Polymeric ligands, polymeric metallocenes, catalyst systems, preparation, and use
    5.
    发明授权
    Polymeric ligands, polymeric metallocenes, catalyst systems, preparation, and use 失效
    聚合物配体,聚合金属茂,催化剂体系,制备和用途

    公开(公告)号:US06372930B1

    公开(公告)日:2002-04-16

    申请号:US09501816

    申请日:2000-02-10

    IPC分类号: C07F1700

    摘要: Polymeric ligands, polymeric metallocenes, and processes for preparing same are provided. The process for preparing polymeric metallocenes comprises reacting a polymeric ligand, a transition metal compound, and an alkali metal compound. In one embodiment, a process for preparing polymeric ligands comprises reacting at least one bridged cyclopentadienyl-type monomer and an initiator under polymerization conditions. In another embodiment, a polymeric ligand is represented by the formula [Q′]n, wherein Q′ is a unit containing at least one bridged cyclopentadienyl-type group and wherein n is 1-5000. In another embodiment, a polymeric metallocene is represented by the formula [Q″MXm]n, wherein Q″ is a unit containing at least one fluorenyl-type group, M is a transition metal, each X is individually a hydrocarbyl group containing 1 to 20 carbon atoms, an alkoxy group containing 1 to 12 carbon atoms, an aryloxy group containing 6 to 20 carbon atoms, a halide, or hydride, m is 2 or 3, and wherein n is 1-5000. Other aspects of the present invention include a catalyst system comprising the polymeric metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.

    摘要翻译: 提供了聚合配体,聚合金属茂及其制备方法。 制备聚合金属茂的方法包括使聚合物配体,过渡金属化合物和碱金属化合物反应。 在一个实施方案中,制备聚合物配体的方法包括在聚合条件下使至少一种桥连环戊二烯基型单体与引发剂反应。 在另一个实施方案中,聚合物配体由式[Q'] n表示,其中Q'是含有至少一个桥连环戊二烯基型基团并且其中n为1-5000的单元。 在另一个实施方案中,聚合物茂金属由式[Q'MXm] n表示,其中Q“是含有至少一个芴基型基团的单元,M是过渡金属,每个X各自含有含烃基 1〜20个碳原子的烷氧基,碳原子数1〜12的烷氧基,碳原子数6〜20的芳氧基,卤化物或氢化物,m为2或3,n为1-5000。 本发明的其它方面包括包含聚合金属茂和有机铝氧烷的催化剂体系,其制备方法和使用催化剂体系的聚合方法。

    Process for isomerizing dichlorobutenes
    6.
    发明授权
    Process for isomerizing dichlorobutenes 失效
    二氯丁烯异构化方法

    公开(公告)号:US06392107B2

    公开(公告)日:2002-05-21

    申请号:US09804894

    申请日:2001-03-13

    申请人: Peter Schertl

    发明人: Peter Schertl

    IPC分类号: C07C2122

    摘要: This invention relates to a process for isomerizing 1,4-dichloro-2-butene to yield 3,4-dichloro-1-butene or 3,4-dichloro-1-butene to yield 1,4-dichloro-2-butene, characterized in that the catalyst used comprises a compound of the formula CpFe(CO)2X, wherein Cp denotes a cyclopentadienyl derivative of the general formula (I), wherein R1 to R5 mutually independently denote H, C1 to C12 alkyl, C5 to C8 cycloalkyl, which may in turn bear C1 to C12 alkyl groups, C6 to C14 aryl, alkylaryl, arylalkyl, wherein two adjacent residues may together form saturated or unsaturated C3 to C14 cycles, or denote—SiR6R7R8, wherein R6 to R7 may mutually independently mean C1 to C4 alkyl, C5 to C8 cycloalkyl or C6 to C14 aryl, and X denotes F, Cl, Br.

    摘要翻译: 本发明涉及使1,4-二氯-2-丁烯异构化得到3,4-二氯-1-丁烯或3,4-二氯-1-丁烯的方法,得到1,4-二氯-2-丁烯, 其特征在于所用催化剂包括式CpFe(CO)2X的化合物,其中Cp表示通式(I)的环戊二烯基衍生物,其中R 1至R 5相互独立地表示H,C 1至C 12烷基,C 5至C 8环烷基, 其还可以承载C1至C12烷基,C6至C14芳基,烷基芳基,芳基烷基,其中两个相邻的残基可以一起形成饱和或不饱和的C3至C14周期,或表示-SiR6R7R8,其中R6至R7可以相互独立地表示C1至 C4烷基,C5至C8环烷基或C6至C14芳基,X表示F,Cl,Br。

    Polymerization-initiating supported systems
    9.
    发明授权
    Polymerization-initiating supported systems 失效
    聚合引发支持体系

    公开(公告)号:US06387837B1

    公开(公告)日:2002-05-14

    申请号:US09244240

    申请日:1999-02-03

    IPC分类号: B01J2904

    摘要: This invention relates to a process for the free-radical polymerization of monomers in gas phase or suspension processes using a supported, polymerization-initiating system comprising a) one or more polymerization-initiating components which initiate and start free-radical polymerization, b) a support, onto which said polymerization-initiating component is applied, and c) optionally, one or more modifiers which have an influence upon reaction kinetics and/or product properties.

    摘要翻译: 本发明涉及使用负载型聚合引发体系的气相或悬浮方法中单体的自由基聚合方法,该方法包括:a)引发和开始自由基聚合的一种或多种聚合引发组分,b)载体 ,其上应用了所述聚合引发组分,和c)任选的一种或多种对反应动力学和/或产物性质有影响的改性剂。