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公开(公告)号：US5654366A
公开(公告)日：1997-08-05
申请号：US604138
申请日：1996-02-20
CPC分类号： C08L55/02 , C08L25/12 , C08L83/04 , C08L83/10 , C08G77/442 , C08G77/452 , C08G77/70
摘要： There is disclosed a thermoplastic resin composition wherein the dispersion of a polyorganosiloxane in a thermoplastic resin is improved by the inclusion of a copolymer of an organosiloxane compound and an ester of a vinylcarboxylic acid or a copolymer of an aromatic vinyl compound, an unsaturated aliphatic nitrile compound and an organosiloxane compound. As a consequence of the excellent dispersion, the composition has improved moldability compared with conventional thermoplastic resins containing only polyorganosiloxane and yields moldings that have a releasability, lubricity, water repellency and mechanical strength superior to moldings from the conventional thermoplastic resins containing only polyorganosiloxane.
摘要翻译： 公开了一种热塑性树脂组合物，其中聚有机硅氧烷在热塑性树脂中的分散体通过包含有机硅氧烷化合物和乙烯基羧酸的酯的共聚物或芳族乙烯基化合物，不饱和脂族腈化合物 和有机硅氧烷化合物。 作为优异分散性的结果，与仅含有聚有机硅氧烷的常规热塑性树脂相比，组合物具有改进的成型性，并且得到具有优于仅含有聚有机硅氧烷的常规热塑性树脂的模制品的脱模性，润滑性，拒水性和机械强度的模制品。
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2.发明申请公开(公告)号：US20080319144A1
公开(公告)日：2008-12-25
申请号：US11813339
申请日：2005-12-15
IPC分类号： C08G77/38
CPC分类号： C08K5/5435 , C08L83/06 , C08L2666/44 , C08L2666/14
摘要： A silicone resin composition comprising a mixture or a reaction mixture of (A) a silicone resin having a softening point above 25° C. and represented by the following average unit formula: (R1SiO3/2)a(R22SiO2/2)b(R33SiO1/2)c(SiO4/2)d(XO1/2)e, and (B) an epoxy-containing alkoxysilane, is characterized by low melt viscosity, excellent reactivity and dispersibility in organic resins; to provide a curable resin composition which is capable of forming a cured resin with excellent flame retardant properties and is free of antimony oxides or halogenated epoxy resins and therefore does not produce a harmful influence on the human body or the environment.
摘要翻译： 一种有机硅树脂组合物，其包含（A）软化点高于25℃并由以下平均单元式表示的（A）有机硅树脂的混合物或反应混合物：（R1SiO3 / 2）a（R22SiO2 / 2）b（R33SiO1 / 2）c（SiO4 / 2）d（XO1 / 2）e和（B）含环氧基的烷氧基硅烷的特征在于低熔融粘度，优异的反应性和在有机树脂中的分散性; 提供能够形成具有优异阻燃性能的固化树脂并且不含氧化锑或卤化环氧树脂的可固化树脂组合物，因此不会对人体或环境产生有害影响。
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3.发明授权Flame-retardant thermoplastic resin composition and manufacturing method thereof 有权阻燃热塑性树脂组合物及其制造方法公开(公告)号：US06699925B2
公开(公告)日：2004-03-02
申请号：US09938251
申请日：2001-08-23
申请人： Hidekatsu Hatanaka , Koji Nakanishi , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
发明人： Hidekatsu Hatanaka , Koji Nakanishi , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
IPC分类号： C08K320
CPC分类号： C08L23/04 , C08L83/04 , C08L2201/02 , C08L83/00
摘要： A flame-retardant thermoplastic resin composition comprising (A) 100 weight parts of a thermoplastic resin, (B) 10 to 300 weight parts of particulate metal hydroxide; (C) 0.01 to 50 weight parts of a branched polyorganosiloxane having alkoxy groups and described by average unit formula R1a(R2O)bSiO(4−a−b)/2, where R1 and R2 are monovalent hydrocarbon groups selected from the group consisting of alkyl, alkenyl, and aryl groups, a is 0 or a positive number; b is a positive number; and a+b is a number from 0.75 to 2.5; (D) 0.01 to 50 weight parts of a branched polyorganosiloxane having silanol groups and described by average unit formula R3a(HO)bSiO(4−a−b)/2, where R3 is a monovalent hydrocarbon group selected from the group consisting of alkyl, alkenyl, and aryl groups, a is 0 or a positive number, b is a positive number, and a+b is a number from 0.75 to 2.5; and (E) 0.01 to 10 weight parts of a condensation reaction promoting catalyst. The present invention further relates to a method for manufacturing the flame-retardant thermoplastic resin composition.
摘要翻译： 一种阻燃热塑性树脂组合物，其包含（A）100重量份的热塑性树脂，（B）10〜300重量份的颗粒状金属氢氧化物; （C）0.01至50重量份的具有烷氧基且由平均单元式R a a（R 2 O）b SiO（4-ab）/ 2表示的支链聚有机硅氧烷，其中R 1和R 2， 2>是选自烷基，烯基和芳基的一价烃基，a是0或正数; b是正数; a + b为0.75〜2.5的数; （D）0.01〜50重量份具有硅烷醇基且由平均单元式R 3 a（HO）b SiO（4-ab）/ 2表示的支链聚有机硅氧烷，其中R 3为选自 由烷基，烯基和芳基组成的组，a为0或正数，b为正数，a + b为0.75至2.5的数; 和（E）0.01〜10重量份缩合反应促进催化剂。 本发明还涉及一种阻燃热塑性树脂组合物的制造方法。
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4.发明授权公开(公告)号：US06303681B1
公开(公告)日：2001-10-16
申请号：US09662371
申请日：2000-09-15
申请人： Haruhiko Furukawa , Hidekatsu Hatanaka , Koji Shiromoto , Hiroshi Ueki , Koji Nakanishi , Yoshitsugu Morita
发明人： Haruhiko Furukawa , Hidekatsu Hatanaka , Koji Shiromoto , Hiroshi Ueki , Koji Nakanishi , Yoshitsugu Morita
IPC分类号： C08K322
CPC分类号： C08L23/04 , C08K3/22 , C08K2003/2217 , C08K2003/2227 , C08L23/08 , C08L83/06 , C08L2201/02 , C08L83/00 , C08L2666/04
摘要： A flame-retardant polyolefin-type resin composition comprising (A) 100 weight parts polyolefin-type resin, (B) 30 to 200 weight parts powder of a hydrated metal compound, and (C) 0.01 to 50 weight parts branched organopolysiloxane with average unit formula RaSiO(4−a)/2 where each R is a selected from the group consisting of monovalent organic groups selected from the group consisting of C1 to C12 alkyl and C6 to C12 aryl and hydroxyl, wherein aryl constitutes from 50 to 100 mole % of the total monovalent organic groups and the hydroxyl content in each molecule is from 1 to 10 weight %, a is a number from 0.75 to 2.5, and the organopolysiloxane contains at least one RSiO3/2 siloxane unit in each molecule, where R is as previously described. The composition is useful as a flame-retardant coating on electrical cables.
摘要翻译： 一种阻燃聚烯烃类树脂组合物，其包含（A）100重量份聚烯烃类树脂，（B）30〜200重量份水合金属化合物粉末，和（C）0.01〜50重量份平均单位的支链有机聚硅氧烷 每个R选自由选自C1至C12烷基和C6至C12芳基和羟基的一价有机基团组成的组，其中芳基构成总一价有机基团的50至100摩尔％，羟基 每个分子中的含量为1至10重量％，a为0.75至2.5的数，并且有机聚硅氧烷在每个分子中含有至少一个RSiO 3/2硅氧烷单元，其中R如前所述。 该组合物可用作电缆上的阻燃涂层。
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5.发明授权Silicone-containing polyimide resin, silicon-containing polyamic acid, and methods for manufacture 有权含有硅酮的聚酰亚胺树脂，含硅聚酰胺酸及其制造方法公开(公告)号：US06297341B1
公开(公告)日：2001-10-02
申请号：US09548649
申请日：2000-04-13
IPC分类号： C08G7726
CPC分类号： C08G77/455 , C08L83/10
摘要： A silicone-containing polyimide resin, a silicone-containing polyamic acid, and methods for manufacturing these. More particularly, a silicone-containing polyimide resin with superior heat resistance and flexibility, a silicone-containing polyamic acid for which this polyimide resin is a raw material, and methods for manufacturing these.
摘要翻译： 含硅酮聚酰亚胺树脂，含硅酮聚酰胺酸及其制造方法。 更具体地，具有优异的耐热性和柔性的含硅酮聚酰亚胺树脂，该聚酰亚胺树脂为原料的含硅氧烷聚酰胺酸及其制造方法。
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6.发明授权Method for the preparation of organofunctional organopentasiloxane, organic resin modifier and organic resins 失效有机官能有机硅氧烷，有机树脂改性剂和有机树脂的制备方法
公开(公告)号：US6133394A
公开(公告)日：2000-10-17
申请号：US237280
申请日：1999-01-26
IPC分类号： B01J31/02 , B01J31/16 , C07B61/00 , C07F7/08 , C07F7/10 , C08G64/08 , C08G64/18 , C08G73/10 , C08G77/04 , C08G77/42 , C08G77/448 , C08G77/455 , C08K5/5419 , C08L101/00 , C08G77/12 , C08G77/16 , C08G77/26
CPC分类号： C07F7/0854 , C07F7/0852 , C07F7/0874 , C07F7/0879 , C08G64/085 , C08G77/045 , C08G77/42
摘要： A method for preparaing of an organofunctional organopentasiloxane which finds utility as a modifier for organic resins is disclosed, said method comprising:(I) reacting(A) a cyclotrisiloxane and(B) an .alpha.,.omega.-dihydrogendiorganodisiloxane in the presence of an(C) acid catalyst to prepare an .alpha.,.omega.-dihydrogendiorganopentasiloxane having the formulaR.sub.2 HSiO(R.sub.2 SiO).sub.3 SiHR.sub.2 wherein R independently represents a monovalent group free of aliphatic unsaturation selected from hydrocarbon or halogenated hydrocarbon groups; and(II) running an addition reaction in the presence of (D) a hydrosilylation catalyst between said .alpha.,.omega.-dihydrogendiorganopentasiloxane and (E) an organic compound containing a monovalent group selected from epoxy or phenol groups as well as an unsaturated aliphatic hydrocarbon group. In a variation of the method, the .alpha.,.omega.-dihydrogendiorganopentasiloxane is reacted with (F) an organic compound bearing an unsaturated aliphatic hydrocarbon group as well as a monovalent group selected from triorganosilyl-protected amino, triorganosilyl-protected carboxyl, triorganosilyl-protected hydroxyl or triorganosilyl-protected phenol and the protective triorganosilyl groups are subsequently removed.
摘要翻译： 公开了一种制备用作有机树脂改性剂的有机官能有机硅氧烷的方法，所述方法包括：（I）使（A）环三硅氧烷和（B）α，ω-二氢羟基二硅氧烷在（C ）酸催化剂以制备具有式R2HSiO（R2SiO）3SiHR2的α，ω-二氢羟基戊酸二硅氧烷，其中R独立地表示不含选自烃或卤代烃基的脂族不饱和基团的一价基团; 和（II）在（D）所述α，ω-二氢羟基二硅氧烷之间的氢化硅烷化催化剂和（E）含有选自环氧基或苯酚基团的一价基团的有机化合物以及不饱和脂族烃基团的存在下进行加成反应 。 在该方法的变体中，α，ω-二氢羟基二硅氧烷与（F）具有不饱和脂族烃基的有机化合物以及选自三有机甲硅烷基保护的氨基，三有机甲硅烷基保护的羧基，三有机甲硅烷基保护的羟基的一价基团反应 或三有机甲硅烷基保护的苯酚，然后除去保护性三有机甲硅烷基。
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7.发明授权公开(公告)号：US07138467B2
公开(公告)日：2006-11-21
申请号：US10504338
申请日：2003-02-14
IPC分类号： C08L63/00
CPC分类号： C08L61/06 , C08K5/0066 , C08L63/00 , C08L83/04 , C08L83/06 , C08L83/00 , C08L2666/22 , C08L2666/14 , C08L2666/02
摘要： The present invention relates to a silicone resin composition of low melt viscosity and excellent reactivity and dispersibility in organic resins. The present invention also relates to a curable resin composition for forming a cured resin of excellent moldability and superior flame retardant properties while having little adverse impact on the human body and the environment as a result of containing no antimony oxides or halogenated epoxy resins. The present invention also relates to a cured resin having little adverse impact on the human body or the environment and possessing superior flame retardant properties.
摘要翻译： 本发明涉及一种熔体粘度低，反应性和分散性优异的有机树脂组合物。 本发明还涉及一种用于形成固化树脂的固化树脂组合物，其具有优异的成型性和优异的阻燃性能，同时由于不含氧化锑或卤化环氧树脂而对人体和环境几乎没有不利的影响。 本发明还涉及对人体或环境几乎没有不利影响且具有优异的阻燃性能的固化树脂。
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公开(公告)号：US06534576B2
公开(公告)日：2003-03-18
申请号：US09907281
申请日：2001-07-17
申请人： Koji Nakanishi , Hidekatsu Hatanaka , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
发明人： Koji Nakanishi , Hidekatsu Hatanaka , Haruhiko Furukawa , Koji Shiromoto , Hiroshi Ueki , Yoshitsugu Morita
IPC分类号： C08K504
CPC分类号： C08L69/00 , C08F283/12 , C08K5/5419 , C08L27/12 , C08L55/02 , C08L83/04 , C08L2666/02 , C08L83/00
摘要： A flame retardant organic resin composition comprising (A) 100 parts by weight of an aromatic ring-containing organic resin and (B) 0.01-50 parts by weight of a branched organopolysiloxane described by average molecular formula (R13SiO1/2)a(R2SiO3/2)b(SiO4/2)c(R3O1/2)d(HO1/2)e, where each R1 is independently selected from alkyl groups comprising 1 to 12 carbon atoms and alkenyl groups comprising 2 to 12 carbon atoms; each R2 is independently selected from alkyl groups comprising 1 to 12 carbon atoms, alkenyl groups comprising 2 to 12 carbon atoms, and aryl groups comprising 6 to 12 carbon atoms, where the aryl groups of R2 are at least 30 mol % based on total monovalent hydrocarbon in R1 and R2, R3 represents an alkyl group, subscripts a and b are positive numbers, and subscripts c, d, and e are 0 or positive numbers.
摘要翻译： 一种阻燃有机树脂组合物，其包含（A）100重量份的含芳环的有机树脂和（B）0.01-50重量份的由平均分子结构域所述的支链有机基聚硅氧烷，每个R 1独立地选自烷基， 1至12个碳原子和2至12个碳原子的链烯基; 每个R 2独立地选自包含1至12个碳原子的烷基，包含2至12个碳原子的烯基和包含6至12个碳原子的芳基，其中R 2的芳基基于总单价为至少30摩尔％ R 1和R 2中的烃，R 3表示烷基，下标a和b为正数，下标c，d和e为0或正数。
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公开(公告)号：US6001942A
公开(公告)日：1999-12-14
申请号：US217075
申请日：1998-12-21
IPC分类号： C08G73/10 , C08G77/455 , C08G77/04
CPC分类号： C08G73/1042 , C08G73/106 , C08G77/455
摘要： The invention relates to a silicon-containing polyimide resin comprising (I) 0.1 to 100 mole % of structural units represented by the formula: ##STR1## where Ar.sup.1 is a tetra valent organic group having at least one aromatic ring, R independently represents a monovalent hydrocarbon group free of aliphatic unsaturated bonds, X is selected from an alkyleneoxyalkylene or an alkylene group having 2 or more carbon atoms, Y is an oxygen atom, an alkyleneoxyalkylene group, or an alkylene group having 2 or more carbon atoms, l, m, n are each integers having a value of 1 to 10, p is an integer having a value of 1 to 80, and a is 0 or 1; and (II) 99.9 to 0 mole % of structural units represented by the formula: ##STR2## where Ar.sup.2 is a tetravalent organic group having at least one aromatic ring, and Ar.sup.3 is a divalent organic group having at least one aromatic group.
摘要翻译： 本发明涉及一种含硅聚酰亚胺树脂，其包含（I）0.1-100摩尔％的由下式表示的结构单元：其中Ar1是具有至少一个芳族环的四价有机基团，R独立地表示一价无烃基团 的脂肪族不饱和键，X选自亚烷氧基亚烷基或碳原子数2以上的亚烷基，Y为氧原子，亚烷基氧化烯基或碳原子数2以上的亚烷基，l，m，n分别为 整数值为1〜10，p为1〜80的整数，a为0或1; 和（II）99.9至0摩尔％的由下式表示的结构单元：其中Ar 2是具有至少一个芳环的四价有机基团，Ar 3是具有至少一个芳族基团的二价有机基团。
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公开(公告)号：US06590032B2
公开(公告)日：2003-07-08
申请号：US09829607
申请日：2001-04-10
IPC分类号： C08L8310
CPC分类号： C08L23/10 , C08L23/02 , C08L23/16 , C08L23/30 , C08L25/04 , C08L51/06 , C08L53/00 , C08L77/00 , C08L83/04 , C08L2205/035 , C08L83/00 , C08L2666/02 , C08L2666/24 , C08L2666/14
摘要： A thermoplastic resin composition comprising (A) 100 weight parts thermoplastic resin, (B) 0.1 to 100 weight parts of a mixture of (b-1) thermoplastic resin and (b-2) polyorganosiloxane that has a viscosity at 25° C. of at least 1,000,000 mPa·s, and (C) 0.1 to 100 weight parts polyorganosiloxane-bonded thermoplastic resin in which (c-1) thermoplastic resin and (c-2) polyorganosiloxane are chemically bonded to each other.
摘要翻译： 一种热塑性树脂组合物，其包含（A）100重量份热塑性树脂，（B）0.1至100重量份（b-1）热塑性树脂和（b-2）聚有机硅氧烷的混合物，其在25℃下的粘度为 （C-1）热塑性树脂和（c-2）聚有机硅氧烷的化学键合的聚有机硅氧烷结合的热塑性树脂为0.1〜100重量份。
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