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    Novel substituted azolylvinyl ketones and carbinols as fungicides and plant growth regulators
    2.
    发明授权
    Novel substituted azolylvinyl ketones and carbinols as fungicides and plant growth regulators 失效
    新型取代的唑基乙烯基酮和甲醇作为杀真菌剂和植物生长调节剂

    公开(公告)号：US4728356A

    公开(公告)日：1988-03-01

    申请号：US754788

    申请日：1985-07-12

    申请人： Hans-Ludwig Elbe ,  Wolf Reiser ,  Erik Regel ,  Karl H. Buchel ,  Paul Reinecke ,  Wilhelm Brandes ,  Klaus Lurssen ,  Paul-Ernst Frohberger

    发明人： Hans-Ludwig Elbe ,  Wolf Reiser ,  Erik Regel ,  Karl H. Buchel ,  Paul Reinecke ,  Wilhelm Brandes ,  Klaus Lurssen ,  Paul-Ernst Frohberger

    IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

    摘要： A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.3 represents optionally substituted phenyl,X represents the CO or CH(OH) group andY represents a nitrogen atom or the CH group,or an addition product thereof with an acid or metal salt.The products are active in combating fungi and in regulating the growth of plants.

    摘要翻译： 其中R 1表示任选取代的具有3至5个碳原子的环烷基，取代的环己基或基团，其中R 3表示任选取代的苯基，烯基，炔基，氰基或基团 - Z-R4，其中R4代表烷基，卤代烷基，任选取代的苯基或任选取代的苯基烷基，Z代表O，S，SO或SO 2，n代表0至2的数，R 2代表烷基，烯基，炔基， 取代的苯基或苯基烷基，或者在每种情况下都是任选取代的环烷基，环烷基烷基，环烯基，环烯基烷基，双环烷基或双环烯基，但R 2不同时代表任选取代的苯基，其中R 1表示任选取代的具有3至5个碳原子的环烷基或取代的环己基 或R 3表示任选取代的苯基，X表示CO或CH（OH）基团，Y表示氮气 m或CH基团，或其与酸或金属盐的加成产物。 该产品在防治真菌和调节植物生长方面发挥积极作用。

    Combating fungi with triazolyl-vinyl ketones and carbinols
    3.
    发明授权
    Combating fungi with triazolyl-vinyl ketones and carbinols 失效
    用三唑基 - 乙烯基酮和甲醇灭菌真菌

    公开(公告)号：US4500537A

    公开(公告)日：1985-02-19

    申请号：US494216

    申请日：1983-05-13

    申请人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    发明人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    IPC分类号： A01N43/653 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64 ,  A01N55/02 ,  C07F1/08

    CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

    摘要： A triazolyl-vinyl ketone or carbinol of the formula ##STR1## in which A represents the keto group or a CH(OH) grouping,R.sup.1 represents alkyl or halogenoalkyl andR.sup.2 represents a primary or tertiary alkyl radical, halogenoalkyl, alkoxyalkyl, alkylmercaptoalkyl, dialkylaminoalkyl, hydroxyalkyl, an optionally substituted alkenyl, alkynyl or alkenynyl radical, phenylalkyl which is optionally substituted in the alkyl part and/or in the phenyl part, an optionally substituted indenyl or fluorenyl radical, or an optionally substituted diphenylmethyl or triphenylmethyl radical,or an addition product thereof with a physiologically acceptable acid or a metal salt, which possesses fungicidal activity.

    摘要翻译： 其中A表示酮基或CH（OH）基团的三唑基 - 乙烯基酮或甲醇，其中A表示酮基或CH（OH）基，R 1表示烷基或卤代烷基，R 2表示伯或叔烷基，卤代烷基，烷氧基烷基，烷基巯基烷基，二烷基氨基烷基 ，羟基烷基，任选取代的烯基，炔基或烯基炔基，在烷基部分和/或苯基部分任选取代的苯基烷基，任选取代的茚基或芴基，或任选取代的二苯基甲基或三苯基甲基，或加成 其具有生理上可接受的酸或金属盐，其具有杀真菌活性。

    Combating fungi with substituted 1-azolyl-butan-2-ones and -2-ols
    6.
    发明授权
    Combating fungi with substituted 1-azolyl-butan-2-ones and -2-ols 失效
    用真菌与取代的1-噻唑基 - 丁-2-酮和-2-ols进行灭菌

    公开(公告)号：US4549900A

    公开(公告)日：1985-10-29

    申请号：US481615

    申请日：1983-04-04

    申请人： Wolfgang Kramer ,  Karl H. Buchel ,  Hans-Ludwig Elbe ,  Udo Kraatz ,  Erik Regel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

    发明人： Wolfgang Kramer ,  Karl H. Buchel ,  Hans-Ludwig Elbe ,  Udo Kraatz ,  Erik Regel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

    IPC分类号： A01N43/50 ,  A01N43/64 ,  A01N43/653 ,  A01N47/02 ,  C07C45/63 ,  C07C45/67 ,  C07C45/71 ,  C07C45/75 ,  C07D249/08 ,  C07D521/00 ,  C07D233/60

    CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/64 ,  A01N47/02 ,  C07C323/00 ,  C07C45/63 ,  C07C45/673 ,  C07C45/71 ,  C07C45/75 ,  C07D233/56 ,  C07D249/08

    摘要： Substituted 1-azolyl-but-2-ones and -2-ols of the formula ##STR1## in which B is --CO-- or --CH(OH)--Az represents a 1,2,4-triazol-1-yl or -4-yl or imidazol-1-yl radical,R.sup.1 represents a hydrogen atom, an alkyl, alkenyl, alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted phenoxyalkyl or optionally substituted aralkyl radical,n is 0 or 1,R.sup.2 represents a cyano radical or a grouping of the general formula --X--R.sup.3 or --CO--NR.sup.4 R.sup.5, or, if n does not represent O at the same time as R.sup.1 represents a hydrogen atom and Az represents a 1,2,4-triazolyl radical,R.sup.2 also additionally represents an optionally substituted aryl or alkoxycarbonyl radical,and whereinX represents an oxygen or sulphur atom or an SO or SO.sub.2 group,R.sup.3 represents an alkyl, halogenoalkyl, optionally substituted aryl or optionally substituted aralkyl radical,R.sup.4 represents a hydrogen atom or an alkyl or optionally substituted aryl radical, andR.sup.5 represents a hydrogen atom or an alkyl radical, or acid addition salts or metal salt complexes thereof which possess fungicidal activity and plant growth regulatory and which can be reduced to the corresponding alcohols which are also fungicidally active.

    摘要翻译： 其中B为-CO-或-CH（OH）的取代的1-噻唑基 - 但-2-酮和2-取代的式“IMAGE”为Az代表1,2,4-三唑-1-基或 R 1表示氢原子，烷基，烯基，炔基，任选取代的环烷基，任选取代的环烷基烷基，任选取代的苯氧基烷基或任选取代的芳烷基，n为0或1，R 2表示 氰基或通式-X-R3或-CO-NR4R5的基团，或者如果在R1表示氢原子的同时不表示O，并且Az表示1,2,4-三唑基 R2还另外表示任选取代的芳基或烷氧基羰基，并且其中X表示氧或硫原子或SO或SO 2基团，R 3表示烷基，卤代烷基，任选取代的芳基或任选取代的芳烷基，R 4表示氢原子 或烷基或任选取代的芳基，R 5表示氢原子或 烷基或其酸加成盐或金属盐络合物，其具有杀真菌活性和植物生长调节，并且可以还原成也是杀真菌活性的相应的醇。

    Combating fungi with imidazolyl-vinyl ketones and carbinols
    7.
    发明授权
    Combating fungi with imidazolyl-vinyl ketones and carbinols 失效
    抗真菌与咪唑基 - 乙烯基酮和甲醇

    公开(公告)号：US4385061A

    公开(公告)日：1983-05-24

    申请号：US259305

    申请日：1981-04-30

    申请人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    发明人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    IPC分类号： C07D233/60 ,  A01N43/50 ,  C07D233/56 ,  C07D521/00 ,  C07D249/08 ,  A01N43/64

    CPC分类号： C07D231/12 ,  A01N43/50 ,  C07D233/56 ,  C07D249/08

    摘要： Imidazolyl-vinyl ketones or carbinols of the formula ##STR1## in which A represents a keto group or a CH(OH) grouping,R.sup.1 represents an alkyl or halogenoalkyl radical andR.sup.2 represents an alkyl radical, an optionally substituted cycloalkyl or cycloalkenyl radical, a halogenoalkyl, alkoxyalkyl, alkylmercaptoalkyl, dialkylaminoalkyl or hydroxyalkyl radical, an optionally substituted alkenyl, alkinyl or alkeninyl radical, a phenylalkyl radical which is optionally substituted in the alkyl part and in the phenyl part, an optionally substituted indenyl or fluorenyl radical or an optionally substituted diphenylmethyl or triphenylmethyl radical,or acid addition products and metal salt complexes thereof which possess fungicidal activity.

    摘要翻译： 咪唑基 - 乙烯基酮或式“IMAGE”的甲醇，其中A表示酮基或CH（OH）基，R 1表示烷基或卤代烷基，R 2表示烷基，任选取代的环烷基或环烯基， 烷氧基烷基，烷基巯基烷基，二烷基氨基烷基或羟烷基，任选取代的烯基，炔基或烯烯基，在烷基部分和苯基部分任选取代的苯基烷基，任选取代的茚基或芴基或任选取代的二苯基甲基 或三苯基甲基，或具有杀真菌活性的酸加成产物及其金属盐络合物。

    Substituted azolylmethyloxiranes
    8.
    发明授权
    Substituted azolylmethyloxiranes 失效
    取代的唑基甲基环氧乙烷

    公开(公告)号：US5371065A

    公开(公告)日：1994-12-06

    申请号：US305836

    申请日：1989-02-02

    申请人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Wilhelm Brandes ,  Stefan Dutzmann ,  Klaus Lurssen

    发明人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Wilhelm Brandes ,  Stefan Dutzmann ,  Klaus Lurssen

    IPC分类号： C07D405/06 ,  A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00

    CPC分类号： C07D249/08 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56

    摘要： Fungicidal and plant growth-regulating substituted azolylmethyloxiranes of the formula ##STR1## in which R.sup.1 stands for alkyl,R.sup.2 stands for alkyl,X stands for a nitrogen atom or the CH group,Y stands (or halogen, alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl and/or optionally substituted phenylalkoxy andm stands for the numbers 0, 1, 2 or 3,and addition products thereof with acids and metal salts.

    摘要翻译： R 1代表烷基，R 2代表烷基，X代表氮原子或CH基团，Y代表（或卤素，烷基，环烷基，环烷基，环烷基或芳烷基）的杀真菌和植物生长调节取代的吡唑基甲基环氧烷， 烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基，任选取代的苯基，任选取代的苯氧基，任选取代的苯基烷基和/或任选取代的苯基烷氧基，m代表数字0,1,2或3，其加成产物与酸和金属盐 。

    Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives
    10.
    发明授权
    Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives 失效
    杀真菌剂1,4-二取代的1-噻唑基-3,3-二甲基丁烷衍生物

    公开(公告)号：US4968712A

    公开(公告)日：1990-11-06

    申请号：US225971

    申请日：1988-07-29

    申请人： Hans-Ludwig Elbe ,  Albrecht Marhold ,  Karl H. Buchel ,  Stefan Dutzmann ,  Paul Reinecke ,  Wilhelm Brandes ,  Gerhard Hanssler

    发明人： Hans-Ludwig Elbe ,  Albrecht Marhold ,  Karl H. Buchel ,  Stefan Dutzmann ,  Paul Reinecke ,  Wilhelm Brandes ,  Gerhard Hanssler

    IPC分类号： A01N43/653 ,  A01N47/02 ,  C07D233/60 ,  C07D249/08 ,  C07D405/10 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/653 ,  A01N47/02 ,  C07D233/56 ,  C07D249/08

    摘要： Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen or halogen,R.sup.2 represents hydrogen or halogen,R.sup.3 represents hydrogen, halogen or trifluoromethoxy,R.sup.4 represents halogen, trifluoromethoxy, trifluoromethylthio, trifluoromethylsulphinyl, trifluoromethylsulphonyl, difluoromethoxy, difluorochloromethoxy, trifluorochloroethoxy, tetrafluoroethoxy, trifluoroethoxy, difluoromethylthio, trifluorochloroethylthio, tetrafuoroethylthio, difluoromethylsulphinyl, difluorochloromethylsulphinyl, trifluorochloroethylsulphinyl, tetrafluoroethylsulphinyl, difluoromethylsulphonyl, difluorochloromethylsulphonyl, trifluorochloroethylsulphonyl, tetrafluoroethylsulphonyl, difluorobromomethylthio, difluorobromomethylsulphinyl, difluorobromomethylsulphonyl or difluorochloromethylthio orR.sup.3 and R.sup.4 together represent alkylenedioxy substituted by halogen,R.sup.5 represents hydrogen or halogen,A represents a keto group or a CH(OH) grouping,Z represents a nitrogen atom or the CH group andR.sup.6 and R.sup.7 identical or different and independently of one another represent hydrogen, alkyl, alkenyl, alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl or optionally substituted phenylalkyl, whereR.sup.3 represents trifluoromethoxy whenR.sup.4 represents halogen,and addition products thereof with acids and metal salts.

    摘要翻译： 式（I）的杀真菌的1,4-二取代的1-吡唑基-3,3-二甲基丁烷衍生物，其中R 1表示氢或卤素，R 2表示氢或卤素，R 3表示氢，卤素或三氟甲氧基，R 4表示卤素 三氟甲氧基，三氟甲硫基，三氟甲磺酰基，三氟甲磺酰基，二氟甲氧基，二氟氯甲氧基，三氟氯乙氧基，四氟乙氧基，三氟乙氧基，二氟甲硫基，三氟氯乙硫基，四氟乙基硫代， 和R4一起代表被卤素取代的亚烷基二氧基，R 5代表氢或卤素，A代表酮基或CH（OH） Z表示氮原子或CH基团，R 6和R 7相同或不同且彼此独立地表示氢，烷基，烯基，炔基，任选取代的环烷基，任选取代的环烷基烷基或任选取代的苯基烷基，其中当R 4表示卤素时，R 3表示三氟甲氧基 ，及其与酸和金属盐的加成产物。