10S420/90
摘要： A hydrogen storage alloy preferably used for electrodes in an alkaline storage battery is provided. The alloy is of the general formula ZrMn.sub.w V.sub.x Mo.sub.b M.sub.y Ni.sub.z, wherein M is at least one element selected from the group consisting of Fe and Co and 0.4.ltoreq.w.ltoreq.0.8, 0.ltoreq.x.ltoreq.0.3, 0.05.ltoreq.b.ltoreq.0.2, 0.ltoreq.y.ltoreq.0.2, 1.0.ltoreq.z.ltoreq.1.5, and 2.0.ltoreq.w+x+b+y+z.ltoreq.2.4. The alloy has C15-type Laves phases of a crystal structure similar to that of MgCu.sub.2 as a main alloy phase, and a lattice constant "a" such that 7.05 .ANG..ltoreq.a.ltoreq.7.13 .ANG..
摘要翻译： 提供优选用于碱性蓄电池中的电极的储氢合金。 该合金具有通式ZrMnwVxMobMyNiz，其中M是选自Fe和Co中的至少一种元素，0.4≤x≤0.0,0.0≤x≤0.0,0.05。 b
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公开(公告)号：US5575831A
公开(公告)日：1996-11-19
申请号：US201602
申请日：1994-02-25
申请人： Yasuharu Yamamura , Hajime Seri , Yoichiro Tsuji , Naoko Owada , Tsutomu Iwaki
发明人： Yasuharu Yamamura , Hajime Seri , Yoichiro Tsuji , Naoko Owada , Tsutomu Iwaki
CPC分类号： C22B34/22 , C22B34/14 , C22B5/04 , H01M4/383 , Y10S420/90
摘要： In a method for producing a multi-component hydrogen storage alloy including metals of zirconium or vanadium, oxides of these metals is used to produce an alloy having characteristics equivalent to that produced with pure metals. It comprises steps of calcining the raw material, wherein at least one selected from the group consisting of zirconium and vanadium is included in its oxide form, at a temperature ranging from 900.degree. C. to 1300.degree. C., mixing metal calcium with said calcined raw material, and treating the mixture with heat at a temperature ranging from the melting point of metal calcium to 1300.degree. C., under inert gas atmosphere.
摘要翻译： 在包含锆或钒的金属的多组分储氢合金的制造方法中，使用这些金属的氧化物来制造具有与纯金属相同的特性的合金。 其包括煅烧原料的步骤，其中在900℃至1300℃的温度范围内以其氧化物形式包含选自锆和钒的至少一种，将金属钙与所述煅烧 在惰性气体气氛下，在金属钙熔点至1300℃的温度范围内加热处理混合物。
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公开(公告)号：US5541018A
公开(公告)日：1996-07-30
申请号：US384809
申请日：1995-02-06
申请人： Yasuharu Yamamura , Hajime Seri , Yoichiro Tsuji , Tsutomu Iwaki
发明人： Yasuharu Yamamura , Hajime Seri , Yoichiro Tsuji , Tsutomu Iwaki
IPC分类号： H01M4/38
CPC分类号： H01M4/383 , Y10S420/90
摘要： The present invention provides a hydrogen storing alloy electrode having a large discharging capacity and a long lifetime at a high temperature. The electrode is also excellent in discharging characteristics in the early charging and discharging cycles. In one aspect of the present invention, the hydrogen storing alloy electrode is made of a hydrogen storing alloy represented by the general formula ZrMn.sub.m V.sub.x X.sub.y Ni.sub.z or a hydride thereof, wherein X is Al, Zn or W; m, x, y, and z are respectively mole ratio of Mn, V, X, and Ni to Zr: 0.4.ltoreq.m.ltoreq.0.8, 0.1.ltoreq.x.ltoreq.0.3, 1.0.ltoreq.z.ltoreq.1.5, and 2.0.ltoreq.m+x+y+z.ltoreq.2.4; when X is Al or Zn, 0
摘要翻译： 本发明提供一种放电容量大，寿命长的储氢合金电极。 该电极在早期充放电循环中的放电特性也优异。 在本发明的一个方面中，储氢合金电极由通式为ZrMnmVxXyNiz或其氢化物表示的储氢合金制成，其中X为Al，Zn或W; m，x，y和z分别是Mn，V，X和Ni与Zr的摩尔比：0.4≤0.08,0.1≤x≤0.3,0.0≤z /=1.5和2.0
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公开(公告)号：US5532076A
公开(公告)日：1996-07-02
申请号：US219697
申请日：1994-03-29
申请人： Yasuharu Yamamura , Hajime Seri , Yoichiro Tsuji , Naoko Owada , Tsutomu Iwaki
发明人： Yasuharu Yamamura , Hajime Seri , Yoichiro Tsuji , Naoko Owada , Tsutomu Iwaki
IPC分类号： H01M4/38
CPC分类号： H01M4/383 , Y10S420/90
摘要： A hydrogen storage alloy preferably used for electrodes in alkaline rechargeable battery is of the general formula: Zr.sub.1.2-a Ti.sub.a Mn.sub.v Al.sub.w Ni.sub.x M.sub.y Cr.sub.z wherein M represents at least one element selected from the group consisting of Si, Zn, Sn, Fe, Mo, Cu and Co; and wherein 0.1.ltoreq.a
摘要翻译： 优选用于碱性可再充电电池中的电极的储氢合金具有以下通式：Zr1.2-aTiaMnvAlwNixMyCrz其中M表示选自Si，Zn，Sn，Fe，Mo，Cu和Co中的至少一种元素; 并且其中0.1≤n≤1.2,0.4≤v≤1.2,0≤w≤0.3,0.8≤x≤1.0,0≤y≤0.2,0.0≤x≤0.2,0≤x≤0.6,0.0≤y≤0.0,0.0,0.0,0.0=0.0 /=z
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公开(公告)号：US5753054A
公开(公告)日：1998-05-19
申请号：US634008
申请日：1996-04-17
CPC分类号： H01M4/383 , Y10S420/90
摘要： Addition of Mo to a Zr--Mn--V--Cr--Co--Ni, a Zr--Mn--Cr--Co--Ni hydrogen storage alloy, or those including Ti as substitution for Zr improves high-rate discharge characteristics of the hydrogen storage alloy at low temperatures. The hydrogen storage alloy is of the general formula ZrMn.sub.a V.sub.b Mo.sub.c Cr.sub.d Co.sub.e Ni.sub.f, wherein 0.4.ltoreq.a.ltoreq.0.8, 0.ltoreq.b
摘要翻译： 将Mo添加到Zr-Mn-V-Cr-Co-Ni，Zr-Mn-Cr-Co-Ni储氢合金或包含Ti作为取代Zr的那些中，提高了储氢合金的高倍率放电特性 在低温下。 储氢合金是通式为ZrMnaVbMocCrdCoeNif，其中0.4
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公开(公告)号：US5879429A
公开(公告)日：1999-03-09
申请号：US827080
申请日：1997-03-26
CPC分类号： B22F1/025 , C01B3/0084 , H01M4/242 , H01M4/383 , Y02E60/327 , Y02P70/54 , Y10S420/90
摘要： A method for producing a hydrogen storage alloy electrode comprising the step of treating a hydrogen storage alloy by immersing it in an alkaline solution containing cobalt ion or copper ion at a high temperature at a stage wherein the alloy is in powder state before formed into an electrode and/or at a stage wherein the alloy has been formed into an electrode. By this treatment, a hydrogen storage alloy electrode having an excellent high-rate discharge performance at a low temperature is obtained.
摘要翻译： 一种储氢合金电极的制造方法，其特征在于，具有以下步骤：将所述储氢合金浸入含有钴离子或铜离子的碱性溶液中的高温下，在合金处于粉末状态之前，形成电极 和/或其中合金已经形成电极的阶段。 通过该处理，获得了在低温下具有优异的高倍率放电性能的储氢合金电极。
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公开(公告)号：US5837317A
公开(公告)日：1998-11-17
申请号：US813889
申请日：1997-03-07
申请人： Yoshio Moriwaki , Yoichi Izumi , Yasuharu Yamamura , Hideo Kaiya
发明人： Yoshio Moriwaki , Yoichi Izumi , Yasuharu Yamamura , Hideo Kaiya
IPC分类号： C22C1/00 , B22F1/02 , C22C1/04 , H01M4/26 , H01M4/38 , H01M10/30 , B05D7/00 , B05D3/02 , B05D3/12 , B05D5/12
CPC分类号： C22C1/0441 , B22F1/025 , H01M4/383 , Y02P70/54
摘要： The present invention provides a method of producing a hydrogen storage alloy low in cobalt content which can restrains a decrease in cycle life characteristic and preservation characteristic of an alkaline storage battery when the alloy is used as a negative electrode. The method includes the following steps. An Mm-Ni system hydrogen storage alloy which has a crystal structure of CaCu.sub.5 and contains 15 atom % or less of cobalt is powdered to have an average particle diameter of 10-100 .mu.m. Then, the powdered alloy is immersed in a treatment solution at 80.degree.-130.degree. C., the treatment solution comprising an alkaline aqueous solution containing 10 g/l or more of lithium hydroxide and having a specific gravity of 1.1 or higher, and cobalt ions which is contained in the alkaline aqueous solution, thereby forming a layer containing nickel and cobalt in higher concentration than in the bulk of the powdered alloy onto the alloy surface.
摘要翻译： 本发明提供一种低合金含量的储氢合金的制造方法，其能够抑制在将该合金用作负极时碱性蓄电池的循环寿命特性和保存特性的降低。 该方法包括以下步骤。 将具有CaCu 5的晶体结构并含有15原子％以下的钴的Mm-Ni体系的储氢合金粉碎成平均粒径为10〜100μm。 然后，将粉末状合金浸入80〜130℃的处理液中，处理液含有10g / l以上的氢氧化锂，比重为1.1以上的碱性水溶液，钴 离子，其包含在碱性水溶液中，从而在合金表面上形成含有比在粉末状合金中高的浓度的含有镍和钴的层。
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10.发明授权Composition for catalytically cleaning exhaust gas and to improve the sensitivity of sensors 失效用于催化清洁排气并提高传感器灵敏度的组合物
公开(公告)号：US5015616A
公开(公告)日：1991-05-14
申请号：US428029
申请日：1989-10-27
IPC分类号： B01J23/78 , B01J23/84 , B01J23/89 , B01J37/04 , C04B35/00 , C04B35/46 , C04B35/47 , G01N27/407
CPC分类号： G01N27/4073 , B01J37/04 , C04B35/47 , Y10S502/525
摘要： This invention provides a composition comprising a mixture or a fired product of a material of the general formula Sr.sub.(1+x)/2 La.sub.(1-x)/2 Co.sub.1-x Me.sub.x O.sub.3-.delta. (wherein Me: at least one of Fe, Mn, Cr and V; O.ltoreq.x.ltoreq.1; .delta.: loss of oxygen) and SrMeO.sub.3 (wherein Me: at least one of Ti, Zr and and Hf), and a catalyst and a multi-functional sensor using such composition. With this composition it is possible to improve the catalytic performance for cleaning exhaust gas grom combusters or internal combustion engines and to improve sensitivity or response characteristics of the sensors for detecting stoichiometric composition.
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