摘要:
Water-insoluble compositions having substantial antioxidant activity which may be used as plasticizers are produced by liquid phase reaction of (a) dimercaptans or mercapto alcohols or combination of these with diols or polyols, (b) aldehydes and/or ketones, and (c) monomercaptans and/or mono-alcohols in the presence of an acid catalyst.
摘要:
New compounds having the formula ##EQU1## wherein R.sub.1 represents a hydrocarbon moiety having from 1 to 7 carbontoms, R.sub.2 is hydrogen, methyl or ethyl, and R.sub.3 is hydrogen, formyl or acetyl. The compounds are useful in the preparation, modification and intensification of a great variety of flavor and perfume compositions.
摘要翻译:具有式CH3 | R1-C-CH2-CH-R2 I || SHOR3的新化合物,其中R1表示具有1至7个碳原子的烃部分,R2是氢,甲基或乙基,R3是氢,甲酰基或乙酰基 。 这些化合物可用于各种风味和香料组合物的制备,改性和增强。
摘要:
REACTING HYDROGEN SULFIDE WITH MON OR POLY, TERMINAL OR NON-TERMINAL, ALIPHATIC OR CYCLOALIPHATIC EPOXIDE AT A TEMPERATURE OF FROM -20*C. TO 150*C., IN THE PRESENCE OF 0.01 TO 10% BY WEIGHT, BASED ON THE EPOXIDE, OF AN ALIPHATIC, CYCLOALIPHATIC, AROMATIC AND/OR HETEROCYCLIC, PRIMARY OR SECONDARY AMINES, TO PRODUCE A HIGHER MOLECULAR WEIGHT HYDROXYALKYL MERCAPTAN.
USEFUL AS PESTICIDES, LUBRICANT ADDITIVES AND INTERMEDIATES FOR SURFACANTS AND TO A NOVEL PROCESS FOR THEIR PREPARATION.
R-CH(-OH)-CH(-R1)-S-
WHEREIN RI IS AN ALIPHATIC GROUP OF 1 TO 22 CARBON ATOMS, R1 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND ALIPHATIC GROUP OF 1 TO 21 CARBONS WITH THE SUM OF CARBON ATOMS IN R AND R1 BEING 4 TO 22 AND R AND R1, TAKEN TOGETHER WITH THE ETHYLENE GROUP TO WHICH THEY ARE ATTACHED FORM A CYCLOALIPHATIC RING OF 6 TO 12 CARBON ATOMS AND A IS SELECTED FROM THE GROUP CONSISTING OF ALIPHATIC AND CYCOALIPHATIC OF 6 TO 24 CARBON ATOMS OPTIONALLY SUBSTITUTED WTH ONE OR MORE GROUPS OF THE FORMULA
摘要:
Polymercaptans especially suitable as epoxy resin curing agents are produced by reacting a polyhalo compound with sodium sulfhydrate in the presence of dimethyl sulfoxide, dimethylformamide, a dimethylformamide-(lower) alkyl alcohol mixture or a dimethyl sulfoxide-(lower)alkyl alcohol mixture as a solvent for the reaction system.
WHEREIN R is an alkyl or aralkyl group; each n is an integer of from five to 50; A is a sulfide, sulfoxide or sulfone group; R1 is hydrogen or a lower alkyl group; and Ro is a halophenyl group, an alkyl or aralkyl group, halophenylethyl or halobenzyl group, or a group of the formula
WHEREIN R, R1 and n are defined above. These compositions have surfactant and/or biological utilities.
摘要:
Disclosed are 2,3-diamino-1,4-butanedithiol; 4,5-diamino-1,2-dithiane; and their N-acyl and N-alkyl derivatives. Also disclosed are processes for preparing the disclosed compounds; pharmaceutical compositions comprising such compounds; and a method of treatment comprising administering such compounds and compositions when an antihypertensive effect or radioprotective effect is indicated.
摘要:
Aminopeptidase inhibitory activity is exhibited by compounds having the formula ##STR1## wherein R.sub.1 is hydrogen, alkyl, carboxyalkyl, halo-substituted alkyl, hydroxyalkyl, aminoalkyl, mercaptoalkyl, alkylthioalkyl, (cycloalkyl)alkyl, (heteroaryl)alkyl, arylalkyl, carbamoylalkyl, guanidinylalkyl or heteroaryl; andR.sub.2 and R.sub.3 are each independently hydrogen, alkyl, cycloalkyl, hydroxyalkyl, aminoalkyl, aryl, arylalkyl, heteroaryl or heteroarylalkyl.
摘要:
A process for the preparation of 2-hydroxy-4-methylthiobutyric acid having improved color, odor and lower viscosity. 2-hydroxy-4-methylthiobutyric acid which is also known as 2-hydroxy-4-(methylthio) butanoic acid, is hydrolyzed with sulfuric acid having an initial strength of between about 50% by weight and about 70% by weight on an organic-free basis, thereby producing an intermediate aqueous hydrolysis product solution containing 2-hydroxy-4-methylthiobutyramide. The 2-hydroxy-4-methylthiobutyramide is hydrolyzed with sulfuric acid having a strength of between about 30% by weight and about 50% by weight on an organic-free basis to produce an aqueous hydrolyzate containing 2-hydroxy-4-methylthiobutyric acid. The hydrolyzate solution is contacted with a substantially water-immiscible organic solvent in a liquid-liquid extraction system to produce an extract comprising the solvent and 2-hydroxy-4-methylthiobutyric acid transferred from the hydrolyzate. The acid product is then recovered from the extract.
摘要:
THIS INVENTION RELATES TO AN IMPROVED PROCESS FOR THE PREPARATION OF POLYETHER THIOETHERS WHICH ARE SUITABLE FOR USE AS PLASTICIZERS. IT HAS BEEN FOUND THAT THE CONDENSATION OF THIOGLYCOL WHICH IS CATALYZED WITH PHOSPHOROUS ACID CAN BE SUBSTANTIALLY ACCELERATED BY ALSO ADDING A SMALL QUANTITY OF A SALT OF METAL FROM THE GROUP II, II-A, VIII-A OF THE PERIODIC SYSTEM AND AN ORGANIC SULPHONIC ACID.