公开(公告)号：US5399657A

公开(公告)日：1995-03-21

申请号：US142737

申请日：1993-10-26

申请人： Henricus H. M. van Hout ,  Christianus J. J. Maas ,  Laurus van der Wekke ,  Martin H. Oyevaar

发明人： Henricus H. M. van Hout ,  Christianus J. J. Maas ,  Laurus van der Wekke ,  Martin H. Oyevaar

IPC分类号： C07C68/02 ,  C07C69/96 ,  C08G64/14 ,  C08G64/00

CPC分类号： C08G64/14 ,  C07C68/02

摘要： The invention relates to a method of preparing a compound of formula 1 ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 correspond to H, a branched or non-branched, optionally substituted alkyl group, or an optionally substituted aryl group, suitable as a chain stopper in the preparation of an aromatic polycarbonate, by reaction of a compound of formula 2 ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 have the meanings described hereinbefore, with phosgene, comprising the continuous supply of the compound of formula 2 and phosgene to a solution of phosgene in a solvent, the temperature being kept at a value between 0.degree. and 15.degree. C. and the pH being kept at a value between 1 and 6.

摘要翻译： 本发明涉及制备式1化合物的方法（1）其中R 1，R 2和R 3对应于H，支链或非支链的任选取代的烷基或任选取代的芳基，其适于 通过将上述式2的化合物与光气反应制备芳族聚碳酸酯的链终止剂，包括连续供给式2化合物和光气至光气在溶剂中的溶液，温度为 保持在0℃和15℃之间的值，并且pH保持在1和6之间的值。

公开(公告)号：US06262218B1

公开(公告)日：2001-07-17

申请号：US09450408

申请日：1999-11-29

申请人： Kazushige Inoue ,  Hiromi Ishida ,  Tomoaki Shimoda ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout ,  Monica M. Marugan ,  David M. Dardaris ,  Patrick J. McCloskey

发明人： Kazushige Inoue ,  Hiromi Ishida ,  Tomoaki Shimoda ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout ,  Monica M. Marugan ,  David M. Dardaris ,  Patrick J. McCloskey

IPC分类号： C08G6400

CPC分类号： C08G64/14 ,  C08G64/307 ,  G11B7/2534

摘要： Increasing the endcap level to a level greater than about 90% for Optical Quality (OQ) Melt Polycarbonate significantly reduces the as-molded static charge for injection molded parts for Optical Disc applications. The use of resins with higher endcap levels in combination with antistatic additives provides a highly robust formulation suitable for even the most demanding emerging formats as Digital Versatile Disc (DVD) and in all commercial Optical media molding machines. Thus, optical quality polycarbonates are prepared by performing a base-catalyzed polymerization of a diaryl carbonate and a dihydric phenol under conditions effective to produce a polycarbonate product having an endcap level of 90% or greater.

摘要翻译： 将端盖水平提高到光学质量（OQ）的大约90％以上熔融聚碳酸酯显着降低了用于光盘应用的注塑部件的模制静电荷。 使用具有更高端帽水平的树脂与抗静电添加剂相结合提供了高度鲁棒的配方，适用于甚至最苛刻的新兴格式，如数字多功能光盘（DVD）和所有商业光学介质成型机。 因此，通过在有效地制备端帽水平为90％以上的聚碳酸酯制品的条件下进行碳酸二芳基酯和二元酚的碱催化聚合来制备光学质量的聚碳酸酯。

公开(公告)号：US06022942A

公开(公告)日：2000-02-08

申请号：US225413

申请日：1999-01-05

申请人： Kenichi Ishiwa ,  Henricus H. M. van Hout ,  Ali Dhinojwala ,  Niles R. Rosenquist ,  Paul D. Sybert ,  Steven F. Hubbard ,  Paul C. Raymond, III ,  Joseph A. King, Jr. ,  Gary C. Davis

发明人： Kenichi Ishiwa ,  Henricus H. M. van Hout ,  Ali Dhinojwala ,  Niles R. Rosenquist ,  Paul D. Sybert ,  Steven F. Hubbard ,  Paul C. Raymond, III ,  Joseph A. King, Jr. ,  Gary C. Davis

IPC分类号： C08G63/64 ,  C08G64/06 ,  G11B7/253 ,  C08G64/00

CPC分类号： G11B7/2534 ,  C08G63/64 ,  C08G64/06

摘要： There is provided herein an optical storage media which has low VBR. In a preferred embodiment, there is provided an optical disk comprising a genus of copolycarbonates, including copolyestercarbonates, which have excellent physical and optical properties. Said copolycarbonates have proportions of structural units which fall within a specific composition range, and said range defines certain materials, a large percentage of which can be molded into optical disks having the desired optical properties, including low VBR.

摘要翻译： 这里提供了具有低VBR的光学存储介质。 在一个优选的实施方案中，提供了一种光盘，其包含具有优异的物理和光学性质的共聚碳酸酯类，包括共聚酯碳酸酯。 所述共聚碳酸酯具有落在特定组成范围内的结构单元的比例，并且所述范围限定某些材料，其中大部分可被模制成具有所需光学性质的光盘，包括低VBR。

公开(公告)号：US06562433B1

公开(公告)日：2003-05-13

申请号：US09663857

申请日：2000-09-18

申请人： Hiromi Ishida ,  Kenichi Ishiwa ,  Mitsuyasu Okamura ,  Tomoaki Shimoda ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout ,  Monica M. Marugan ,  Patrick J. McCloskey ,  Joseph A. King, Jr. ,  Paul M. Smigelski, Jr.

发明人： Hiromi Ishida ,  Kenichi Ishiwa ,  Mitsuyasu Okamura ,  Tomoaki Shimoda ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout ,  Monica M. Marugan ,  Patrick J. McCloskey ,  Joseph A. King, Jr. ,  Paul M. Smigelski, Jr.

IPC分类号： C08G6430

CPC分类号： G11B7/2534 ,  C08G64/06 ,  C08G64/307 ,  G11B7/2533 ,  G11B7/26

摘要： The present invention provides a composition comprising polycarbonate wherein the polycarbonate has a very low Fries content (e.g., above 5 ppm and below 360 ppm). The present invention also provides a polycarbonate having a very low Fries content which is made by the melt process. This polycarbonate has high ductility and high impact strength. The invention also provides a method for making these compositions. Another aspect of the invention is an optical disk comprising polycarbonate having a very low Fries content which is made by the melt process. Such optical disks resist breakage due to bending.

摘要翻译： 本发明提供包含聚碳酸酯的组合物，其中聚碳酸酯具有非常低的薯条含量（例如高于5ppm和低于360ppm）。 本发明还提供了通过熔融法制造的具有非常低的薯条含量的聚碳酸酯。 该聚碳酸酯具有高延展性和高冲击强度。 本发明还提供了制备这些组合物的方法。 本发明的另一方面是包括通过熔融法制造的具有非常低的薯条含量的聚碳酸酯的光盘。 这种光盘由于弯曲而抵抗破损。

公开(公告)号：US6022943A

公开(公告)日：2000-02-08

申请号：US287668

申请日：1999-04-07

申请人： Kazushige Inoue ,  Hiromi Ishida ,  Tomoaki Shimoda ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout ,  Monica M. Marugan ,  David M. Dardaris ,  Patrick J. McCloskey

发明人： Kazushige Inoue ,  Hiromi Ishida ,  Tomoaki Shimoda ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout ,  Monica M. Marugan ,  David M. Dardaris ,  Patrick J. McCloskey

IPC分类号： C08L69/00 ,  C08G64/14 ,  C08G64/30 ,  G11B7/253 ,  G11B11/105 ,  C08G64/00

CPC分类号： C08G64/14 ,  C08G64/307 ,  G11B7/2534

摘要： Increasing the endcap level to a level greater than about 90% for Optical Quality (OQ) Melt Polycarbonate significantly reduces the as-molded static charge for injection molded parts for Optical Disc applications. The use of resins with higher endcap levels in combination with antistatic additives provides a highly robust formulation suitable for even the most demanding emerging formats as Digital Versatile Disc (DVD) and in all commercial Optical media molding machines. Thus, optical quality polycarbonates are prepared by performing a base-catalyzed polymerization of a diaryl carbonate and a dihydric phenol under conditions effective to produce a polycarbonate product having an endcap level of 90% or greater.

摘要翻译： 将端盖水平提高到光学质量（OQ）的大约90％以上熔融聚碳酸酯显着降低了用于光盘应用的注塑部件的模制静电荷。 使用具有更高端帽水平的树脂与抗静电添加剂相结合提供了高度鲁棒的配方，适用于甚至最苛刻的新兴格式，如数字多功能光盘（DVD）和所有商业光学介质成型机。 因此，通过在有效地制备端帽水平为90％以上的聚碳酸酯制品的条件下进行碳酸二芳基酯和二元酚的碱催化聚合来制备光学质量的聚碳酸酯。

公开(公告)号：US5576413A

公开(公告)日：1996-11-19

申请号：US233285

申请日：1994-04-25

申请人： Jan Bussink ,  Henricus G. C. Denissen ,  Erwin M. A. Gijzen ,  Hendrik T. van de Grampel ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout

发明人： Jan Bussink ,  Henricus G. C. Denissen ,  Erwin M. A. Gijzen ,  Hendrik T. van de Grampel ,  Theodorus L. Hoeks ,  Henricus H. M. van Hout

IPC分类号： C08G64/06 ,  C08G64/00

CPC分类号： C08G64/06

摘要： Polycarbonate compositions comprising copolymers of bis-(4-hydroxyphenyl)methane and 2,2-bis-(4-hydroxyphenyl)propane are described and they unexpectedly display high glass transition temperatures, high impact resistances, flame retardant properties and superior brittle ductile transition temperature.

摘要翻译： 描述了包含双 - （4-羟基苯基）甲烷和2,2-双 - （4-羟基苯基）丙烷的共聚物的聚碳酸酯组合物，并且它们意外地显示出高玻璃化转变温度，高抗冲击性，阻燃性能和优异的脆性延性转变温度 。

公开(公告)号：US5512620A

公开(公告)日：1996-04-30

申请号：US238288

申请日：1994-05-05

申请人： Henricus H. M. van Hout ,  James F. Hoover ,  Karl H. Roell ,  Augustina M. Willemsen

发明人： Henricus H. M. van Hout ,  James F. Hoover ,  Karl H. Roell ,  Augustina M. Willemsen

IPC分类号： C08K3/00 ,  C08K5/36 ,  C08K5/45 ,  C08K5/52 ,  C08K5/524 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  C08L101/00 ,  C07D263/62

CPC分类号： C08K5/45 ,  Y10S430/134

摘要： Benzoxazolyl brightner compounds and thermoplastic combinations containing such are provided herein. The thermoplastic compositions comprise a thermoplastic resin, a phosphite heat stabilizer present in reduced levels, a brightner present in reduced levels and a pigment. Preferably the thermoplastic resin composition is transparent in nature. The compositions are useful for making molded and blow molded articles which require high levels of transparency, for example, glazing materials such thermoplastic windows. The composition exhibits enhanced appearance, namely a bright natural color in combination with low levels of yellowness by utilizing in combination reduced levels of phosphite and reduced levels of brightner, with moderate levels of pigment.

摘要翻译： 本文提供了苯并恶唑基光亮剂化合物和含有这些化合物的热塑性组合物。 热塑性组合物包括热塑性树脂，以降低的水平存在的亚磷酸酯热稳定剂，以降低的水平存在的增白剂和颜料。 优选地，热塑性树脂组合物在本质上是透明的。 该组合物可用于制造需要高水平透明度的模制和吹塑制品，例如玻璃材料如热塑性窗。 组合物表现出增强的外观，即通过以中等水平的颜料组合降低亚磷酸盐水平和降低水平的光亮剂，结合低水平黄色而具有明亮的天然色彩。

公开(公告)号：US5210173A

公开(公告)日：1993-05-11

申请号：US878788

申请日：1992-05-05

申请人： Henricus H. M. van Hout

发明人： Henricus H. M. van Hout

IPC分类号： C08G64/22 ,  C08G64/24

CPC分类号： C08G64/24

摘要： The invention relates to a method of preparing aromatic polycarbonates by catalytic interface polymerization of at least one bivalent phenol and a carbonyl halide in the presence of a polycondensation catalyst, which method is characterized in that the conversion is carried out in a two-phase system with continuous dosing of the carbonyl halide, which two-phase system is based on water and an organic solvent, in which the quantity of organic solvent at the beginning of the polycondensation lies between 10% and 75% of the quantity of organic solvent which is required at the polymerization temperature for dissolving the quantity of polycarbonate which may be formed from the quantity of bivalent phenol which is present at the beginning of the polycondensation, in that after dosing at least 20% of the carbonyl halide a remaining quantity of organic solvent is added which is at least sufficient to keep the formed polycarbonate in solution.