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    Enhancement of the storage stability of organic phosphites and phosphonites
    1.
    发明授权
    Enhancement of the storage stability of organic phosphites and phosphonites 失效
    提高有机亚磷酸盐和亚膦酸盐的储存稳定性

    公开(公告)号：US5856550A

    公开(公告)日：1999-01-05

    申请号：US867112

    申请日：1997-06-02

    申请人： Helmut Linhart ,  Udo Quotschalla ,  Jean-Roch Pauquet ,  Ronald Salathe ,  Jurg Zingg

    发明人： Helmut Linhart ,  Udo Quotschalla ,  Jean-Roch Pauquet ,  Ronald Salathe ,  Jurg Zingg

    IPC分类号： C07F9/02 ,  C07F9/141 ,  C07F9/48

    CPC分类号： C07F9/025

    摘要： Described are compositions comprising (a) 25 to 99% of organic phosphite or phosphonite, based on the total weight of the composition, (b) an effective stabilizing amount of organic amine, and (c) an effective stabilizing amount of acid-binding metal salt, wherein said composition comprises no organic polymers or alkali metal phosphates as further components, as well as a process for stabilising organic phosphites or phosphonites against hydrolysis by addition of organic amine and acid-binding metal salt. The compositions are distinguished by their excellent stability to hydrolysis and have good storage stability even at high atmospheric humidity. The novel compositions and process products can be used with advantage as stabilisers for organic material against the harmful action of heat, oxygen and/or light.

    摘要翻译： 描述的是包含（a）25至99％的有机亚磷酸酯或亚膦酸酯，基于组合物的总重量，（b）有效稳定量的有机胺，和（c）有效稳定量的酸结合金属 盐，其中所述组合物不包含作为其它组分的有机聚合物或碱金属磷酸盐，以及通过加入有机胺和酸结合金属盐来稳定有机亚磷酸酯或亚膦酸酯以防止水解的方法。 组合物的特征在于其优异的水解稳定性，即使在高的大气湿度下也具有良好的储存稳定性。 新颖的组合物和工艺产品可以有利地用作有机材料的稳定剂，以抵抗热，氧和/或光的有害作用。

    Enhancing the storage stability of organic phosphites and phosphonites
    2.
    发明授权
    Enhancing the storage stability of organic phosphites and phosphonites 失效
    提高有机亚磷酸盐和亚膦酸盐的储存稳定性

    公开(公告)号：US5840954A

    公开(公告)日：1998-11-24

    申请号：US129704

    申请日：1993-09-30

    申请人： Udo Quotschalla ,  Helmut Linhart

    发明人： Udo Quotschalla ,  Helmut Linhart

    IPC分类号： C07D211/46 ,  C07D211/58 ,  C07D241/04 ,  C07D491/113 ,  C07F9/141 ,  C07F9/145 ,  C07F9/48 ,  C07F9/6574 ,  C08K5/3435 ,  C08K5/524 ,  C08K5/5393 ,  C09K15/18 ,  C09K15/30

    CPC分类号： C08K5/5393 ,  C08K5/3435 ,  C08K5/524

    摘要： The invention relates to a process for stabilizing an organic phosphite or phosphonite or a mixture of organic phosphites or phosphonites against hydrolysis, which comprises adding, as the stabilizer, a compound from the class of sterically hindered amines, so that the stabilized phosphite or phosphonite contains 0.1 to 25% by weight of the amine compound (relative to the phosphite or phosphonite). Compositions comprising organic phosphite or phosphonite and sterically hindered amines are notable for excellent hydrolytic stability and have a long shelf life even at high atmospheric humidity. The products of the process according to the invention are very useful as stabilizers for organic material, in particular organic polymers, for example synthetic polymers, against the damaging influence of heat, oxygen and/or light.

    摘要翻译： 本发明涉及一种使有机亚磷酸酯或亚膦酸盐或有机亚磷酸酯或亚膦酸酯与水解产物的混合物稳定的方法，其包括加入来自空间位阻胺类化合物作为稳定剂的稳定剂，使得稳定的亚磷酸酯或亚膦酸酯包含 胺化合物（相对于亚磷酸酯或亚膦酸酯）为0.1〜25重量％。 包含有机亚磷酸酯或亚膦酸酯和空间位阻胺的组合物具有优异的水解稳定性，并且即使在高的大气湿度下也具有长的保质期。 根据本发明的方法的产物作为有机材料的稳定剂，特别是有机聚合物，例如合成聚合物，对抗热，氧和/或光的有害影响是非常有用的。

    Process for stabilizing trivalent phosphorus compounds with amines
    3.
    发明授权
    Process for stabilizing trivalent phosphorus compounds with amines 失效
    用胺稳定三价磷化合物的方法

    公开(公告)号：US5371263A

    公开(公告)日：1994-12-06

    申请号：US129705

    申请日：1993-09-30

    申请人： Udo Quotschalla ,  Helmut Linhart

    发明人： Udo Quotschalla ,  Helmut Linhart

    IPC分类号： C07F9/48 ,  C07F9/6574 ,  C08K5/17 ,  C08K5/3435 ,  C08K5/3462 ,  C08K5/524 ,  C08K5/5393 ,  C09K15/16 ,  C07F9/141

    CPC分类号： C08K5/3435 ,  C08K5/17 ,  C08K5/3462 ,  C08K5/524 ,  C08K5/5393

    摘要： The invention relates to a process for stabilizing a crystalline organic phosphite or phosphonite against hydrolysis, which comprises introducing a mixture comprising phosphite or phosphonite, a solvent or solvent mixture, and 0.1 to 100% by weight (relative to phosphite or phosphonite) of an amine and having a temperature of 50.degree.-100.degree. C. as a homogeneous melt into a liquid crystallization medium whose temperature during the addition is maintained 10.degree.-70.degree. C. below the temperature of the melt.The phosphites or phosphonites stabilized according to the invention are distinguished by their excellent resistance to hydrolysis and have a long shelf life even at high atmospheric humidity. They can be advantageously used as stabilizers for organic material against the damaging effect of heat, oxygen, and/or light.

    摘要翻译： 本发明涉及一种使结晶有机亚磷酸酯或亚膦酸酯水解稳定的方法，其包括将包含亚磷酸酯或亚膦酸酯，溶剂或溶剂混合物的混合物和0.1至100重量％（相对于亚磷酸酯或亚膦酸酯）的胺 并将温度为50℃-100℃作为均匀熔体加入到液体结晶介质中，其加入温度保持在熔体温度以下10〜-70℃。 根据本发明稳定的亚磷酸酯或亚膦酸酯的特征在于其优异的耐水解性，并且即使在高的大气湿度下也具有长的保质期。 它们可以有利地用作有机材料的稳定剂，以抵抗热，氧和/或光的破坏作用。

    Trivalent phosphorus compounds stabilized with amines
    4.
    发明授权
    Trivalent phosphorus compounds stabilized with amines 失效
    用胺稳定的三价磷化合物

    公开(公告)号：US5534645A

    公开(公告)日：1996-07-09

    申请号：US298894

    申请日：1994-08-31

    申请人： Udo Quotschalla ,  Helmut Linhart

    发明人： Udo Quotschalla ,  Helmut Linhart

    IPC分类号： C07F9/48 ,  C07F9/6574 ,  C08K5/17 ,  C08K5/3435 ,  C08K5/3462 ,  C08K5/524 ,  C08K5/5393 ,  C09K15/16 ,  C09K15/32

    CPC分类号： C08K5/3435 ,  C08K5/17 ,  C08K5/3462 ,  C08K5/524 ,  C08K5/5393

    摘要： The invention relates to a process for stabilizing a crystalline organic phosphite or phosphonite against hydrolysis, which comprises introducing a mixture comprising phosphite or phosphonite, a solvent or solvent mixture, and 0.1 to 100% by weight (relative to phosphite or phosphonite) of an amine and having a temperature of 50.degree.-100.degree. C. as a homogeneous melt into a liquid crystallization medium whose temperature during the addition is maintained 10.degree.-70.degree. C. below the temperature of the melt.The phosphites or phosphonites stabilized according to the invention are distinguished by their excellent resistance to hydrolysis and have a long shelf life even at high atmospheric humidity. They can be advantageously used as stabilizers for organic material against the damaging effect of heat, oxygen, and/or light.

    摘要翻译： 本发明涉及一种使结晶有机亚磷酸酯或亚膦酸酯水解稳定的方法，其包括将包含亚磷酸酯或亚膦酸酯，溶剂或溶剂混合物的混合物和0.1至100重量％（相对于亚磷酸酯或亚膦酸酯）的胺 并将温度为50℃-100℃作为均匀熔体加入到液体结晶介质中，其加入温度保持在熔体温度以下10〜-70℃。 根据本发明稳定的亚磷酸酯或亚膦酸酯的特征在于其优异的耐水解性，并且即使在高的大气湿度下也具有长的保质期。 它们可以有利地用作有机材料的稳定剂，以抵抗热，氧和/或光的破坏作用。

    Stabilization systems from triarylphosphites and phenols
    5.
    发明授权
    Stabilization systems from triarylphosphites and phenols 失效
    三芳基亚磷酸酯和酚类的稳定体系

    公开(公告)号：US4187212A

    公开(公告)日：1980-02-05

    申请号：US802921

    申请日：1977-06-02

    申请人： Horst Zinke ,  Hans J. Lorenz ,  Helmut Linhart

    发明人： Horst Zinke ,  Hans J. Lorenz ,  Helmut Linhart

    IPC分类号： C08K5/134 ,  C08K5/526 ,  C08K5/52

    CPC分类号： C08K5/1345 ,  C08K5/526

    摘要： Stabilization system consisting of a triarylphosphite of the general formula ##STR1## wherein R.sub.1 represents tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl, and one ofR.sub.2 and R.sub.3 is hydrogen and the other is hydrogen, methyl, tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl,and a phenolic antioxidant, for stabilizing polyolefins.

    摘要翻译： 其中R1代表叔丁基，1,1-二甲基丙基，环己基或苯基，R 2和R 3之一是氢，另一个是氢，甲基，叔丁基 ，1,1-二甲基丙基，环己基或苯基，以及酚类抗氧化剂，用于稳定聚烯烃。