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    Mixtures of thermoplastic polymers in powder form
    4.
    发明授权
    Mixtures of thermoplastic polymers in powder form 失效
    粉末形式的热塑性聚合物的混合物

    公开(公告)号：US5112910A

    公开(公告)日：1992-05-12

    申请号：US743678

    申请日：1991-08-12

    申请人： Karl-Erwin Piejko ,  Christian Lindner ,  Ralph Ostarek ,  Hans-Eberhard Braese ,  Karl-Heinz Ott

    发明人： Karl-Erwin Piejko ,  Christian Lindner ,  Ralph Ostarek ,  Hans-Eberhard Braese ,  Karl-Heinz Ott

    IPC分类号： C08J3/00 ,  C08L21/00 ,  C08L25/12 ,  C08L33/06 ,  C08L33/12 ,  C08L51/04

    CPC分类号： C08L33/06 ,  C08J3/005 ,  C08L21/00 ,  C08L25/12 ,  C08L33/12 ,  C08L51/04

    摘要： Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.

    摘要翻译： 制备粉末形式的热塑性聚合物的混合物的方法，该方法由以下混合物的水性乳液制备：a）丙烯酸C 2 -C 8烷基酯和/或丁二烯与（基于共聚物）的至少40重量％的颗粒部分交联的橡胶状共聚物。 丙烯腈，苯乙烯或甲基丙烯酸C 1 -C 4烷基酯，b）热塑性树脂，如果合适，c）在二烯或烷基上的苯乙烯，α-甲基苯乙烯，丙烯腈，甲基丙烯酸甲酯和/或丙烯酸烷基酯的富含橡胶的接枝聚合物 丙烯酸酯橡胶，其橡胶含量为50〜95重量％ ％，其中a）和b）和如果合适的水性乳液c）具有15至50重量％的聚合物含量。 ％与凝固溶液同时混合，但在单独的流中，在20℃至100℃连续或半连续，聚合物a）和b），如果合适，c）凝结，将流合并，聚合物 混合物然后分离出来。

    Polymer mixture
    6.
    发明授权
    Polymer mixture 失效
    聚合物混合物

    公开(公告)号：US5104935A

    公开(公告)日：1992-04-14

    申请号：US447300

    申请日：1989-12-06

    申请人： Edgar Leitz ,  Karl-Erwin Piejko ,  Christian Lindner ,  Karl-Heinz Ott ,  Hans-Eberhard Braese

    发明人： Edgar Leitz ,  Karl-Erwin Piejko ,  Christian Lindner ,  Karl-Heinz Ott ,  Hans-Eberhard Braese

    IPC分类号： C08L25/06 ,  C08L33/00 ,  C08L33/04 ,  C08L33/06 ,  C08L33/08 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L67/04

    CPC分类号： C08L33/08 ,  C08L51/04 ,  C08L51/003 ,  C08L67/04

    摘要： Polymer mixtures ofa. 10 to 60 parts by weight of a graft polymer,b. 10 to 50 parts by weight of a partially cross-linked, rubber like copolymer of from 5 to 40% by weight of acrylonitrile, styrene, alkyl methacrylate or mixtures thereof and from 95 to 60% by weight of alkyl acrylate having a gel content of from 20 to 99% by weight,c. 5 to 40 parts by weight of an uncross-linked polymer of styrenes, .alpha.-methyl styrenes, acrylonitrile, methacrylonitrile, esters of acrylic acid or methacrylic acid, vinyl C.sub.1 to C.sub.4 carboxylic acids or mixtures of these monomers having Staudinger Indices (.eta.) (determined in dimethyl formamide at 23.degree. C.) of from 0.3 to 1.5 dl/g andd. 1 to 45 parts by weight of a polymer of a cyclic aliphatic ester or of an aliphatic cyclic ester and an aliphatic cyclic carbonate.

    摘要翻译： 聚合物混合物 10〜60重量份的接枝聚合物，b。 10至50重量份的5-40重量％的丙烯腈，苯乙烯，甲基丙烯酸烷基酯或其混合物的部分交联的橡胶状共聚物和95至60重量％的具有凝胶含量的丙烯酸烷基酯 20至99重量％，c。 5至40重量份苯乙烯，α-甲基苯乙烯，丙烯腈，甲基丙烯腈，丙烯酸或甲基丙烯酸的酯，乙烯基C1至C4羧酸或具有Staudinger指数（eta）的这些单体的混合物的未交联聚合物 在23℃的二甲基甲酰胺中测定）为0.3〜1.5dl / g，d。 1至45重量份的环状脂族酯或脂族环酯和脂族环状碳酸酯的聚合物。

    Rubber-like thermoplastic polymer mixtures
    8.
    发明授权
    Rubber-like thermoplastic polymer mixtures 失效
    橡胶状热塑性聚合物混合物

    公开(公告)号：US4902745A

    公开(公告)日：1990-02-20

    申请号：US283464

    申请日：1988-12-12

    申请人： Karl-Erwin Piejko ,  Otto Billinger ,  Lothar Meier ,  Christian Lindner ,  Karl-Heinz Ott

    发明人： Karl-Erwin Piejko ,  Otto Billinger ,  Lothar Meier ,  Christian Lindner ,  Karl-Heinz Ott

    IPC分类号： C08L33/04 ,  C08L33/08 ,  C08L51/04

    CPC分类号： C08L33/08 ,  C08L51/04

    摘要： Soft polymer mixtures of(a) 10 to 50 parts by weight of a graft polymer obtained from a particulate, highly cross linked diene or alkyl acrylate rubber and graft polymerized alkyl methacylate, acrylonitrile, styrene, alkyl acrylate or mixtures thereof and(b) 90 to 50 parts by weight of a partly cross-linked, particulate, rubber-like copolymer of acrylonitrile and/or methyl methacrylate and C.sub.1 to C.sub.8 alkyl acrylate having a gel content of from 60 to 99% by weight and an average particle diameter (d.sub.50) of from 0.1 to 0.6 .mu.m,and a process for the preparation of the mixtures and their use for the production of moulded articles.

    摘要翻译： 由（a）10至50重量份由颗粒状高度交联的二烯或丙烯酸烷基酯橡胶和接枝聚合的甲基丙烯酸烷基酯，丙烯腈，苯乙烯，丙烯酸烷基酯或其混合物获得的接枝聚合物和（b）90 至50重量份的丙烯腈和/或甲基丙烯酸甲酯的部分交联的颗粒状橡胶状共聚物和丙烯酸C1-C8烷基酯，其凝胶含量为60至99重量％，平均粒径（d50 ）为0.1至0.6μm，以及制备混合物的方法及其用于生产模塑制品的方法。

    ABS moulding compounds with novel morphology
    9.
    发明授权
    ABS moulding compounds with novel morphology 失效
    ABS模塑料具有新颖的形态

    公开(公告)号：US5674939A

    公开(公告)日：1997-10-07

    申请号：US557359

    申请日：1995-11-13

    申请人： Herbert Eichenauer ,  Adolf Schmidt ,  Edgar Leitz ,  Karl-Erwin Piejko

    发明人： Herbert Eichenauer ,  Adolf Schmidt ,  Edgar Leitz ,  Karl-Erwin Piejko

    IPC分类号： C08L51/04 ,  C08F279/00 ,  C08F279/04 ,  C08L55/00 ,  C08L55/02

    CPC分类号： C08L55/02 ,  C08F279/04

    摘要： Moulding compounds the ABS type consisting of at least one resin matrix and a particulate graft-rubber polymer distributed therein and produced by emulsion polymerisation, wherein at least 70% of the graft-rubber particles (number) exhibit a structure of the rubber phase which can be detected by photographs taken with the aid of a transmission electron microscope and in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles exhibits an irregularly jagged structure such that, for each particle illustrated, 5 to 30 of such jagged projections are present which differ from an idealised round particle (with a diameter d) by virtue of a diameter d+d/x with x=3 to 15, as well as a process for the manufacture of said moulding compounds.

    摘要翻译： 成型化合物由至少一种树脂基质和分散在其中的颗粒状接枝橡胶聚合物组成的ABS类型，通过乳液聚合制备，其中至少70％的接枝橡胶颗粒（数量）表现出橡胶相的结构，其可以 通过借助透射电子显微镜拍摄的照片进行检测，其中各个颗粒含有不规则的树脂形成性聚合物的细胞夹杂物，并且颗粒的表面呈现不规则的锯齿状结构，使得对于所示的每个颗粒为5〜30 存在这样的锯齿形突起，其与理想化的圆形颗粒（直径d）不同，其直径d = + d / x，x = 3〜15，以及制造所述模塑料的方法。