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公开(公告)号：US3941848A
公开(公告)日：1976-03-02
申请号：US382277
申请日：1973-07-24
IPC分类号： B01J31/00 , B01J38/00 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00 , C07C45/08
CPC分类号： C07C45/50
摘要： An improvement in the process for the manufacture of predominantly straight-chain aldehydes by hydroformylation of olefinically unsaturated compounds of 2 to 20 carbon atoms with carbon monoxide and hydrogen in which, in a first stage, aqueous cobalt solutions are treated with carbon monoxide and hydrogen at temperatures of 50.degree. to 200.degree.C and pressures of 100 to 400 atmospheres in the presence of active charcoal, zeolites or basic ion exchangers which are charged with cobalt carbonyl, in a second stage cobalt carbonyl-hydride is extracted from the reaction mixtures thus obtained, at temperatures of 20.degree. to 180.degree.C and pressures of 1 to 400 atmospheres, by means of olefinically unsaturated compounds which must be water-insoluble and liquid under the conditions used, the aqueous phase is separated off and the organic phase is transferred to a third stage and in this stage, after introducing olefinically unsaturated compounds if the latter have only been used partially for the extraction, the hydroformylation is carried out at temperatures of 70.degree. to 170.degree.C and pressures of 100 to 400 atmospheres, the improvement being that the extraction in the second stage is carried out as a co-current extraction whilst maintaining turbulent flow.
摘要翻译： 通过用一氧化碳和氢气将2-20个碳原子的烯属不饱和化合物加氢甲酰化制备主要是直链醛的方法的改进，其中在第一阶段中用一氧化碳和氢处理含钴水溶液 在由此得到的反应混合物中提取在第二阶段钴羰基氢化物中，在活性炭，沸石或带有羰基钴的碱性离子交换剂存在下，在50〜200℃的温度和100〜400个大气压的压力 在20〜180℃的温度和1〜400个大气压的压力下，通过烯烃不饱和化合物，在所用的条件下必须是不溶于水和液体的，分离出水相，将有机相转移到 在第三阶段，在这一阶段，如果后者仅部分用于前者，则引入烯属不饱和化合物 牵引，加氢甲酰化在70〜170℃的温度和100〜400个大气压的压力下进行，其改进在于，在保持湍流的同时进行第二阶段的萃取。
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公开(公告)号：US4101588A
公开(公告)日：1978-07-18
申请号：US684401
申请日：1976-05-07
CPC分类号： C07C45/50 , B01J31/185 , B01J31/20 , B01J31/2404 , C07C41/56 , B01J2531/822
摘要： An improved process for the production of aliphatic or cycloaliphatic dialdehydes or acetals of the same by reaction of an aliphatic or cycloaliphatic conjugated diene with carbon monoxide and hydrogen in the presence of a rhodium catalyst which is modified with a tertiary phosphine or phosphite at a temperature of from 70.degree. to 160.degree. C and at a pressure of from 100 to 600 atmospheres, the improvement consisting in using as catalyst a rhodium complex which contains carbon monoxide, a tertiary organic phosphine or tertiary organic phosphite and a halogen atom as ligands. Aliphatic and cycloaliphatic dialdehydes or the acetals of the same are suitable for the production of the corresponding diols which may be used in the production of polymers and particularly of polyurethanes.
摘要翻译： 在铑催化剂存在下，通过脂族或脂环族共轭二烯与一氧化碳和氢气的反应生产脂族或脂环族二醛或其缩醛的改进方法，该催化剂用叔膦或亚磷酸酯在温度为 70至160℃，压力为100至600大气压，改进之处在于使用含有一氧化碳，叔有机膦或叔有机亚磷酸酯和卤素原子作为配体的铑络合物作为催化剂。 脂肪族和脂环族二醛或其缩醛适用于生产可用于生产聚合物，特别是聚氨酯的相应二醇。
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公开(公告)号：US3959385A
公开(公告)日：1976-05-25
申请号：US81168
申请日：1970-10-15
IPC分类号： C07C27/22 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/158 , C07C29/16 , C07C45/50 , C07C67/00 , C07F9/50 , C07C45/08
CPC分类号： C07C45/50 , C07C29/16 , C07F9/5004
摘要： An improved process for the production of aldehydes and alcohols by the oxo process comprising the reaction of olefinically unsaturated compounds with carbon monoxide and hydrogen at elevated temperatures and elevated pressures in the presence of carbonyl complexes of metals in Group VIII of the Periodic Table modified by trisubstituted organic phosphines and in the presence of alkali or alkaline earth metal salts of carboxylic acids, the improvement comprising the use of modifying agents which consist of trisubstituted organic phosphines containing one or more carboxylic acid groups, at least one of which is present in the form of its alkali metal or alkaline earth metal salt.
摘要翻译： 通过羰基方法生产醛和醇的改进方法包括在升高的温度和升高的压力下，烯属不饱和化合物与一氧化碳和氢气的反应，在周期表第Ⅷ族金属羰基络合物存在下，通过三取代 有机膦，并且在羧酸的碱金属或碱土金属盐的存在下，改进包括使用由含有一个或多个羧酸基团的三取代有机膦组成的改性剂，其中至少一种以 其碱金属或碱土金属盐。
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4.发明授权
公开(公告)号：US3957684A
公开(公告)日：1976-05-18
申请号：US482251
申请日：1974-06-24
摘要： Solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents are prepared by treating aqueous solutions of cobalt salts with carbon monoxide and hydrogen at a temperature of from 50.degree. to 200.degree.C and a pressure of from 50 to 500 atmospheres in the presence of solvents which are sparingly water-miscible or are water-immiscible and which have a content of cobalt carbonyl, cobalt carbonyl hydride or mixtures thereof, the starting materials and the organic solvents being passed cocurrently through a zone in which a turbulent flow is maintained. The improvement includes using n-butanol as solvent. Solutions of cobalt carbonyl and cobalt carbonyl hydride in n-butanol are suitable as catalyst solutions for oxo syntheses.
摘要翻译： 羰基钴和羰基氢化钴在有机溶剂中的溶液通过在溶剂存在下，在50至200℃的温度和50-500大气压的条件下处理钴盐与一氧化碳和氢气的水溶液来制备 其易于水混溶或与水不混溶并且具有钴羰基钴，羰基氢化钴或其混合物的含量，原料和有机溶剂并流通过维持湍流的区域。 改进之处在于使用正丁醇作为溶剂。 羰基羰基钴和羰基氢化钴在正丁醇中的溶液适合用作氧代合成的催化剂溶液。
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公开(公告)号：US3933920A
公开(公告)日：1976-01-20
申请号：US450284
申请日：1974-03-12
CPC分类号： C07C45/50
摘要： An improved process for the production of .alpha.,.omega.-dialdehydes by reaction of linear .alpha.,.omega.-diolefins having isolated double bonds with carbon monoxide and hydrogen at elevated temperature and at superatmospheric pressure in the presence of a cobalt carbonyl complex in which the improvement consists in supplying the cobalt to the reaction as cobalt carbonyl hydride dissolved in the .alpha.,.omega.-diolefin to be used or in an inert organic solvent and carrying out the reaction at a temperature of from 70.degree. to 130.degree.C.
摘要翻译： 通过在羰基钴络合物的存在下，在升高的温度和超大气压下，将分离的双键与一氧化碳和氢的线性α，ω-二烯烃反应生成α，ω-二醛的改进方法，其中改进组成 在将羰基氢化钴溶于所使用的α，ω-二烯烃或惰性有机溶剂中并在70〜130℃的温度下进行反应时，将钴作为反应物。
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公开(公告)号：US4454358A
公开(公告)日：1984-06-12
申请号：US337683
申请日：1982-01-07
IPC分类号： C07C29/132 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C27/04 , C07C29/149 , C07C29/80 , C07C29/92 , C07C31/08 , C07C67/00 , B01D3/00
CPC分类号： C07C29/80 , C07C29/149 , C07C67/08 , C07C67/36 , C07C67/54 , Y02P20/52 , Y10S203/06 , Y10S203/20
摘要： Ethanol is produced continuously via the carbonylation of methanol, by(a) carbonylating methanol, in a reactor R, in the presence of a carbonyl complex of a metal of group VIII of the periodic table and of a halogen compound,(b) separating, in a distillation column D1, the reactor discharge, into a top fraction comprising methyl acetate, methanol, dimethyl ether and an organohalogen compound, and into a bottom fraction comprising water, small quantities of acetic acid and the catalyst, if the latter is not in a fixed bed, the residence time being so adjusted that the greater part of the acetic acid reacts with the methanol present to give methyl acetate,(c) separating the top fraction from D1, in a distillation column D2, into a top fraction comprising small quantities of methyl acetate, methanol, dimethyl ether and the organo-halogen compound, and a bottom fraction comprising methyl acetate and methanol, and recycling the top fraction to reactor R,(d) distilling off, via the top of distillation column D3, the greater part of the water from the bottom fraction from D1and removing this water from circulation, and recycling to reactor R the bottom fraction consisting of small quantities of water, acetic acid and the catalyst,(e) using hydrogen to hydrogenate, in the hydrogenation reactor H, the bottom fraction from D2, in a conventional manner, to give a mixture of methanol and ethanol, and(f) separating the mixture into ethanol and methanol in a distillation column D4, and recycling the methanol to reactor R.
摘要翻译： 通过（a）在反应器R中羰基化甲醇，在周期表第VIII族金属的羰基络合物和卤素化合物的存在下，连续生产乙醇，（b）分离， 在蒸馏塔D1中，反应器排出成为包含乙酸甲酯，甲醇，二甲醚和有机卤素化合物的顶级馏分，并进入包含水，少量乙酸和催化剂的底部馏分，如果后者不在 固定床，停留时间如此调节，使得大部分乙酸与存在的甲醇反应得到乙酸甲酯，（c）将蒸馏塔D2中的顶馏分与D1分离成包含小分子的顶馏分 数量的乙酸甲酯，甲醇，二甲醚和有机卤素化合物，以及包含乙酸甲酯和甲醇的底部馏分，并将顶部馏分再循环到反应器R中，（d）通过顶部o蒸馏 f蒸馏塔D3，来自D1的底部馏分的大部分水从循环中除去，并且将反应器R再循环到由少量水，乙酸和催化剂组成的底部馏分，（e）使用氢气 以常规方式在氢化反应器H中将来自D2的塔底馏分氢化，得到甲醇和乙醇的混合物，和（f）将混合物在蒸馏塔D4中分离成乙醇和甲醇，并将甲醇再循环至 反应器
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7.发明授权
公开(公告)号：US4350572A
公开(公告)日：1982-09-21
申请号：US204637
申请日：1980-11-06
CPC分类号： C07C67/60
摘要： A process for purifying carboxylic acid esters which have been obtained by reacting olefinically unsaturated compounds with carbon monoxide and alkanols and which contain aldehydes or acetals, wherein the said esters are treated with a strongly acidic agent, with or without addition of water.
摘要翻译： 通过使烯属不饱和化合物与一氧化碳和链烷醇反应并且含有醛或缩醛而获得的羧酸酯的方法，其中所述酯用强酸性剂处理，或不加入水。
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公开(公告)号：US4305888A
公开(公告)日：1981-12-15
申请号：US813971
申请日：1977-07-08
IPC分类号： C07C55/02 , C07C51/00 , C07C55/10 , C07C55/12 , C07C55/14 , C07C55/16 , C07C55/18 , C07C55/20 , C07C55/21 , C07C67/00 , C07C209/00 , C07C211/09 , C07C87/14
摘要： A process for the manufacture of salts of alkanedicarboxylic acids of 4 to 12 carbon atoms and alkanediamines of 3 to 14 carbon atoms, comprising reacting esters of alkanols of 1 to 4 carbon atoms and alkanedicarboxylic acids of 4 to 12 carbon atoms with alkanediamines of 3 to 14 carbon atoms in stoichiometric amounts in the presence of water at an elevated temperature, with continuous removal of the alkanols formed, in which process the reaction is carried out, from the start, in the presence of the particular salt of alkanedicarboxylic acid and alkanediamine which is to be manufactured.
摘要翻译： 一种制备4至12个碳原子的链烷二羧酸盐和3至14个碳原子的烷二胺的方法，包括使1至4个碳原子的链烷醇与4至12个碳原子的烷基二羧酸酯与3个烷二胺反应 在高温存在下，在水存在下，化学计算量为14个碳原子，连续除去所形成的链烷醇，在该过程中进行反应，从一开始就在特定的烷基二羧酸和烷二胺盐存在下 将被制造。
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公开(公告)号：US4259520A
公开(公告)日：1981-03-31
申请号：US2329
申请日：1979-01-10
IPC分类号： C07C67/38
CPC分类号： C07C67/38
摘要： In a process for the preparation of butanedicarboxylic acid esters by(a) reacting butadiene or hydrocarbon mixtures containing butadiene with carbon monoxide and a C.sub.1 -C.sub.4 -alkanol in the presence of a tertiary nitrogen base and a cobalt carbonyl catalyst at from 80.degree. to 150.degree. C. under superatmospheric pressure,(b) removing the greater part of the tertiary nitrogen base together with any excess hydrocarbon and(c) reacting the resulting pentenoic acid ester, in the presence of the catalyst remaining in the reaction mixture, and in the presence of the remaining amount of tertiary nitrogen base, with carbon monoxide and a C.sub.1 - to C.sub.4 -alkanol at from 140.degree. to 200.degree. C. under superatmospheric pressure, to give the butanedicarboxylic acid ester, the improvement wherein the reaction mixture in stage c) is substantially free from dissolved butadiene or butadiene bonded to the catalyst.Butanedicarboxylic acid esters may be used for the preparation of polymers.
摘要翻译： 在（a）将叔丁基或含有丁二烯的烃混合物与一氧化碳和C 1 -C 4烷醇在叔氮碱和羰基钴催化剂存在下反应制备丁烷二羧酸酯的方法中， （b）将大部分叔氮碱与任何过量的烃一起除去，和（c）使所得戊烯酸酯在残留在反应混合物中的催化剂存在下反应，并在 在超大气压下，在140℃至200℃下存在剩余量的叔氮碱，一氧化碳和一种C 1 -C 4烷醇，得到丁烷二羧酸酯，其中阶段c中的反应混合物 ）基本上不含结合到催化剂上的溶解的丁二烯或丁二烯。 丁二羧酸酯可用于制备聚合物。
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公开(公告)号：US4258203A
公开(公告)日：1981-03-24
申请号：US58944
申请日：1979-07-19
CPC分类号： C07C67/38
摘要： Multistep process for the preparation of butanedicarboxylic acid by the hydrogenation of carbon monoxide under pressure in the presence of a cobalt carbonyl catalyst, the improvement of heating at a temperature of 250.degree. to 350.degree. C. under superatmospheric pressure the resulting aqueous solution of cobalt carbonyl hydride that has been extracted with butadiene or with mixtures thereof before using in a subsequent step of the multistep process.
摘要翻译： 通过在羰基钴催化剂存在下加压一氧化碳制备丁烷二羧酸的多步法，在超大气压下在250℃至350℃的温度下加热，得到羰基钴水溶液 氢化物，在多步骤的后续步骤中使用之前已用丁二烯或其混合物萃取。
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