摘要:
Dispersions suitable for the manufacture of moulding compositions which can be cured with low shrinkage to give mouldings with excellent surfaces can be obtained by the addition of finely divided ethylene copolymers manufactured in aqueous emulsion to unsaturated polyester resins.
摘要:
Pourable and pumpable, storage-stable organic dispersions which can be cured with little shrinkage comprising unsaturated polyesters, copolymerizable vinyl monomers, ethylene vinyl ester copolymers and optionally dispersing agents.
摘要:
Weather-resistant thermoplastic moulding compounds of mixtures ofA. copolymers of (meth)acrylonitrile, of at least one aromatic vinyl compound and of optionally at least one monoolefin, andB. a graft copolymer of an ethylene/vinyl ester copolymer as graft substrate and grafted polymerized units of (meth)acrylonitrile of at least one aromatic monovinyl compound and of optionally at least one aliphatic monoolefin.
摘要:
The object of the invention is the use of ethylene-vinyl acetate-copolymers produced by emulsion polymerization and containing unipolymerized acids, for the modification of polyvinyl chloride.
摘要:
Copolymers with improved dimensional stability under heat consisting essentially of (meth)acrylonitrile, styrene and at least one aliphatic monoolefin with 2 to 8 carbon atoms.
摘要:
Transparent thermoplastic moulding compositions having improved mechanical properties consist of graft copolymers or mixtures thereof with a cellulose ester of aliphatic C.sub.1 -C.sub.5 carboxylic acids, wherein the graft copolymers consist of an ethylene vinyl ester copolymer and a cellulose ester of aliphatic C.sub.1 -C.sub.5 -carboxylic acids as the graft substrate, at least part of which being bridged with polymerized grafted units of vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid, and, optionally, C.sub.2 -C.sub.4 -olefins.
摘要:
A process for the preparation of dispersions of optionally cross-linked ethylene-vinyl ester graft polymers wherein an ethylene-vinyl ester copolymer is used as graft substrate and a vinyl ester of a C.sub.1 -C.sub.18 carboxylic acid and/or a C.sub.1 -C.sub.10 -alkyl ester of acrylic and/or methacrylic acid are used as a graft monomer which is polymerized, optionally together with a cross-linking agent having two or more C--C double bonds, in organic solution until at least 25% by weight of the graft monomer has been reacted, the reaction product is converted into a stable finely divided dispersion by the addition of a precipitating agent under the action of shearing forces and polymerisation is completed before, during or after the formation of the dispersion.
摘要:
Anhydride-group- or carboxyl-group-containing graft copolymers of vinyl esters and other suitable monomers on polysaccharide esters of (A) a polysaccharide ester of aliphatic C.sub.1 -C.sub.5 -mono-carboxylic acids as the graft substrate and (B) a grafted-on monomer mixture of (a) a vinyl ester of a C.sub.1 -C.sub.18 -monocarboxylic acid and (b) maleic acid anhydride and/or semiesters of maleic acid and/or fumaric acid with aliphatic C.sub.1 -C.sub.14 -monoalcohols, the ratio by weight of (A) to (B) being from 1:0.1 to 1:2 and the molar ratio of (a) to (b) being from 1:0.5 to 1:3, and a process for producing these graft copolymers.
摘要:
A process for the preparation of graft polymers from ethylene homopolymers or copolymers and olefinically unsaturated monomers, especially from ethylene/vinyl ester copolymers, in the presence of a radical forming agent in homogenous or heterogeneous phase, in which a mixture of (meth)acrylonitrile, at least one aromatic vinyl compound and vinylchloride are polymerized in the presence of an ethylene homopolymer or copolymer. The products obtained contain no ungrafted styrene/acrylonitrile copolymer and more than 80% by weight of the graft polymer is chemically almost uniform in structure. The products obtained according to the invention are eminently suitable for use as coating materials and as materials which can be thermoplastically processed.
摘要:
Moulding compounds with improved impact strength and weather resistance comprising mixtures of polyvinylchloride and graft polymers prepared from ethylene/vinyl ester copolymers on which have been grafted units of monomer mixtures of aromatic vinyl compounds, (meth)acrylonitrile and aliphatic monoolefins.