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公开(公告)号：US20050061462A1
公开(公告)日：2005-03-24
申请号：US10990219
申请日：2004-11-16
申请人： Hans Johansson-Vestin , Johan Nyander , Jan Nordin
发明人： Hans Johansson-Vestin , Johan Nyander , Jan Nordin
IPC分类号： C08L97/00 , D21H17/23 , D21H17/29 , D21H17/37 , D21H17/45 , D21H17/57 , D21H17/68 , D21H21/10 , D21H17/74
CPC分类号： D21H21/10 , D21H17/23 , D21H17/29 , D21H17/375 , D21H17/455 , D21H17/57 , D21H17/68 , D21H17/74
摘要： The present invention relates to an aqueous silica-containing composition comprising an anionic organic polymer having at least one aromatic group and anionic silica-based particles. The aqueous silica-containing composition contains the anionic organic polymer having at least one aromatic group and the anionic silica-based particles in an amount of at least 0.01% by weight of the total weight of the aqueous silica-containing composition. The aqueous silica-containing composition contains substantially no cellulose-reactive sizing agent and the anionic organic polymer having at least one aromatic group is not an anionic naphthalene sulphonate formaldehyde condensate. The invention further relates to methods for the preparation of the aqueous silica-containing composition and the use of the aqueous silica-composition as a drainage and retention aid in a process for the production of paper. The invention also relates to a process for the production of paper from an aqueous suspension containing cellulosic fibres, and optionally filler, in which the aqueous silica-containing composition and at least one charged organic polymer are added to the cellulosic suspension.
摘要翻译： 本发明涉及包含具有至少一个芳族基团的阴离子有机聚合物和阴离子二氧化硅基颗粒的含水二氧化硅的组合物。 含水二氧化硅的组合物含有至少一种芳族基团的阴离子有机聚合物和阴离子二氧化硅基颗粒，其量为含二氧化硅含水组合物总重量的至少0.01重量％。 含水二氧化硅的组合物基本上不含纤维素反应性施胶剂，并且具有至少一个芳族基团的阴离子有机聚合物不是阴离子萘磺酸盐甲醛缩合物。 本发明还涉及制备含水二氧化硅的组合物的方法以及二氧化硅水溶液作为生产纸的方法中的排水和助留剂的用途。 本发明还涉及从含有纤维素纤维和任选填料的含水悬浮液生产纸的方法，其中将含水二氧化硅的组合物和至少一种带电有机聚合物加入到纤维素悬浮液中。
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公开(公告)号：US07608644B2
公开(公告)日：2009-10-27
申请号：US11129251
申请日：2005-05-13
CPC分类号： D21H17/74 , D21H17/47 , D21H17/68 , D21H21/10 , D21H23/765
摘要： The present invention refers to a process for the production of paper from a suspension containing cellulosic fibers, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.
摘要翻译： 本发明涉及一种由含有纤维素纤维和任选的填料的悬浮液生产纸的方法，包括向悬浮液中加入至少一种阳离子有机聚合物和含二氧化硅的含水组合物，其中包含阴离子萘磺酸甲醛缩合物和阴离子 二氧化硅基颗粒，该组合物具有萘磺酸甲醛缩合物与二氧化硅基颗粒的重量比在0.2:1至99:1的范围内，并且含有萘磺酸甲醛缩合物和二氧化硅基颗粒的量为 至少0.01重量％，基于含水二氧化硅的组合物的总重量，条件是该组合物基本上不含纤维素反应性上浆剂。 本发明还包括含水二氧化硅的组合物和含水二氧化硅的化合物的制备方法。
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3.发明授权公开(公告)号：US07156955B2
公开(公告)日：2007-01-02
申请号：US10326316
申请日：2002-12-20
CPC分类号： D21H17/74 , D21H17/47 , D21H17/68 , D21H21/10 , D21H23/765
摘要： The present invention refers to a process for the production of paper from a suspension containing cellulosic fibers, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.
摘要翻译： 本发明涉及一种由含有纤维素纤维和任选的填料的悬浮液生产纸的方法，包括向悬浮液中加入至少一种阳离子有机聚合物和含二氧化硅的含水组合物，其中包含阴离子萘磺酸甲醛缩合物和阴离子 二氧化硅基颗粒，该组合物具有萘磺酸甲醛缩合物与二氧化硅基颗粒的重量比在0.2:1至99:1的范围内，并且含有萘磺酸甲醛缩合物和二氧化硅基颗粒的量为 至少0.01重量％，基于含水二氧化硅的组合物的总重量，条件是该组合物基本上不含纤维素反应性上浆剂。 本发明还包括含水二氧化硅的组合物和含水二氧化硅的化合物的制备方法。
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公开(公告)号：US20050209389A1
公开(公告)日：2005-09-22
申请号：US11129251
申请日：2005-05-13
申请人： Johan Nyander , Hans Johansson-Vestin , Jan Nordin , Annika Pal
发明人： Johan Nyander , Hans Johansson-Vestin , Jan Nordin , Annika Pal
CPC分类号： D21H17/74 , D21H17/47 , D21H17/68 , D21H21/10 , D21H23/765
摘要： The present invention refers to a process for the production of paper from a suspension containing cellulosic fibres, and optionally fillers, comprising adding to the suspension at least one cationic organic polymer and an aqueous silica-containing composition comprising an anionic naphthalene sulphonate formaldehyde condensate and anionic silica-based particles, the composition having a weight ratio of naphthalene sulphonate formaldehyde condensate to silica-based particles within the range of from 0.2:1 to 99:1, and containing naphthalene sulphonate formaldehyde condensate and silica-based particles in an amount of at least 0.01% by weight, based on the total weight of the aqueous silica-containing composition, and with the proviso that the composition contains substantially no cellulose-reactive sizing agent. The invention also encompasses an aqueous silica-containing composition and a method for preparation of an aqueous silica-containing compound.
摘要翻译： 本发明涉及一种由含有纤维素纤维和任选的填料的悬浮液生产纸的方法，包括向悬浮液中加入至少一种阳离子有机聚合物和含二氧化硅的含水组合物，其中包含阴离子萘磺酸甲醛缩合物和阴离子 二氧化硅基颗粒，该组合物具有萘磺酸甲醛缩合物与二氧化硅基颗粒的重量比在0.2:1至99:1的范围内，并且含有萘磺酸甲醛缩合物和二氧化硅基颗粒的量为 至少0.01重量％，基于含水二氧化硅的组合物的总重量，条件是该组合物基本上不含纤维素反应性上浆剂。 本发明还包括含水二氧化硅的组合物和含水二氧化硅的化合物的制备方法。
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公开(公告)号：US08148434B2
公开(公告)日：2012-04-03
申请号：US12946274
申请日：2010-11-15
申请人： Johan Nyander , Glenn Mankin
发明人： Johan Nyander , Glenn Mankin
IPC分类号： C01B33/141 , C01B33/20
CPC分类号： C01B33/1435 , D21H17/68 , D21H21/10 , Y10S516/928
摘要： A process for producing an aqueous silica-based sol is disclosed wherein a cationic ion exchange resin having part of its ion exchange capacity in hydrogen form is contacted with an aqueous alkali metal silicate to form a slurry having a pH from 5.0 to 11.5 and/or having particle aggregation or microgel formation corresponding to a S value up to 45%; adjusting the pH using a material comprising an aluminum compound; and separating the resin from the slurry.Silica-based sols having an S value from 15 to 25%, mole ratio Si:Al from 20:1 to 50:1, mole ratio Si:X, where X=alkali metal, from 5:1 to 17:1, SiO2 content of at least 5% by weight and containing silica-based particles having a specific surface area of at least 300 m2/g, as well as the use of such silica-based sols in producing paper are disclosed.
摘要翻译： 公开了一种生产水性二氧化硅基溶胶的方法，其中具有氢形式的部分离子交换容量的阳离子交换树脂与碱金属硅酸盐水溶液接触以形成pH为5.0至11.5的浆料和/或 具有对应于高达45％的S值的颗粒聚集或微凝胶形成; 使用包含铝化合物的材料调节pH; 并从浆料中分离树脂。 二氧化硅溶胶的S值为15〜25％，摩尔比Si:Al为20:1〜50:1，摩尔比Si:X，其中X =碱金属为5:1〜17:1，SiO2 含有至少5重量％的含有比表面积至少为300m 2 / g的二氧化硅基颗粒以及这种二氧化硅基溶胶在生产纸中的用途。
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公开(公告)号：US08252143B2
公开(公告)日：2012-08-28
申请号：US11149613
申请日：2005-06-10
申请人： Erik Sanne , Rune Kjell Andersson , Johan Nyander
发明人： Erik Sanne , Rune Kjell Andersson , Johan Nyander
摘要： The present invention relates to a filler comprising clay and cellulose derivative having a degree of substitution of net ionic groups up to about 0.65.
摘要翻译： 本发明涉及包含粘土和纤维素衍生物的填料，其具有高达约0.65的净离子基团的取代度。
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公开(公告)号：US5223591A
公开(公告)日：1993-06-29
申请号：US776366
申请日：1991-11-25
申请人： Johan Nyander , Sonny Jonsson , Bjorn Elman , Ann-Britt Pettersson , Per-Erik Sundell , Sven Gothe , Jan-Erik Nystrom
发明人： Johan Nyander , Sonny Jonsson , Bjorn Elman , Ann-Britt Pettersson , Per-Erik Sundell , Sven Gothe , Jan-Erik Nystrom
IPC分类号： C07D333/12 , C07D333/14 , C07D333/46 , C07D333/72 , C07D335/06 , C07D337/08 , C08F2/46 , C08F2/50 , C08F4/00 , C08G59/68 , C08G65/10 , G03F7/029
CPC分类号： C08G65/105 , C07D333/46 , C07D333/72 , C07D337/08 , C08F2/50 , C08G59/687 , G03F7/029
摘要： Initiators for cationic polymerization by thermal activation, photochemical activation (UV-irradiation) or activation by electron bombardment are compounds wherein a heterocyclic, aryl substituted or aryl ring is fused to a sulfonium moiety in combination with a non-nucleophilic anion. During the activation of the initiator, a carbon-sulfur bond is broken leading to formation of a sulfide and a carbonium ion within the same molecule. The carbonium ion initiates the polymerization.
摘要翻译： PCT No.PCT / SE90 / 00179 Sec。 371日期：1991年11月25日 102（e）1991年11月25日PCT PCT 1990年3月20日PCT公布。 WO90 / 11303 PCT出版物 日本1990年10月4日。用于通过热激活，光化学活化（UV照射）或通过电子轰击的活化的阳离子聚合的引发剂是其中杂环，芳基取代或芳基环与锍部分， 亲核阴离子。 在引发剂的活化过程中，碳 - 硫键断裂，导致在相同分子内形成硫化物和碳离子。 碳鎓离子引发聚合。
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公开(公告)号：US08828188B2
公开(公告)日：2014-09-09
申请号：US13560255
申请日：2012-07-27
申请人： Erik Sanne , Rune Kjell Andersson , Johan Nyander
发明人： Erik Sanne , Rune Kjell Andersson , Johan Nyander
摘要： The present invention relates to a filler comprising clay and cellulose derivative having a degree of substitution of net ionic groups up to about 0.65.
摘要翻译： 本发明涉及包含粘土和纤维素衍生物的填料，其具有高达约0.65的净离子基团的取代度。
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公开(公告)号：US20060254464A1
公开(公告)日：2006-11-16
申请号：US11430341
申请日：2006-05-09
申请人： Johan Nyander , Fredrik Solhage
发明人： Johan Nyander , Fredrik Solhage
IPC分类号： C04B28/26
摘要： The present invention relates to a drainage and retention aid composition which comprises: (g) a first anionic component which is a water-soluble anionic organic polymer; (h) a second anionic component which is a water-dispersible or branched anionic organic polymer; and (i) a third anionic component which is an anionic siliceous material; wherein the first, second and third anionic components are present in a dry matter content of from 0.01 to 50% by weight.
摘要翻译： 本发明涉及排水和助留剂组合物，其包括：（g）第一阴离子组分，其为水溶性阴离子有机聚合物; （h）第二阴离子组分，其为水分散性或支链阴离子有机聚合物; 和（i）第三阴离子组分，其为阴离子硅质材料; 其中所述第一，第二和第三阴离子组分以干物质含量为0.01至50重量％存在。
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公开(公告)号：US20050228057A1
公开(公告)日：2005-10-13
申请号：US11100683
申请日：2005-04-07
申请人： Johan Nyander , Glenn Mankin
发明人： Johan Nyander , Glenn Mankin
IPC分类号： B01F3/12 , C01B33/143 , D21H17/68 , D21H21/10
CPC分类号： C01B33/1435 , D21H17/68 , D21H21/10 , Y10S516/928
摘要： A process for producing an aqueous silica-based sol is disclosed wherein a cationic ion exchange resin having part of its ion exchange capacity in hydrogen form is contacted with an aqueous alkali metal silicate to form a slurry having a pH from 5.0 to 11.5 and/or having particle aggregation or microgel formation corresponding to a S value up to 45%; adjusting the pH using a material comprising an aluminium compound; and separating the resin from the slurry. Silica-based sols having an S value from 15 to 25%, mole ratio Si:Al from 20:1 to 50:1, mole ratio Si:X, where X=alkali metal, from 5:1 to 17:1, SiO2 content of at least 5% by weight and containing silica-based particles having a specific surface area of at least 300 m2/g, as well as the use of such silica-based sols in producing paper are also disclosed.
摘要翻译： 公开了一种生产水性二氧化硅基溶胶的方法，其中具有氢形式的部分离子交换容量的阳离子交换树脂与碱金属硅酸盐水溶液接触以形成pH为5.0至11.5的浆料和/或 具有对应于高达45％的S值的颗粒聚集或微凝胶形成; 使用包含铝化合物的材料调节pH; 并从浆料中分离树脂。 S值为15〜25％，Si:Al摩尔比为20：1〜50：1的二氧化硅溶胶，X =碱金属摩尔比为5：1〜17：1，SiO： 至少5重量％的含量为2重量％，并且含有比表面积至少为300微米2 /克的二氧化硅基颗粒，以及使用这样的 还公开了生产纸中的二氧化硅基溶胶。
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