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    Stabilization systems from triarylphosphites and phenols
    1.
    发明授权
    Stabilization systems from triarylphosphites and phenols 失效
    三芳基亚磷酸酯和酚类的稳定体系

    公开(公告)号：US4187212A

    公开(公告)日：1980-02-05

    申请号：US802921

    申请日：1977-06-02

    申请人： Horst Zinke ,  Hans J. Lorenz ,  Helmut Linhart

    发明人： Horst Zinke ,  Hans J. Lorenz ,  Helmut Linhart

    IPC分类号： C08K5/134 ,  C08K5/526 ,  C08K5/52

    CPC分类号： C08K5/1345 ,  C08K5/526

    摘要： Stabilization system consisting of a triarylphosphite of the general formula ##STR1## wherein R.sub.1 represents tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl, and one ofR.sub.2 and R.sub.3 is hydrogen and the other is hydrogen, methyl, tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl,and a phenolic antioxidant, for stabilizing polyolefins.

    摘要翻译： 其中R1代表叔丁基，1,1-二甲基丙基，环己基或苯基，R 2和R 3之一是氢，另一个是氢，甲基，叔丁基 ，1,1-二甲基丙基，环己基或苯基，以及酚类抗氧化剂，用于稳定聚烯烃。

    Stabilized, chlorine-containing polymer compositions
    3.
    发明授权
    Stabilized, chlorine-containing polymer compositions 失效
    稳定的含氯聚合物组合物

    公开(公告)号：US5516827A

    公开(公告)日：1996-05-14

    申请号：US377297

    申请日：1995-01-24

    申请人： Johannes Kaufhold ,  Horst Zinke

    发明人： Johannes Kaufhold ,  Horst Zinke

    IPC分类号： C08K5/5398 ,  C08K5/57 ,  C08K5/09 ,  C08K5/48 ,  C08K5/51

    CPC分类号： C08K5/5398 ,  C08K5/57

    摘要： Compositions comprising a chlorine-containing polymer and a stabilizer mixture comprising:a) at least one tin alcoholate or tin carboxylate of the formula[(R.sub.2).sub.2 Sn(OR')].sub.2 O (Ia);[(R.sub.2)Sn(OR').sub.2 ].sub.2 O (Ib);(R.sub.2)Sn(OR')O (Ic);[-(R.sub.2)Sn(OR')O--].sub.m (Id);[-(R.sub.1 CO.sub.2 Sn(R.sub.2).sub.2 ].sub.2 O (IIa);or[-(R.sub.2).sub.2 Sn--O.sub.2 C--R.sub.3 --CO.sub.2 --{(R.sub.2).sub.2 SnO{(R.sub.2).sub.2 SnO}.sub.i -].sub.n (IIb);b) at least one organic zinc carboxylate, zinc phenoxide or a tin chloride of the formula[(R.sub.1 CO.sub.2).sub.x (R.sub.2).sub.y CL.sub.z Sn].sub.n O.sub.n-1 (III)andc) at least one thiophosphate or thiophosphite of the formula(R.sub.6 S).sub.3 P.dbd.X.sub.b (IV)where the individual radicals are as defined in claim 1.

    摘要翻译： 包含含氯聚合物和稳定剂混合物的组合物，其包含：a）至少一种式[（R2）2Sn（OR'）] 2 O（Ia）的锡醇化物或羧酸锡; [（R2）Sn（OR'）2] 2O（Ib）; （R2）Sn（OR'）O（Ic）; [ - （R2）Sn（OR'）O-] m（Id）; [ - （R1CO2Sn（R2）2] 2O（IIa）;或[ - （R2）2Sn-O2C-R3-CO2- {（R2）2SnO {（R2）2SnO} i-] n（IIb） 至少一种式[（R1CO2）x（R2）yCLzSn] nOn-1（Ⅲ）的至少一种有机羧酸锌，苯酚锌或氯化锡，和c）至少一种式（R6S）3P = Xb的硫代磷酸酯或硫代亚磷酸酯 IV）其中各个基团如权利要求1所定义。

    Trisamidodithionodiphospates
    4.
    发明授权
    Trisamidodithionodiphospates 失效
    三氨基二硫代磷酸酯

    公开(公告)号：US5360563A

    公开(公告)日：1994-11-01

    申请号：US68369

    申请日：1993-05-27

    申请人： Horst Zinke ,  Rolf Schumacher

    发明人： Horst Zinke ,  Rolf Schumacher

    IPC分类号： C07F9/24 ,  C07F9/22 ,  C07F9/572 ,  C07F9/59 ,  C07F9/6533 ,  C10M137/16 ,  C10N30/06 ,  C10N40/08 ,  C10N40/25

    CPC分类号： C07F9/6533 ,  C07F9/22 ,  C07F9/5721 ,  C10M137/16 ,  C10M2223/047 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/102 ,  C10N2240/103 ,  C10N2240/104 ,  C10N2240/105 ,  C10N2240/106

    摘要： There are disclosed compounds of formulae I and Ia ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.13 alkyl which may be interrupted by oxygen, C.sub.5 -C.sub.6 cycloalkyl or, together with the linking N-atom, are a group of formula ##STR2## R is hydrogen or methyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.13 alkyl, andR.sub.4 and R.sub.5 are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl which may be interrupted by oxygen, C.sub.5 -C.sub.6 cycloalkyl or, together with the linking N-atom, are a group of formula ##STR3## withe proviso that R.sub.3, R.sub.4 and R.sub.5 are not simultaneously hydrogen and HNR.sub.1 R.sub.2 are not identical with NR.sub.3 R.sub.4 R.sub.5.The compounds are suitable for use as lubricant additives.

    摘要翻译： 公开了式I和Ia的化合物（Ia）其中R 1和R 2各自独立于可被氧，C 5 -C 6环烷基间隔的另一个C 1 -C 13烷基，或者与连接 N原子是式的基团R是氢或甲基，R 3是氢或C 1 -C 13烷基，R 4和R 5各自独立地是氢，可被氧中断的C 1 -C 18烷基， C 6环烷基或与连接的N-原子一起是式（Ia）的基团，条件是R3，R4和R5不同时为氢，且HNR1R2与NR3R4R5不相同。 该化合物适合用作润滑剂添加剂。

    Asymmetric aryl phosphites
    10.
    发明授权
    Asymmetric aryl phosphites 失效
    不对称芳基亚磷酸酯

    公开(公告)号：US5401845A

    公开(公告)日：1995-03-28

    申请号：US212756

    申请日：1994-03-11

    申请人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

    发明人： Rita Pitteloud ,  Peter Hofmann ,  Rudolf Maul ,  Volker Schenk ,  Eduard Troxler ,  Horst Zinke

    IPC分类号： C07F9/145 ,  C07F9/146 ,  C07F9/59 ,  C08K5/52 ,  C08K5/526 ,  C08K5/529 ,  C08L23/00 ,  C08L101/00

    CPC分类号： C08K5/526 ,  C07F9/145 ,  C07F9/146 ,  C07F9/591 ,  C07F9/595

    摘要： Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.8 alkyl, and n is 3-6, with the proviso that R.sup.1 is not a phenyl radical which is substituted in both ortho-positions to the carbon atom bonded to the oxygen atom,if x=2, R.sup.1 is C.sub.2 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkylene which is interrupted by --NR.sup.5, --O-- or --S--, or is a ##STR3## radical, and, if x=3, R.sup.1 is C.sub.4 -C.sub.12 alkanetriyl or a ##STR4## group in which m is 1-4, are suitable as stabilizers for organic materials which are sensitive to thermal, oxidative and/or photoinduced degradation.

    摘要翻译： 式I的化合物（I）其中x为1,2或3，如果x = 1，则R1为C1-C30烷基，被卤素取代的C1-C18烷基，-COOR2，-CN，-NR3R4或 被-CONR 3 R 4，被-NR 5 - ，-O-或-S-，C 3 -C 18烯基，C 5 -C 12环烷基，苯基-C 1 -C 4烷基，未被取代或被C 1 -C 12烷基取代的苯基，卤素， 苯基-C 1 -C 4烷基和/或C 1 -C 4烷氧基，或者R 1为萘基，R 2，R 3，R 4和R 5彼此独立地为氢，C 1 -C 18烷基， C 1 -C 12烷基或苯基-C 1 -C 4烷基，R 6是氢，甲基，烯丙基或苄基，R 7是氢或-OR 9，R 8是氢或甲基，R 9是氢或C 1 -C 30烷基，R 10和R 11彼此独立地是氢 或C 1 -C 8烷基，n为3-6，条件是R 1不是在与氧原子键合的碳原子的两个邻位被取代的苯基，如果x = 2，则R1为C2-C18亚烷基 被-NR 5，-O-或-S-中断的C 2 -C 18亚烷基，或者是a 如果x = 3，则R 1为C 4 -C 12烷基三乙基或其中m为1-4的基团，适用于对热，氧化和/或光诱导降解敏感的有机材料的稳定剂 。