公开(公告)号：US20210122878A1

公开(公告)日：2021-04-29

申请号：US17123758

申请日：2020-12-16

申请人： Henkel AG & Co. KGaA

发明人： Jan-Erik Damke ,  Johann Klein ,  Marion Marquardt ,  Esteban Mejia ,  Udo Kragl

IPC分类号： C08G65/26 ,  C09D171/02 ,  C09J171/02 ,  C09K3/10

摘要： The present invention is directed to supported catalyst having utility in the polymerization and co-polymerization of epoxide monomers, said supported catalyst having the general Formula (I): [DMCC]*b Supp  (I) wherein: [DMCC] denotes a double metal cyanide complex which comprises a double metal cyanide (DMC) compound, at least one organic complexing agent and a metal salt; Supp denotes a hydrophobic support material; and, b represents the average proportion by weight of said support material, based on the total weight of [DMCC] and Supp, and is preferably in the range 1 wt. %≤b≤99 wt. %.

公开(公告)号：US20210040269A1

公开(公告)日：2021-02-11

申请号：US17075482

申请日：2020-10-20

申请人： Henkel AG & Co. KGaA

发明人： Marta Woznicka ,  Swarup Ghosh ,  Marion Marquardt ,  Esteban Mejia ,  Udo Kragl ,  Christina Despotopoulou ,  Jan-Erik Damke ,  Johann Klein

IPC分类号： C08G77/46 ,  C08L53/00 ,  C08G18/61 ,  C08G18/10

摘要： The present invention is directed to a hydroxyl-functionalized polyether-polysiloxane block copolymer of the structure A(-X—B)n wherein: A represents said polysiloxane block; B represents said polyether block; X is a linker group characterized by including the moiety Si—C—C— of which said Si is the terminal silicon atom of the polysiloxane block A; and, n is an integer of from 2 to 4, said block copolymer being further characterized by a terminal unsaturation of less than 0.04 meq/g, preferably less than 0.03 meq/g and more preferably less than 0.025 meq/g and the method for producing thereof.

公开(公告)号：US11883803B2

公开(公告)日：2024-01-30

申请号：US17123758

申请日：2020-12-16

申请人： Henkel AG & Co. KGaA

发明人： Jan-Erik Damke ,  Johann Klein ,  Marion Marquardt ,  Esteban Mejia ,  Udo Kragl

IPC分类号： B01J27/26 ,  C08G65/26 ,  C09D171/02 ,  C09J171/02 ,  C09K3/10 ,  C07F15/00 ,  C01C3/11 ,  C01C3/00 ,  C07F7/00 ,  C07F13/00 ,  C07F1/08 ,  C07F3/06 ,  C07F9/00 ,  C07F11/00

CPC分类号： B01J27/26 ,  C01C3/001 ,  C01C3/11 ,  C07F1/08 ,  C07F3/06 ,  C07F7/00 ,  C07F9/00 ,  C07F11/00 ,  C07F13/00 ,  C07F15/00 ,  C08G65/2609 ,  C08G65/2663 ,  C08G65/2693 ,  C09D171/02 ,  C09J171/02 ,  C09K3/10 ,  C09K2200/0657

摘要： The present invention is directed to supported catalyst having utility in the polymerization and co-polymerization of epoxide monomers, said supported catalyst having the general Formula (I):

[DMCC]*b Supp  (I)

wherein:

[DMCC] denotes a double metal cyanide complex which comprises a double metal cyanide (DMC) compound, at least one organic complexing agent and a metal salt;
Supp denotes a hydrophobic support material; and,
b represents the average proportion by weight of said support material, based on the total weight of [DMCC] and Supp, and is preferably in the range 1 wt. %≤b≤99 wt. %.

公开(公告)号：US09458286B2

公开(公告)日：2016-10-04

申请号：US14041075

申请日：2013-09-30

申请人： HENKEL AG & CO. KGAA

发明人： Lars Zander ,  Christiane Kunze ,  Johann Klein ,  Eckhard Paetzold ,  Marion Marquardt ,  Udo Kragl

IPC分类号： C08G59/68 ,  C08G65/04 ,  B01J31/02 ,  C08G64/34

CPC分类号： C08G59/686 ,  B01J31/0202 ,  B01J2231/14 ,  C08G64/34

摘要： The invention relates to a catalyst for catalysing the polymerisation of epoxides, and which is to be improved such that it allows a more efficient reaction to be carried out. This is achieved by providing a catalyst obtainable by mixing a) at least one double metal cyanide compound, b) at least one organic complexing agent, and c) at least one primary alcohol with 6 to 24 C atoms. In addition, the invention relates to a method for the polymerisation of epoxides, and to the use of the claimed catalyst for the polymerisation of epoxides and the copolymerisation of epoxides with carbon dioxide.

摘要翻译： 本发明涉及一种用于催化环氧化物聚合的催化剂，并且其被改进使得其能够进行更有效的反应。 这通过提供可通过混合a）至少一种双金属氰化物化合物，b）至少一种有机络合剂和c）至少一种具有6至24个C原子的伯醇获得的催化剂来实现。 此外，本发明涉及环氧化物聚合的方法，以及所要求保护的催化剂用于环氧化物聚合的用途以及环氧化物与二氧化碳的共聚。

公开(公告)号：US20140031519A1

公开(公告)日：2014-01-30

申请号：US14041075

申请日：2013-09-30

申请人： HENKEL AG & CO. KGAA

发明人： Lars Zander ,  Christiane Kunze ,  Johann Klein ,  Eckhard Paetzold ,  Marion Marquardt ,  Udo Kragl

IPC分类号： C08G59/68

CPC分类号： C08G59/686 ,  B01J31/0202 ,  B01J2231/14 ,  C08G64/34

摘要： The invention relates to a catalyst for catalysing the polymerisation of epoxides, and which is to be improved such that it allows a more efficient reaction to be carried out. This is achieved by providing a catalyst obtainable by mixing a) at least one double metal cyanide compound, b) at least one organic complexing agent, and c) at least one primary alcohol with 6 to 24 C atoms. In addition, the invention relates to a method for the polymerisation of epoxides, and to the use of the claimed catalyst for the polymerisation of epoxides and the copolymerisation of epoxides with carbon dioxide.

摘要翻译： 本发明涉及一种用于催化环氧化物聚合的催化剂，并且其被改进使得其能够进行更有效的反应。 这通过提供可通过混合a）至少一种双金属氰化物化合物，b）至少一种有机络合剂和c）至少一种具有6至24个C原子的伯醇获得的催化剂来实现。 此外，本发明涉及环氧化物聚合的方法，以及所要求保护的催化剂用于环氧化物聚合的用途以及环氧化物与二氧化碳的共聚。