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1.发明授权
公开(公告)号：US3957684A
公开(公告)日：1976-05-18
申请号：US482251
申请日：1974-06-24
摘要： Solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents are prepared by treating aqueous solutions of cobalt salts with carbon monoxide and hydrogen at a temperature of from 50.degree. to 200.degree.C and a pressure of from 50 to 500 atmospheres in the presence of solvents which are sparingly water-miscible or are water-immiscible and which have a content of cobalt carbonyl, cobalt carbonyl hydride or mixtures thereof, the starting materials and the organic solvents being passed cocurrently through a zone in which a turbulent flow is maintained. The improvement includes using n-butanol as solvent. Solutions of cobalt carbonyl and cobalt carbonyl hydride in n-butanol are suitable as catalyst solutions for oxo syntheses.
摘要翻译： 羰基钴和羰基氢化钴在有机溶剂中的溶液通过在溶剂存在下，在50至200℃的温度和50-500大气压的条件下处理钴盐与一氧化碳和氢气的水溶液来制备 其易于水混溶或与水不混溶并且具有钴羰基钴，羰基氢化钴或其混合物的含量，原料和有机溶剂并流通过维持湍流的区域。 改进之处在于使用正丁醇作为溶剂。 羰基羰基钴和羰基氢化钴在正丁醇中的溶液适合用作氧代合成的催化剂溶液。
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公开(公告)号：US3941848A
公开(公告)日：1976-03-02
申请号：US382277
申请日：1973-07-24
IPC分类号： B01J31/00 , B01J38/00 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00 , C07C45/08
CPC分类号： C07C45/50
摘要： An improvement in the process for the manufacture of predominantly straight-chain aldehydes by hydroformylation of olefinically unsaturated compounds of 2 to 20 carbon atoms with carbon monoxide and hydrogen in which, in a first stage, aqueous cobalt solutions are treated with carbon monoxide and hydrogen at temperatures of 50.degree. to 200.degree.C and pressures of 100 to 400 atmospheres in the presence of active charcoal, zeolites or basic ion exchangers which are charged with cobalt carbonyl, in a second stage cobalt carbonyl-hydride is extracted from the reaction mixtures thus obtained, at temperatures of 20.degree. to 180.degree.C and pressures of 1 to 400 atmospheres, by means of olefinically unsaturated compounds which must be water-insoluble and liquid under the conditions used, the aqueous phase is separated off and the organic phase is transferred to a third stage and in this stage, after introducing olefinically unsaturated compounds if the latter have only been used partially for the extraction, the hydroformylation is carried out at temperatures of 70.degree. to 170.degree.C and pressures of 100 to 400 atmospheres, the improvement being that the extraction in the second stage is carried out as a co-current extraction whilst maintaining turbulent flow.
摘要翻译： 通过用一氧化碳和氢气将2-20个碳原子的烯属不饱和化合物加氢甲酰化制备主要是直链醛的方法的改进，其中在第一阶段中用一氧化碳和氢处理含钴水溶液 在由此得到的反应混合物中提取在第二阶段钴羰基氢化物中，在活性炭，沸石或带有羰基钴的碱性离子交换剂存在下，在50〜200℃的温度和100〜400个大气压的压力 在20〜180℃的温度和1〜400个大气压的压力下，通过烯烃不饱和化合物，在所用的条件下必须是不溶于水和液体的，分离出水相，将有机相转移到 在第三阶段，在这一阶段，如果后者仅部分用于前者，则引入烯属不饱和化合物 牵引，加氢甲酰化在70〜170℃的温度和100〜400个大气压的压力下进行，其改进在于，在保持湍流的同时进行第二阶段的萃取。
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公开(公告)号：US4002539A
公开(公告)日：1977-01-11
申请号：US508162
申请日：1974-09-23
申请人： Max Strohmeyer , Werner Hagen , Heinz Hohenschutz
发明人： Max Strohmeyer , Werner Hagen , Heinz Hohenschutz
IPC分类号： C07C53/122 , C07C27/00 , C07C27/20 , C07C45/00 , C07C45/50 , C07C51/00 , C07C51/02 , C07C51/487 , C07C53/124 , C07C67/00 , B01D3/34
CPC分类号： C07C51/02 , C07C45/50 , C07C51/487
摘要： A process for isolating carboxylic acids from residues of the oxo reaction which are obtained as residues, on hydroformylation of ethylene or propylene, optionally after removing a part of the aldehydes produced, subsequent hydrogenation, treatment with aqueous alkali metal hydroxide solutions and subsequent distillation, wherein the residues are acidified with strong mineral acids to a pH of from 2-4, the acidified mixture not containing more than 5 parts by weight of water per part by weight of the carboxylic acids contained in the mixture, the organic phase is then separated off and the carboxylic acids are isolated therefrom by distillation at pressures below 150 mbar. The carboxylic acids obtained can be used as solvents or for the manufacture of esters.
摘要翻译： 从羰基反应的残留物中分离出羧酸的方法，其作为残余物，在乙烯或丙烯的加氢甲酰化作用下，任选地在除去一部分所生成的醛后，随后氢化，用碱金属氢氧化物水溶液处理和随后的蒸馏而获得，其中 残留物用强无机酸酸化至pH为2-4，酸化混合物不含每重量份混合物中所含的羧酸5重量份以上的水，然后将有机相分离 并且通过在低于150毫巴的压力下蒸馏分离羧酸。 所得羧酸可用作溶剂或用于制备酯。
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4.发明授权
公开(公告)号：US3932523A
公开(公告)日：1976-01-13
申请号：US542709
申请日：1975-01-20
申请人： Max Strohmeyer , Helmut Walz , Max Appl , Hans Moell , Horst Kerber , Heinz Hohenschutz
发明人： Max Strohmeyer , Helmut Walz , Max Appl , Hans Moell , Horst Kerber , Heinz Hohenschutz
CPC分类号： C07C45/50
摘要： The formation of an emulsion when working up reaction mixtures containing butyraldehydes and cobalt is avoided by a treatment with gases containing molecular oxygen in an aqueous acid medium at an elevated temperature, at least twice the amount of molecular oxygen stoichiometrically required for the oxidation of the cobalt being used per gram atom of cobalt present in the oxoreaction mixture.
摘要翻译： 在加工含有丁醛和钴的反应混合物时，通过在含水酸性介质中在高温下含有分子氧的气体处理，避免形成乳液，至少是钴氧化所需的化学计量分子量的两倍 每克原子存在于氧化反应混合物中的钴被使用。
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公开(公告)号：US4198531A
公开(公告)日：1980-04-15
申请号：US842304
申请日：1977-10-14
申请人： Franz Merger , Max Strohmeyer , Gerhard Sandrock , Heinz Hohenschutz , Ludwig Schroff , Gerhard Nestler
发明人： Franz Merger , Max Strohmeyer , Gerhard Sandrock , Heinz Hohenschutz , Ludwig Schroff , Gerhard Nestler
CPC分类号： C07C37/14
摘要： p-alkylphenols are manufactured by continuous reaction of phenol with olefins in the presence of a pulverulent polystyrenesulfonic acid ion exchanger which is suspended in the reaction mixture.
摘要翻译： 在烷基苯酚是通过苯酚与烯烃在悬浮在反应混合物中的粉状聚苯乙烯磺酸离子交换剂存在下的连续反应来制备的。
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公开(公告)号：US4173589A
公开(公告)日：1979-11-06
申请号：US844648
申请日：1977-10-25
IPC分类号： C07C45/00 , C07C45/50 , C07C45/82 , C07C47/02 , C07C49/82 , C07C67/00 , C07C45/24 , C07C45/08
CPC分类号： C07C45/50
摘要： Oxo aldehydes containing iron pentacarbonyl are purified by distilling them in the presence of air.
摘要翻译： 含有五羰基铁的氧醛通过在空气存在下蒸馏来纯化。
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公开(公告)号：US4134915A
公开(公告)日：1979-01-16
申请号：US793788
申请日：1977-05-05
申请人： Heinz Hohenschutz , Max Strohmeyer , Manfred Herr , Hans Kiefer
发明人： Heinz Hohenschutz , Max Strohmeyer , Manfred Herr , Hans Kiefer
IPC分类号： C07C231/02 , C07C20060101 , C07C67/00 , C07C231/00 , C07C233/03 , C07C102/06
CPC分类号： C07C231/02
摘要： Formamide is manufactured continuously from methyl formate and gaseous ammonia. The reaction is carried out in a reactor at from 30 to 90.degree. C, from 5 to 20% by volume of the reactor output is drawn off continuously and fed to the formamide working-up stage, and the remainder of the reactor output is cooled, in an external circuit maintained by means of a pump, to from 25 to 60.degree. C and is mixed with the amount of fresh methyl formate required for steady-state operation, after which the appropriate amount of gaseous ammonia is introduced into the stream of liquid through a jet, by the sucking-jet principle, and the stream of liquid is recycled to the reactor.
摘要翻译： 由甲酸甲酯和气态氨连续制备甲酰胺。 该反应在30-90℃的反应器中进行，5至20体积％的反应器输出连续排出，并送入甲酰胺处理阶段，反应器输出的其余部分被冷却 在通过泵保持的外部电路中，温度为25至60℃，并与稳态操作所需的新鲜甲酸甲酯的量混合，之后将适量的气态氨引入到 液体通过喷射原理通过射流，并且液体流被再循环到反应器中。
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公开(公告)号：US3983010A
公开(公告)日：1976-09-28
申请号：US547642
申请日：1975-02-06
申请人： Konrad Rauch , Hans Kiefer , Dieter Hesse , Max Strohmeyer , Heinz Hohenschutz
发明人： Konrad Rauch , Hans Kiefer , Dieter Hesse , Max Strohmeyer , Heinz Hohenschutz
CPC分类号： C07C51/44
摘要： Formic acid is isolated from mixtures containing formic acid, methyl formate, methanol and water by fractional distillation, the mixture being fed into the upper half of the distillation column and 5 to 15 theoretical plates being maintained above the feed point and 10 to 25 theoretical plates below the feed point. The formic acid is withdrawn at the bottom end of the column as an azeotrope with water, the azeotrope being in the liquid state or preferably in the vapor state.
摘要翻译： 甲酸通过分馏从含有甲酸，甲酸甲酯，甲醇和水的混合物中分离，将混合物进料到蒸馏塔的上半部分，并将5至15个理论塔板保持在进料点上方和10至25个理论塔板 低于饲料点。 甲酸在塔的底端作为与水的共沸物排出，共沸物处于液态或优选处于蒸汽状态。
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公开(公告)号：US4778929A
公开(公告)日：1988-10-18
申请号：US70963
申请日：1987-07-08
申请人： Peter Zehner , Herwig Hoffmann , Wolfgang Richter , Dieter Stuetzer , Max Strohmeyer , Helmut Walz , Erich Weippert
发明人： Peter Zehner , Herwig Hoffmann , Wolfgang Richter , Dieter Stuetzer , Max Strohmeyer , Helmut Walz , Erich Weippert
CPC分类号： C07C45/50
摘要： Olefinically unsaturated compounds are hydroformylated continuously, the olefin being passed into the lower region of the reactor, under from 1 to 40 bar and at from 50.degree. to 140.degree. C. with the aid of a rhodium complex as a catalyst in a hydroformylation reactor having a liquid reaction zone which occupies about 60-85% of the reactor volume, the gaseous products and reactants being removed from the hydroformylation reactor, the products being isolated and the major part of the remaining gas being recycled to the reactor by the cycle gas method, by a process in which from 20 to 80% by volume of the cycle gas is fed into the hydroformylation reactor above the liquid reaction zone and/or below the liquid surface in the top fourth of the liquid reaction zone.
摘要翻译： 烯化不饱和化合物连续加氢甲酰化，在加氢甲酰化反应器中借助于铑络合物作为催化剂，将烯烃在1至40巴和50至140℃下进入反应器的下部区域， 占反应器体积约60-85％的液体反应区，气态产物和反应物从加氢甲酰化反应器中除去，产物被分离，剩余气体的主要部分通过循环气体法再循环到反应器 ，其中循环气体的20至80体积％被输入到液体反应区上方的加氢甲酰化反应器和/或液体反应区顶部第四个液体表面下方的流程。
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公开(公告)号：US4709105A
公开(公告)日：1987-11-24
申请号：US932637
申请日：1986-11-19
IPC分类号： C07B61/00 , B01J23/00 , B01J23/88 , C07C27/00 , C07C29/14 , C07C29/141 , C07C31/02 , C07C67/00 , C07C31/125
CPC分类号： C07C29/141
摘要： Preparation of C.sub.3 - to C.sub.25 -alkanols by catalytic hydrogenation of corresponding crude C.sub.3 - to C.sub.25 -alkanols, as obtained in the cobalt-catalyzed hydroformylation of C.sub.2 - to C.sub.24 -olefins, by partial 80-95% hydrogenation conversion in a first stage using a silica supported nickel and molybdenum oxide catalyst and then completing the conversion in a second stage using a cobalt catalyst containing copper, manganese, molybdenum and,optionally other activating additives. The process is especially adapted to the economic preparation of C.sub.9 -C.sub.11 - and C.sub.13 -C.sub.15 -alkanols which are used to prepare high-grade plasticizer esters.
摘要翻译： 通过在C2-至C24-烯烃的钴催化加氢甲酰基化中获得的相应的粗C3-至C25-链烷醇的催化氢化，通过在第一阶段中部分80-95％氢化转化使C3-至C25-链烷醇的制备 二氧化硅负载的镍和氧化钼催化剂，然后使用含有铜，锰，钼和任选的其它活化添加剂的钴催化剂在第二阶段完成转化。 该方法特别适用于用于制备高级增塑剂酯的C9-C11-和C13-C15-链烷醇的经济性制备。
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