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12 条记录 (耗时 0.019 秒)

    Stabilization of anionic indole dyestuffs
    1.
    发明授权
    Stabilization of anionic indole dyestuffs 失效
    阴离子吲哚染料的稳定化

    公开(公告)号：US4245995A

    公开(公告)日：1981-01-20

    申请号：US876514

    申请日：1978-02-09

    申请人： Herbert Hugl ,  Hans-Gunter Otten ,  Hans W. Petroll ,  Karlheinz Wolf

    发明人： Herbert Hugl ,  Hans-Gunter Otten ,  Hans W. Petroll ,  Karlheinz Wolf

    IPC分类号： C09B46/00 ,  C09B67/24 ,  D06P3/24 ,  D06P1/645 ,  D06P1/647

    CPC分类号： C09B67/0072 ,  D06P3/241

    摘要： Azo dyestuffs which contain, as the coupling component an indole of the formula ##STR1## wherein R denotes an optionally substituted alkyl radical, an optionally substituted aryl radical or an optionally substituted aralkyl radical, and the benzene ring A can be further substituted,frequently exhibit an undesired irreversible change in the color shade in acid solutions, which surprisingly can be prevented by adding nitrogen-containing complex-forming substances.

    摘要翻译： 作为偶合成分的偶氮染料含有下式的吲哚：其中R表示任意取代的烷基，任意取代的芳基或任意取代的芳烷基，苯环A可进一步被取代，经常表现出 在酸性溶液中色调的不希望的不可逆变化，令人惊奇地可以通过加入含氮复合物形成物质来防止。

    Water-soluble diphenylamine-azo-sulfatoalkoxyphenyl dyestuffs
    2.
    发明授权
    Water-soluble diphenylamine-azo-sulfatoalkoxyphenyl dyestuffs 失效
    水溶性二苯胺 - 偶氮 - 硫酸烷氧基苯基染料

    公开(公告)号：US4119623A

    公开(公告)日：1978-10-10

    申请号：US713820

    申请日：1976-08-12

    申请人： Herbert Hugl ,  Hans-Gunter Otten ,  Richard Sommer ,  Gerhard Wolfrum

    发明人： Herbert Hugl ,  Hans-Gunter Otten ,  Richard Sommer ,  Gerhard Wolfrum

    IPC分类号： C09B29/12 ,  C09B43/02 ,  C09B43/11 ,  C09B43/28 ,  C09B62/825 ,  C09B67/24 ,  C09B43/00

    CPC分类号： C09B43/02 ,  C09B29/12 ,  C09B43/28 ,  C09B62/825 ,  C09B67/0072

    摘要： Dyestuffs, which in the form of the free acid of the formula ##STR1## wherein R.sub.1 denotes hydrogen, nitro, cyano, SO.sub.2 --R.sub.7, CONR.sub.8 R.sub.9, SO.sub.2 NR.sub.8 R.sub.9, SO.sub.2 OR.sub.10, COOR.sub.10, SO.sub.2 --NHSO.sub.2 --R.sub.11, sulpho or alkyl,R.sub.2 denotes hydrogen, nitro, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.3 denotes hydrogen, halogen, SO.sub.2 --R.sub.7, SO.sub.2 --NR.sub.8 R.sub.9 or optionally subsituted alkyl, alkoxy or aryl,R.sub.4 denotes hydrogen, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.5 denotes hydrogen or optionally substituted alkyl,R.sub.6 denotes alkylene,R.sub.7 denotes optionally substituted alkyl, aryl or aralkyl,R.sub.8 and R.sub.9 denote hydrogen, optionally substituted alkyl, cycloalkyl, aryl or aralkyl or the radical of a heterocyclic compound or, together with the N-atom, denote a heterocyclic structure,R.sub.10 denotes hydrogen or optionally substituted alkyl, aryl or aralkyl,R.sub.11 denotes optionally substituted alkyl or aryl or dialkylamino andn denotes 1 or 2 andThe radical O--R.sub.6 --OSO.sub.3 H is in the ortho-position or para-position relative to the azo group, are suitable for the dyeing and printing of the natural and synthetic amide group containing fiber materials.

    摘要翻译： 其中R1表示氢，硝基，氰基，SO2-R7，CONR8R9，SO2NR8R9，SO2OR10，COOR10，SO2-NHSO2-R11，磺基或烷基的式（Ⅰ）游离酸形式的染料， R 2表示氢，硝基，卤素或任选取代的烷基，烷氧基或芳基，R 3表示氢，卤素，SO 2 -R 7，SO 2 -NR 8 R 9或任选取代的烷基，烷氧基或芳基，R 4表示氢，卤素或任选取代的烷基，烷氧基或 芳基，R5表示氢或任选取代的烷基，R6表示亚烷基，R7表示任选取代的烷基，芳基或芳烷基，R8和R9表示氢，任选取代的烷基，环烷基，芳基或芳烷基或杂环化合物的基团， N原子表示杂环结构，R 10表示氢或任选取代的烷基，芳基或芳烷基，R 11表示任选取代的烷基或芳基或二烷基氨基，N DENOTES 1 OR 2，并且该自由基O-R6-OSO3H在邻 - 位置或对位r 适用于偶氮基团，适用于天然和合成含酰胺基团的纤维材料的染色和印花。

    Water-soluble phenylazoaminonaphthol sulphonic acid dyestuffs
    7.
    发明授权
    Water-soluble phenylazoaminonaphthol sulphonic acid dyestuffs 失效
    水溶性苯偶氮基萘酚磺酸染料

    公开(公告)号：US4218373A

    公开(公告)日：1980-08-19

    申请号：US917572

    申请日：1978-06-21

    申请人： Gerhard Wolfrum ,  Erich Klauke ,  Hans-Gunter Otten

    发明人： Gerhard Wolfrum ,  Erich Klauke ,  Hans-Gunter Otten

    IPC分类号： C09B29/01 ,  C09B29/30 ,  C09B43/24 ,  D06P1/06 ,  D06P1/39 ,  D06P3/24

    CPC分类号： C09B29/0003 ,  C09B29/30 ,  C09B43/24

    摘要： A water-soluble monoazo dyestuff which, in the form of the free acid, corresponds to the formula ##STR1## wherein R.sub.1 denotes alkyl which can be mono-substituted by chlorine, hydroxyl, C.sub.1 to C.sub.4 alkoxy, cyano, phenyl or tolyl, cyclohexyl which can be optionally substituted by C.sub.1 -C.sub.4 alkyl, phenyl, C.sub.1 -C.sub.4 -alkyl phenyl, chlorophenyl, bromophenyl, trifluoromethylphenyl or naphthyl, alkenyl or benzenesulphonyl which can be substituted by fluorine, chlorine, bromine, trifluoromethyl, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sub.2 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl which can be substituted by hydroxyl, cyano, formylamino, C.sub.1 -C.sub.4 alkylcarbonylamino or benzoylamino which in turn can be substituted by methyl, chlorine, bromine or trifluoromethyl; cyclohexyl or phenyl which can be substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine, bromine or trifluoromethyl andR.sub.3 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl and a process for the preparation of such water-soluble mono-azo dyestuff. The dyestuffs according to the invention are suitable for dyeing natural and synthetic fibre materials, for example for dyeing wool or polyamide fibres, in level, deep red to violet shades with very good fastness to light, wet processing and perspiration.

    摘要翻译： 游离酸形式的水溶性单偶氮染料对应于下式：其中R 1表示可以被氯，羟基，C 1至C 4烷氧基，氰基，苯基或甲苯基， 苯基，C 1 -C 4烷基苯基，氯苯基，溴苯基，三氟甲基苯基或萘基，可被氟，氯，溴，三氟甲基，C 1 -C 4 - 烷基取代的烯基或苯磺酰基， C 1 -C 4烷氧基，R 2表示氢，可被羟基，氰基，甲酰氨基，C 1 -C 4烷基羰基氨基或苯甲酰基氨基取代的C 1 -C 4 - 烷基，其又可被甲基，氯，溴或三氟甲基取代; 可被C 1 -C 4烷基，C 1 -C 4 - 烷氧基，氯，溴或三氟甲基取代的环己基或苯基，R 3表示氢或C 1 -C 4 - 烷基，以及制备这种水溶性单偶氮染料的方法。 根据本发明的染料适用于染色天然和合成纤维材料，例如染色羊毛或聚酰胺纤维，水平，深红色至紫色色调具有非常好的耐光牢度，湿润加工和出汗。

    Dyestuff mixture
    8.
    发明授权
    Dyestuff mixture 失效
    染料混合物

    公开(公告)号：US4539009A

    公开(公告)日：1985-09-03

    申请号：US667525

    申请日：1984-11-02

    申请人： Horst Nickel ,  Hans-Gunter Otten

    发明人： Horst Nickel ,  Hans-Gunter Otten

    IPC分类号： C09B31/062 ,  C09B67/22 ,  D06P1/06

    CPC分类号： C09B31/062 ,  C09B67/0055 ,  Y10S534/01 ,  Y10S8/917 ,  Y10S8/924

    摘要： Mixtures of dyestuffs of the formula I ##STR1## and of the formula II ##STR2## wherein R=alkyl,R.sub.1 =H or R andR.sub.2 /R.sub.3 =R.sub.1 or alkoxy,are distinguished by being readily soluble in hard water and produce satisfactory golden yellow dyeings on polyamide fibres.

    摘要翻译： 其中R =烷基，R 1 = H或R和R 2 / R 3 = R 1或烷氧基的式I化合物（I）和式II的化合物（II）的染料的混合物的特征在于容易溶于 硬水，并在聚酰胺纤维上产生令人满意的金黄色染色。

    Sulfo containing monoazo dyestuffs containing a benzthiazole diazo moiety and an N-benzylamino anilino coupling component
    9.
    发明授权
    Sulfo containing monoazo dyestuffs containing a benzthiazole diazo moiety and an N-benzylamino anilino coupling component 失效
    含有苯并噻唑重氮部分的含磺酸单偶氮染料和N-苄基氨基苯胺基偶联组分

    公开(公告)号：US4041024A

    公开(公告)日：1977-08-09

    申请号：US294526

    申请日：1972-10-03

    申请人： Gerhard Wolfrum ,  Hans-Gunter Otten

    发明人： Gerhard Wolfrum ,  Hans-Gunter Otten

    IPC分类号： C09B29/00 ,  C09B29/08 ,  C09B35/06 ,  C09B35/22 ,  D06P1/06 ,  D06P3/24

    CPC分类号： C09B29/0088 ,  C09B29/08 ,  C09B29/0803

    摘要： Azo dyestuffs of formula ##STR1## wherein R.sub.1 denotes hydrogen, C.sub.1 --C.sub.4 alkyl, Cl, Br, --OCH.sub.3, --OC.sub.2 H.sub.5, --NO.sub.2, --CN, --SCN, --SO.sub.2 CH.sub.3, --SO.sub.2 C.sub.2 H.sub.5, --SO.sub.3 H, --SO.sub.2 NX.sub.2 (X=H or C.sub.m H.sub.2m.sub.+1 with m = 1-4) or --COOC.sub.n H.sub.2n.sub.+1 (n = 0-4);R.sub.2 represents hydrogen, CH.sub.3, C.sub.2 H.sub.5, --OCH.sub.3, --OC.sub.2 H.sub.5, Cl, Br, or the grouping --NHCOC.sub.n H.sub.2n.sub.+1 (n = 0-4);R.sub.3 denotes hydrogen, OCH.sub.3, OC.sub.2 H.sub.5, CH.sub.3 or C.sub.2 H.sub.5 ;R.sub.4 represents C.sub.n H.sub.2n.sub.+1 (n = o-4), or CH.sub.2 CH.sub.2 SO.sub.3 H;R.sub.5 represents hydrogen or a sulphonic acid group, and p is 1 or 2,With only one of the residues R.sub.1, R.sub.4 and R.sub.5 representing or containing a sulphonic acid group. The dyestuffs are suitable for dyeing nitrogen-containing materials especially for dyeing synthetic polyamide and polyurethane fibers. The dyestuffs are very well absorbed on the polyamide fibers both from an acid dyebath and from a neutral dyebath. In one example synthetic polyamide fibers are dyed in clear shades having good to very good fastness properties.

    摘要翻译： 其中R1表示氢，C1-C4烷基，C1，Br，-OCH3，-OC2H5，-NO2，-CN，-SCN，-SO2CH3，-SO2C2H5，-SO3H，-SO2NX2（X = H或CmH2m + 1，m = 1-4）或-COOCnH2n + 1（n = 0-4）; R 2表示氢，CH 3，C 2 H 5，-OCH 3，-OC 2 H 5，Cl，Br或分组-NHCOC n H 2n + 1（n = 0-4）; R3表示氢，OCH3，OC2H5，CH3或C2H5; R4表示C n H 2n + 1（n = o-4）或CH 2 CH 2 SO 3 H; R5代表氢或磺酸基团，p是1或2，只有一个表示或含有磺酸基团的残基R1，R4和R5。 该染料适用于染色含氮材料，特别是染色合成聚酰胺和聚氨酯纤维。 染料在酸性染浴和中性染浴上均聚酰胺纤维非常好地被吸收。 在一个实例中，合成聚酰胺纤维以清晰的色调染色，具有良好至非常好的牢度性能。