公开(公告)号：US20100137664A1

公开(公告)日：2010-06-03

申请号：US12452715

申请日：2008-07-18

申请人： Hee Du Lee ,  Kyung Jong Oh ,  Min Su Ko ,  Min Gyoo Park ,  Seong Jun Lee ,  Yoon Jae Yim ,  Seung Hoon Oh ,  Tae Jin Kim ,  Yong Seung Kim ,  Deuk Soo Park ,  Hong Chan Kim

发明人： Hee Du Lee ,  Kyung Jong Oh ,  Min Su Ko ,  Min Gyoo Park ,  Seong Jun Lee ,  Yoon Jae Yim ,  Seung Hoon Oh ,  Tae Jin Kim ,  Yong Seung Kim ,  Deuk Soo Park ,  Hong Chan Kim

IPC分类号： C07C2/38 ,  B01J10/00

CPC分类号： C10G67/04 ,  C07C7/08 ,  C07C11/107 ,  C10G21/00 ,  C10G21/28 ,  C10G45/32 ,  C10G2300/44 ,  C10G2400/20 ,  C07C11/167

摘要： Disclosed is a method of recovering 1,3-butadiene from a C4 stream containing butane, isobutane, 2-butene, 1-butene, isobutene, butadiene and acetylene. The process of recovering highly pure 1,3-butadiene includes acetylene conversion for selectively converting acetylene through liquid-phase hydrogenation, so that the acetylene content is decreased to 70 wt ppm or less, and 1,3-butadiene extraction using an extractive distillation column, a pre-separator, a solvent stripping column, a solvent recovery column, and a purification column. Through the acetylene conversion, the concentration of vinylacetylene is decreased to 70 wt ppm or less, after which 1,3-butadiene is recovered using only one extractive distillation column, thereby considerably decreasing the degree of utility and the loss of streams in the course of extraction. The number of units necessary for the process is decreased, thus remarkably reducing the time during which impurities can accumulate in a processing unit.

摘要翻译： 公开了从含有丁烷，异丁烷，2-丁烯，1-丁烯，异丁烯，丁二烯和乙炔的C4流中回收1,3-丁二烯的方法。 回收高纯度1,3-丁二烯的方法包括乙炔转化，用于通过液相氢化选择性地转化乙炔，使得乙炔含量降低至70重量ppm以下，使用萃取蒸馏塔进行1,3-丁二烯萃取 ，预分离器，溶剂汽提塔，溶剂回收塔和纯化塔。 通过乙炔转化，乙烯基乙炔的浓度降低至70重量ppm以下，此后仅使用一个萃取蒸馏塔回收1,3-丁二烯，从而大大降低了在过程中的效用和流失 萃取。 该方法所需的单元数量减少，从而显着地减少了杂质在处理单元中积累的时间。

公开(公告)号：US09062262B2

公开(公告)日：2015-06-23

申请号：US12452715

申请日：2008-07-18

申请人： Hee Du Lee ,  Kyung Jong Oh ,  Min Su Ko ,  Min Gyoo Park ,  Seong Jun Lee ,  Yoon Jae Yim ,  Seung Hoon Oh ,  Tae Jin Kim ,  Yong Seung Kim ,  Deuk Soo Park ,  Hong Chan Kim

发明人： Hee Du Lee ,  Kyung Jong Oh ,  Min Su Ko ,  Min Gyoo Park ,  Seong Jun Lee ,  Yoon Jae Yim ,  Seung Hoon Oh ,  Tae Jin Kim ,  Yong Seung Kim ,  Deuk Soo Park ,  Hong Chan Kim

IPC分类号： C10G67/04 ,  C07C7/08 ,  C10G21/00 ,  C07C11/107 ,  C10G21/28 ,  C10G45/32

CPC分类号： C10G67/04 ,  C07C7/08 ,  C07C11/107 ,  C10G21/00 ,  C10G21/28 ,  C10G45/32 ,  C10G2300/44 ,  C10G2400/20 ,  C07C11/167

摘要： Disclosed is a method of recovering 1,3-butadiene from a C4 stream containing butane, isobutane, 2-butene, 1-butene, isobutene, butadiene and acetylene. The process of recovering highly pure 1,3-butadiene includes acetylene conversion for selectively converting acetylene through liquid-phase hydrogenation, so that the acetylene content is decreased to 70 wt ppm or less, and 1,3-butadiene extraction using an extractive distillation column, a pre-separator, a solvent stripping column, a solvent recovery column, and a purification column. Through the acetylene conversion, the concentration of vinylacetylene is decreased to 70 wt ppm or less, after which 1,3-butadiene is recovered using only one extractive distillation column, thereby considerably decreasing the degree of utility and the loss of streams in the course of extraction. The number of units necessary for the process is decreased, thus remarkably reducing the time during which impurities can accumulate in a processing unit.

摘要翻译： 公开了从含有丁烷，异丁烷，2-丁烯，1-丁烯，异丁烯，丁二烯和乙炔的C4流中回收1,3-丁二烯的方法。 回收高纯度1,3-丁二烯的方法包括乙炔转化，用于通过液相氢化选择性地转化乙炔，使得乙炔含量降低至70重量ppm以下，使用萃取蒸馏塔进行1,3-丁二烯萃取 ，预分离器，溶剂汽提塔，溶剂回收塔和纯化塔。 通过乙炔转化，乙烯基乙炔的浓度降低至70重量ppm以下，此后仅使用一个萃取蒸馏塔回收1,3-丁二烯，从而大大降低了在过程中的效用和流失 萃取。 该方法所需的单元数量减少，从而显着地减少了杂质在处理单元中积累的时间。

公开(公告)号：US08962900B2

公开(公告)日：2015-02-24

申请号：US13880838

申请日：2011-10-20

申请人： Hong Chan Kim ,  Yong Seung Kim ,  Sang Hun Oh ,  Hyuck Jae Lee ,  Jae Suk Koh ,  Gyung Rok Kim ,  Myoung Han Noh ,  Sang Il Lee ,  Seung Woo Lee ,  Do Woan Kim ,  Jae Hyun Koh ,  Jong Hyung Lee ,  Sun Choi ,  Seung Hoon Oh ,  Kyung Jong Oh

发明人： Hong Chan Kim ,  Yong Seung Kim ,  Sang Hun Oh ,  Hyuck Jae Lee ,  Jae Suk Koh ,  Gyung Rok Kim ,  Myoung Han Noh ,  Sang Il Lee ,  Seung Woo Lee ,  Do Woan Kim ,  Jae Hyun Koh ,  Jong Hyung Lee ,  Sun Choi ,  Seung Hoon Oh ,  Kyung Jong Oh

IPC分类号： C07C5/10 ,  C07C5/02

CPC分类号： C07C5/02 ,  B01J23/24 ,  B01J23/74 ,  B01J23/85 ,  B01J29/072 ,  B01J29/076 ,  B01J29/7057 ,  B01J29/7615 ,  B01J2229/42 ,  C07C5/2737 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/16 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2529/18 ,  C07C2529/70 ,  C10G1/002 ,  C10G1/06 ,  C10G45/34 ,  C10G47/20 ,  C10G65/12 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/08

摘要： This invention relates to a method of producing aromatics and light paraffins from hydrocarbonaceous oils derived from oil, coal or wood, including partially saturating and hydrocracking the oils derived from oil in a hydrogenation and reaction area, separating them depending on the number of carbons, recirculating heavy oils having 11 or more carbons to the hydrogenation and reaction area, feeding oils suitable for producing BTX to an aromatic separation process and a transalkylation process to recover aromatics, and feeding hydrocarbonaceous components having 5 or fewer carbons to a light separation process, thus obtaining light paraffins.

摘要翻译： 本发明涉及一种从油，煤或木油衍生的烃类油中生产芳香烃和轻链烷烃的方法，包括在氢化和反应区域中部分饱和和加氢裂解油衍生的油，这取决于碳数，再循环 向氢化和反应区域中具有11个或更多个碳的重油，将适用于生产BTX的油进料到芳族分离方法和烷基转移方法中以回收芳族化合物，并将具有5个或更少碳原子的烃类组分进料到光分离过程中，从而获得 轻石蜡

公开(公告)号：US20130267744A1

公开(公告)日：2013-10-10

申请号：US13880838

申请日：2011-10-20

申请人： Hong Chan Kim ,  Yong Seung Kim ,  Sang Hun Oh ,  Hyuck Jae Lee ,  Jae Suk Koh ,  Gyung Rok Kim ,  Myoung Han Noh ,  Sang Il Lee ,  Seung Woo Lee ,  Do Woan Kim ,  Jae Hyun Koh ,  Jong Hyung Lee ,  Sun Choi ,  Seung Hoon Oh ,  Kyung Jong Oh

发明人： Hong Chan Kim ,  Yong Seung Kim ,  Sang Hun Oh ,  Hyuck Jae Lee ,  Jae Suk Koh ,  Gyung Rok Kim ,  Myoung Han Noh ,  Sang Il Lee ,  Seung Woo Lee ,  Do Woan Kim ,  Jae Hyun Koh ,  Jong Hyung Lee ,  Sun Choi ,  Seung Hoon Oh ,  Kyung Jong Oh

IPC分类号： C07C5/02

CPC分类号： C07C5/02 ,  B01J23/24 ,  B01J23/74 ,  B01J23/85 ,  B01J29/072 ,  B01J29/076 ,  B01J29/7057 ,  B01J29/7615 ,  B01J2229/42 ,  C07C5/2737 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/16 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2529/18 ,  C07C2529/70 ,  C10G1/002 ,  C10G1/06 ,  C10G45/34 ,  C10G47/20 ,  C10G65/12 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/08

摘要： This invention relates to a method of producing aromatics and light paraffins from hydrocarbonaceous oils derived from oil, coal or wood, including partially saturating and hydrocracking the oils derived from oil in a hydrogenation and reaction area, separating them depending on the number of carbons, recirculating heavy oils having 11 or more carbons to the hydrogenation and reaction area, feeding oils suitable for producing BTX to an aromatic separation process and a transalkylation process to recover aromatics, and feeding hydrocarbonaceous components having 5 or fewer carbons to a light separation process, thus obtaining light paraffins.

摘要翻译： 本发明涉及一种从油，煤或木油衍生的烃类油中生产芳香烃和轻链烷烃的方法，包括在氢化和反应区域中部分饱和和加氢裂解油衍生的油，这取决于碳数，再循环 向氢化和反应区域中具有11个或更多个碳的重油，将适用于生产BTX的油进料到芳族分离方法和烷基转移方法中以回收芳族化合物，并将具有5个或更少碳原子的烃类组分进料到光分离过程中，从而获得 轻石蜡

公开(公告)号：US08030239B2

公开(公告)日：2011-10-04

申请号：US12312361

申请日：2007-11-16

申请人： Seung Hoon Oh ,  Sang Il Lee ,  Kyeong Hak Seong ,  Jong Hyung Lee ,  Kyung Jong Oh

发明人： Seung Hoon Oh ,  Sang Il Lee ,  Kyeong Hak Seong ,  Jong Hyung Lee ,  Kyung Jong Oh

IPC分类号： B01J29/06

CPC分类号： B01J29/44 ,  B01J29/061 ,  B01J29/064 ,  B01J29/076 ,  B01J29/48 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2708 ,  C07C5/2724 ,  C07C5/2737 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/14 ,  C07C2523/18 ,  C07C2529/22 ,  C07C2529/44 ,  C07C2529/67 ,  C07C2529/74 ,  Y02P20/52 ,  C07C15/08

摘要： Disclosed herein is a catalyst for xylene isomerization, including: a carrier including a zeolite, having a molar ratio of silica to alumina of 20˜100, impregnated with or mixed with a metal salt (I) having an amount of a metal component of 0.05˜5.0 wt % relative to a zeolite, and an inorganic binder, in which an amount of the zeolite is 10˜90 wt % based on the total amount of the carrier, wherein the carrier is supported with a VIII group metal such that an amount of the VIII group metal is 0.001˜3.0 wt % based on a total amount of the catalyst, or is supported with the VII group metal additionally supported with tin, bismuth or lead such that an amount of the tin, bismuth or lead is 0.01-5.0 wt % based on the total amount of the catalyst, and a method of producing the catalyst. The catalyst for xylene isomerization is advantageous in that, when xylene or C8 aromatic compounds are isomerized using the catalyst, the ethylbenzene conversion is increased while the xylene loss is decreased, compared to conventional technologies.

摘要翻译： 本文公开了二甲苯异构化催化剂，其包括：含有二氧化硅与氧化铝的摩尔比为20〜100的沸石的载体，其浸渍或混合金属成分为0.05的金属盐（I） 相对于沸石为约5.0重量％，以及无机粘合剂，其中所述沸石的量相对于所述载体的总量为10〜90重量％，其中所述载体以VIII族金属负载，使得量 Ⅷ族金属的含量相对于催化剂总量为0.001〜3.0重量％，或由锡，铋或铅另外负载的VII族金属负载，使得锡，铋或铅的含量为0.01〜 5.0wt％的催化剂总量，以及催化剂的制造方法。 用于二甲苯异构化的催化剂的优点在于，当使用催化剂使二甲苯或C8芳族化合物异构化时，与常规技术相比，乙苯转化率增加，而二甲苯损失降低。