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公开(公告)号：US5200093A
公开(公告)日：1993-04-06
申请号：US709264
申请日：1991-06-03
IPC分类号： C02F11/08
CPC分类号： C02F11/086
摘要： In a supercritical oxidation process, the oxidized supercritical fluid effluent (46) discharged from the upper region of the reactor vessel (10) is contacted with a cold quench liquid (66) so as to produce a relatively solids free vapor stream (53) and a liquid stream (51) containing the bulk of the precipitates and other solids carried over in the oxidized supercritical fluid effluent (46). The temperature of the resultant liquid stream (51) is maintained at a temperature below the solids solubility inversion temperature, typically below 600.degree. F., so as to dissolve a substantial portion of the precipitates and other solids collected therein.
摘要翻译： 在超临界氧化过程中，从反应器容器（10）的上部区域排出的氧化的超临界流体（46）与冷骤冷液体（66）接触，以产生相对不含固体的蒸汽流（53）和 含有在氧化超临界流体流出物（46）中载带的大部分沉淀物和其它固体的液体流（51）。 所得液流（51）的温度保持在低于固体溶解度转化温度（通常低于600°F）的温度，以便溶解大部分沉淀物和其中收集的其它固体。
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公开(公告)号：US5250193A
公开(公告)日：1993-10-05
申请号：US921190
申请日：1992-07-28
CPC分类号： C02F11/08 , C02F11/086 , Y10S210/908 , Y10S210/909
摘要： This invention relates to improved wet oxidation process for the destruction of organic components in a wastewater stream contaminated with inorganic salts. In wet oxidation, the wastewater stream is contacted with an oxygen-containing water stream at elevated temperatures and pressures. The improvement for treating aqueous wastewater streams contaminated with inorganic salts wherein the organic contaminants are present in an amount from about 0.5 to 2% by weight resides in oxidizing the organic components in a tubular reactor at a temperature ranging from 325.degree. C. to not more than 370.degree. C. and a pressure ranging from 220 to 345 bar. The oxidation reaction is carried out in a reaction time of 5 minutes or less.
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3.发明授权Process for the oxidation of materials in water at supercritical temperatures utilizing reaction rate enhancers 失效使用反应速率增强剂在超临界温度下在水中氧化材料的方法
公开(公告)号：US5232604A
公开(公告)日：1993-08-03
申请号：US973217
申请日：1992-11-06
摘要： Disclosed is a method of substantially completely oxidizing material in an aqueous phase at supercritical temperatures and sub- or supercritical pressures by initiating the oxidation in the presence of small amounts of strong oxidizing agents that function to increase the initial reaction rate for the oxidation. The strong oxidizing agents suitable for use in the present invention comprise at least one selected from the group consisting of ozone (O.sub.3), hydrogen peroxide (H.sub.2 O.sub.2), salts containing persulfate (S.sub.2 O.sub.8.sup.2-), salts containing permanganate (MnO.sub.4.sup.-), nitric acid (HNO.sub.3), salts containing nitrate (NO.sub.3.sup.-), oxyacids of chlorine and their corresponding salts, hypochlorous acid (HOCl), salts containing hypochlorite (OCl.sup.-), chlorous acid (HOClO), salts containing chlorite (ClO.sub.2.sup.-), chloric acid (HOClO.sub.2), salts containing chlorate (ClO.sub.3.sup.), perchloric acid (HOClO.sub.3), and salts containing perchlorate (ClO.sub.4.sup.-).
摘要翻译： 公开了一种在超临界温度和亚临界压力或超临界压力下在水相中基本上完全氧化材料的方法，其通过在少量强氧化剂存在下引发氧化，所述强氧化剂起到增加氧化的初始反应速率的作用。 适合用于本发明的强氧化剂包括选自臭氧（O 3），过氧化氢（H 2 O 2），含有过硫酸盐（S2O82-）的盐，含有高锰酸盐（MnO4-），硝酸 （HNO 3），含有硝酸盐（NO 3 - ）的盐，氯及其相应的盐，次氯酸（HOCl），含有次氯酸盐（OCl-），氯酸（HOClO），含有亚氯酸盐（ClO 2 - ），氯酸盐 （HOClO 2），含有氯酸盐（ClO 3），高氯酸（HOClO 3）的盐和含有高氯酸盐（ClO 4 - ）的盐）。
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4.发明授权
公开(公告)号：US5358645A
公开(公告)日：1994-10-25
申请号：US935408
申请日：1992-08-26
CPC分类号： C02F11/086 , C02F11/08
摘要： Disclosed is an apparatus and a process for high temperature water oxidation of combustibles in which during at least a part of the oxidation, corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus, wherein at least a portion of the contact surface area comprises a zirconia based ceramic, with the temperature of the oxidation process in excess of about 300.degree. C. and the pressure of the oxidation process is in excess of about 27.5 bar (400 psi).
摘要翻译： 公开了一种用于可燃物的高温水氧化的装置和方法，其中在至少一部分氧化期间存在腐蚀性材料并且在装置的接触区域上与装置的至少一部分接触，其中在 接触表面积的至少一部分包括氧化锆基陶瓷，氧化过程的温度超过约300℃，氧化过程的压力超过约27.5巴（400psi）。
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公开(公告)号：US5674405A
公开(公告)日：1997-10-07
申请号：US509504
申请日：1995-07-08
CPC分类号： C02F1/025 , C02F11/086 , F01K3/188 , Y02P20/582
摘要： A method of continuous flow hydrothermal oxidation which provides for a low cost means of reaction initiation and propagation. The aqueous-organic feedstock and oxidant are introduced to a small reaction chamber and allowed to mix with the hot, partially reacted contents thereof. This backmixing serves to initiate the reaction of the incoming feedstock. Optionally, the contents of the chamber then pass to a second reactor located downstream, in order to allow for completion of the oxidation reaction.
摘要翻译： 连续流动水热氧化方法，其提供反应开始和传播的低成本手段。 将含水有机原料和氧化剂引入到小的反应室中，并与其部分反应的热的物质混合。 该回混用于引发进料的反应。 任选地，室的内容物然后传递到位于下游的第二反应器，以便完成氧化反应。
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6.发明授权
公开(公告)号：US5492634A
公开(公告)日：1996-02-20
申请号：US382648
申请日：1995-02-02
IPC分类号： A62D3/00 , A62D3/34 , A62D3/36 , A62D3/38 , A62D101/22 , B01J3/00 , B01J3/04 , B01J19/00 , C02F1/02 , C02F1/66 , C02F1/70 , C02F1/74
CPC分类号： C02F1/70 , B01J3/008 , B01J3/04 , C02F1/025 , C02F1/66 , Y10S210/908 , Y10S210/915
摘要： A method for pretreating a halogenated hydrocarbon feed to a hydrothermal oxidation reactor which includes forming a combination of a halogenated hydrocarbon with added alkali under hydrothermal conditions, adding water to the combination, thereby effectuating hydrolysis of the halogenated hydrocarbon so as to liberate halogen ions which are neutralized by the alkali. The neutralized halogen ion, a salt, may be removed from the process prior to or during the oxidation step as brine droplets.
摘要翻译： 一种用于将卤代烃进料预处理成水热氧化反应器的方法，其包括在水热条件下形成卤代烃与加入的碱的组合，向组合中加入水，从而实现卤代烃的水解以释放卤素离子， 被碱中和。 中和的卤素离子，盐可以在氧化步骤之前或期间作为盐水滴从工艺中除去。
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公开(公告)号：US4822497A
公开(公告)日：1989-04-18
申请号：US99773
申请日：1987-09-22
CPC分类号： B01D11/0203 , C02F11/086
摘要： The present invention relates to a novel aqueous-phase oxidizer and solids separator reactor. More particularly, the invention relates to a two zone pressure vessel in which precipitates and other solids fall or are sprayed from a supercritical temperature super zone into a lower temperature sub zone. The feed material may consist of various waste products which are subsequently oxidized in the super zone of the pressure vessel. The resultant brine or slurry which is found at the lower temperature sub zone of the vessel is removed via a pipe and disposed of accordingly.
摘要翻译： 本发明涉及一种新的水相氧化器和固体分离器反应器。 更具体地说，本发明涉及一种其中沉淀物和其它固体落下或从超临界温度超级区域喷入低温子区域的双区压力容器。 进料可以由随后在压力容器的超级区域中被氧化的各种废物构成。 在容器的低温子区域中发现的所得盐水或浆料经由管道被去除并相应地处理。
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