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1.发明授权Combating pests with O-alkyl-O-trifluoromethylsulphinylphenyl-thiono(thiol)-phosphoric acid esters 失效用O-烷基-O-三氟甲基亚磺酰基苯硫基（硫醇） - 磷酸酯防治害虫
公开(公告)号：US4164575A
公开(公告)日：1979-08-14
申请号：US883001
申请日：1978-03-03
摘要： O-Alkyl-O-trifluoromethylsulphinylphenyl-thiono (thiol)-phosphoric acid esters of the formula ##STR1## wherein R and R.sup.1 each independently is alkyl,R.sup.2 is hydrogen, halogen or alkyl, andX is oxygen or sulphur,Which possess arthropodicidal and nematicidal properties.
摘要翻译： 其中R和R 1各自独立地为烷基，R 2为氢，卤素或烷基，且X为氧或硫，其为无定形的抗坏血酸的化合物及其盐， NEMATICIDAL属性。
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2.发明授权
公开(公告)号：US4284643A
公开(公告)日：1981-08-18
申请号：US64253
申请日：1979-08-06
申请人： Rainer Fuchs , Erich Klauke , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel , Reinhard Lantzsch , Albrecht Marhold
发明人： Rainer Fuchs , Erich Klauke , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel , Reinhard Lantzsch , Albrecht Marhold
IPC分类号： A01N37/00 , A01N37/10 , A01N37/38 , A01N43/24 , A01N43/30 , A01N43/32 , A01N47/02 , A01N53/00 , C07C59/64 , C07C69/612 , C07C255/53 , C07D317/46 , C07D319/20 , C07C121/75
CPC分类号： C07C255/00 , A01N37/10 , A01N37/38 , A01N43/30 , A01N43/32 , A01N47/02 , A01N53/00 , C07C323/00 , C07C59/64 , C07D317/46 , C07D319/20
摘要： Fluorine-containing phenylacetic acid esters of the formula ##STR1## in which R represents the radical of an alcohol customary in the case of pyrethroids,R.sup.1 represents C.sub.2-4 -alkyl, C.sub.2-4 -alkenyl or cyclopropyl,X represents H, halogen, alkyl, alkoxy, OCHF.sub.2, SCHF.sub.2, SCClF.sub.2 or SCF.sub.3 andX.sup.1 can vary widely or form a fused ring with X,the overall compound necessarily containing a fluorine atom, which compounds possess arthropodicidal properties. Intermediates therefor and an overall synthesis from an alcohol of the formula ROH and a toluene of the formula ##STR2## are also shown.
摘要翻译： 式（I）的含氟苯乙酸酯其中R表示在拟除虫菊酯类中常用的醇的基团，R 1表示C 2-4烷基，C 2-4链烯基或环丙基，X表示H ，卤素，烷基，烷氧基，OCHF 2，SCHF 2，SCClF 2或SCF 3和X 1可以广泛变化或与X形成稠环，所述化合物必须含有氟原子，该化合物具有节肢动物学特性。 还示出了其中间体和来自式ROH的醇和式“IMAGE”的甲苯的总体合成。
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3.发明授权Combating pests with novel substituted phenylcyclopropanecarboxylic acid esters 失效用新型取代的苯基环丙烷羧酸酯防治害虫
公开(公告)号：US4529557A
公开(公告)日：1985-07-16
申请号：US395766
申请日：1982-07-06
IPC分类号： C07C45/00 , A01N53/00 , A01N53/04 , A01N53/08 , C07C43/225 , C07C43/23 , C07C45/29 , C07C47/575 , C07C51/00 , C07C62/34 , C07C65/21 , C07C67/00 , C07C67/08 , C07C69/74 , C07C69/753 , C07C69/757 , C07C253/00 , C07C255/39 , C07C255/53 , C07C313/00 , C07C323/62 , C07D213/64 , C07D213/647 , C07C121/50 , C07C69/76 , C07C149/40
CPC分类号： C07D213/647 , A01N53/00 , C07C323/00 , C07C43/225 , C07C43/23 , C07C45/292 , C07C47/575 , C07C65/21
摘要： Substituted phenyl-cyclopropanecarboxylic acid esters of the formula ##STR1## in which R.sup.1 represents an alkoxy or alkylthio radical which is monosubstituted or polysubstituted by identical or different halogen substituents,R.sup.2 represents a hydrogen or halogen atom, orR.sup.1 and R.sup.2 together represent an alkylenedioxy radical which is monosubstituted or polysubstituted by identical or different halogen substituents,R.sup.3 represents a hydrogen atom, a cyano group or an alkyl, alkenyl or alkinyl radicals which is optionally monosubstituted or polysubstituted by identical or different halogen substituents,Y represents a nitrogen atom or a methinyl radical, andR.sup.4 and R.sup.5 are identical or different and represent a hydrogen or halogen atom,which possess pesticidal properties, plus novel intermediates therefor.
摘要翻译： 取代的式“IMAGE”的苯基 - 环丙烷羧酸酯，其中R 1表示被相同或不同的卤素取代基单取代或多取代的烷氧基或烷硫基，R2表示氢或卤原子，或R1和R2一起代表亚烷基二氧基 其被相同或不同的卤素取代基单取代或多取代，R 3表示氢原子，氰基或烷基，烯基或炔基，其任选被相同或不同的卤素取代基单取代或多取代，Y表示氮原子或甲基 自由基，R4和R5相同或不同，代表具有杀虫特性的氢或卤素原子，加上其新颖的中间体。
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公开(公告)号：US4405639A
公开(公告)日：1983-09-20
申请号：US374370
申请日：1982-05-03
申请人： Rainer Fuchs , Erich Klauke , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel , Reinhard Lantzsch , Albrecht Marhold
发明人： Rainer Fuchs , Erich Klauke , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel , Reinhard Lantzsch , Albrecht Marhold
IPC分类号： A01N37/00 , A01N37/10 , A01N37/38 , A01N43/24 , A01N43/30 , A01N43/32 , A01N47/02 , A01N53/00 , C07C59/64 , C07C69/612 , C07C255/53 , C07D317/46 , C07D319/20
CPC分类号： C07C255/00 , A01N37/10 , A01N37/38 , A01N43/30 , A01N43/32 , A01N47/02 , A01N53/00 , C07C323/00 , C07C59/64 , C07D317/46 , C07D319/20
摘要： Fluorine-containing phenylacetic acid esters of the formula ##STR1## in which R represents the radical of an alcohol customary in the case of pyrethroids,R.sup.1 represents C.sub.2-4 -alkyl, C.sub.2-4 -alkenyl or cyclopropyl,X represents H, halogen, alkyl, alkoxy, OCHF.sub.2, SCHF.sub.2, SCClF.sub.2 or SCF.sub.3 andX.sup.1 can vary widely or form a fused ring with X,the overall compound necessarily containing a fluorine atom, which compounds possess arthropodicidal properties. Intermediates therefor and an overall synthesis from an alcohol of the formula ROH and a toluene of the formula ##STR2## are also shown.
摘要翻译： 式（I）的含氟苯乙酸酯其中R表示在拟除虫菊酯类中常用的醇的基团，R 1表示C 2-4烷基，C 2-4链烯基或环丙基，X表示H ，卤素，烷基，烷氧基，OCHF 2，SCHF 2，SCClF 2或SCF 3和X 1可以广泛变化或与X形成稠环，所述化合物必须含有氟原子，该化合物具有节肢动物学特性。 还示出了其中间体和来自式ROH的醇和式“IMAGE”的甲苯的总体合成。
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5.发明授权O-Alkyl-O-[8-chloro-quinoxal-2-yl]-thionoalkanephosphonic acid esters 失效O-烷基-O- {8 8-氯 - 喹喔啉-2-基{9-硫代烷基膦酸酯
公开(公告)号：US4134978A
公开(公告)日：1979-01-16
申请号：US786914
申请日：1977-04-12
IPC分类号： A01N57/24 , C07F9/6509 , A01N9/36
CPC分类号： C07F9/650994 , A01N57/24
摘要： O-Alkyl-O-[8-chloro-quinoxal-2-yl]-thionoalkanephosphonic acid esters of the formula ##STR1## in which R and R.sup.1 each independently is alkyl with 1 to 6 carbon atoms, which possess arthropodicidal, especially insecticidal and acaricidal, properties.
摘要翻译： 具有式（I）的O-烷基-O- [8-氯 - 喹喔啉-2-基] - 硫代烷基膦酸酯，其中R和R 1各自独立地为具有1至6个碳原子的烷基，其具有节肢杀虫剂 ，特别是杀虫和杀螨的性质。
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6.发明授权2,2-Dimethyl-3-(2-bromo-2-phenyl-vinyl)-cyclopropanecarboxylic acid 3-phenoxybenzyl esters and pesticidal use 失效2,2-二甲基-3-（2-溴-2-苯基 - 乙烯基） - 环丙烷甲酸3-苯氧基苄酯和杀虫剂
公开(公告)号：US4279920A
公开(公告)日：1981-07-21
申请号：US74045
申请日：1979-09-10
IPC分类号： C07C69/747 , A01N53/00 , A01N53/08 , A01P7/02 , A01P7/04 , B01J27/00 , B01J27/232 , B01J31/00 , C07C61/40 , C07C67/00 , C07C67/08 , C07C67/14 , C07C253/00 , C07C255/39 , C07C313/00 , C07C323/62 , C07D317/52 , C07D317/62 , C07F9/40 , A01N43/30 , C07C69/743 , C07C121/75
CPC分类号： A01N53/00 , C07C61/40 , C07F9/4056
摘要： 2,2-Dimethyl-3-(2-bromo-2-phenyl-vinyl)-cyclopropanecarboxylic acid 3-phenoxybenzyl ester of the formula ##STR1## which possess arthropodicidal properties. In addition, the new intermediate of the formula ##STR2## is produced by reacting an .alpha.-bromo-benzyl-phosphonic acid ester of the formula ##STR3## in which R.sup.6 each independently is alkyl or phenyl, or the two radicals R.sup.6 together are alkanediyl, with a 3-formyl-2,2-dimethyl-cyclopropanecarboxylic acid ester and saponifying. Also the compounds of the formula ##STR4## which are new when R.sup.1 is not alkyl, are produced by reacting triphenylphosphine and bromine to form dibromo-triphenylphosphorane, and reacting the dibromo-triphenylphosphorane without isolation with an .alpha.-hydroxy-benzyl-phosphonic acid ester of the formula ##STR5##
摘要翻译： 具有节肢动物特性的式“IMAGE”的2,2-二甲基-3-（2-溴-2-苯基 - 乙烯基） - 环丙烷甲酸3-苯氧基苄基酯。 此外，式“IMAGE”的新中间体是通过使式“IMAGE”的α-溴 - 苄基膦酸酯反应，其中R6各自独立地为烷基或苯基，或两个基团R6一起为烷二基 ，与3-甲酰基-2,2-二甲基 - 环丙烷甲酸酯和皂化。 另外，当R1不是烷基时，新的化合物“IMAGE”也是通过使三苯基膦和溴反应形成二溴 - 三苯基正膦而制备的，并且不分离的二溴 - 三苯基正膦与α-羟基 - 苄基膦酸酯 的公式
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7.发明授权Pesticidal O-alkyl-O-(1,5-disubstituted-1,2,4-triazolyl-(3)-thiono-phosphoric (phosphonic) acid esters and ester-amides 失效杀虫剂O-烷基-O-（1,5-二取代-1,2,4-三唑基 - （3） - 硫代磷酸（膦酸）酯和酯酰胺
公开(公告)号：US4229444A
公开(公告)日：1980-10-21
申请号：US907388
申请日：1978-05-18
IPC分类号： A01N57/08 , A01N57/16 , A01N57/24 , A01N57/32 , A01P5/00 , A01P7/02 , A01P7/04 , C07D249/12 , C07F9/6518 , A01N9/36 , C07F9/65
CPC分类号： C07D249/12 , C07F9/65183
摘要： O-alkyl-O-[1,5-disubstituted-1,2,4-triazolyl-(3)]-thiono-phosphoric (phosphonic) acid esters and ester-amides of the formula ##STR1## in which R is alkyl of 1 to 6 carbon atoms,R' is alkyl, alkoxy or alkylamino of 1 to 6 carbon atoms or phenyl,R" is alkyl or cyanoalkyl of 1 to 4 carbon atoms or alkenyl of 3 or 4 carbon atoms,R'" is alkyl or cyanoalkyl with 1 to 6 carbon atoms in the alkyl radical, andX is oxygen or sulfur,which possess insecticidal and acaricidal properties.
摘要翻译： O-烷基-O- [1,5-二取代-1,2,4-三唑基 - （3）] - 硫代磷酸（膦酸）酯和式（Ⅰ）的酯酰胺，其中R R 1为具有1至6个碳原子的烷基，R'为1至6个碳原子的烷基，烷氧基或烷基氨基或苯基，R“为1至4个碳原子的烷基或氰基烷基或3或4个碳原子的烯基，R' “是烷基中具有1至6个碳原子的烷基或氰基烷基，X是具有杀虫和杀螨性质的氧或硫。
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8.发明授权O-Alkyl-N-subustituted-S-halophenoxymethyl-dithiophosphoric acid ester-amides 失效O-烷基-N-取代的S-卤代苯氧基甲基 - 二硫代磷酸酯 - 酰胺
公开(公告)号：US4036947A
公开(公告)日：1977-07-19
申请号：US638875
申请日：1975-12-08
CPC分类号： C07F9/2408
摘要： O-Alkyl-N-substituted-S-halophenoxymethyl-dithiophosphoric acid ester-amides of the formula ##STR1## in which R is alkyl with 1 to 4 carbon atoms,R.sub.1 is alkyl with 1 to 6 or alkenyl with 2 to 5 carbon atoms andX is halophenyl,Which possess insecticidal, acaricidal and nematocidal properties.
摘要翻译： 其中R为具有1至4个碳原子的烷基的式（I）的O-烷基-N-取代的S-卤代苯氧基甲基 - 二硫代磷酸酯 - 酰胺，R 1为具有1至6个碳原子的烷基或具有2至 5个碳原子，X是卤代苯基，其具有杀虫剂，杀虫剂和杀虫剂性质。
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9.发明授权Combating pests with N-acetyl-0-(2-chloro-1-fluoro-ethyl)-thionophosphoric (phosphonic) acid ester-amides 失效与N-乙酰基-O-（2-氯-1-氟 - 乙基） - 硫代磷酸（膦酸）酸酯 - 酰胺相结合的害虫
公开(公告)号：US4166850A
公开(公告)日：1979-09-04
申请号：US932073
申请日：1978-08-08
CPC分类号： C07F9/4492 , A01N57/28 , C07F9/20 , C07F9/2408 , C07F9/2487 , C07F9/425 , C07F9/4438
摘要： N-Acetyl-0-(2-chloro-1-fluoro-ethyl)-thionophosphoric (phosphonic) acid ester-amides of the formula ##STR1## IN WHICH R is alkyl or alkoxy, which possess arthropodicidal and nematicidal properties.
摘要翻译： 式中的N-乙酰基-O-（2-氯-1-氟 - 乙基） - 硫代磷酸（膦酸） - 酸酯 - 酰胺，其中R是烷基或烷氧基，其具有节肢杀虫和杀线虫性质。
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10.发明授权O-Alkyl-O-[1-cyanoalkyl-5-substituted-merc apto-triazol(3)yl]-(thiono)-phosphoric(phosphonic) acid esters or ester-amides 失效O-烷基-O-（1-氰基烷基-5-取代的三烯三唑（3）YL） - （硫代） - 磷酸（磷酸）酯或酯 -
公开(公告)号：US3987168A
公开(公告)日：1976-10-19
申请号：US576074
申请日：1975-05-09
IPC分类号： A01N57/08 , A01N57/24 , C07D249/12 , C07F9/6518 , A01N9/36 , C07F9/65
CPC分类号： C07D249/12 , C07F9/65183
摘要： O-Alkyl-O-[1-cyanoalkyl-5-substituted-mercapto-triazol(3)yl]-(thiono)-phosphoric (phosphonic) acid esters or ester-amides of the formula ##EQU1## in which R is alkyl with 1 to 6 carbon atoms,R' is alkyl, alkoxy or alkylamino each with 1 to 6 carbon atoms, amino or phenyl,R" is alkenyl with 2 to 6 carbon atoms, or alkyl, cyanoalkyl or alkylthioalkyl with 1 to 4 carbon atoms in each alkyl moiety,R'" is cyanoalkyl with 1 to 4 carbon atoms in the alkyl moiety, andX is oxygen or sulfur,Which possess insecticidal, acaricidal and nematocidal properties.
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