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公开(公告)号：US4757137A
公开(公告)日：1988-07-12
申请号：US534914
申请日：1983-09-22
申请人： Gerhard Wolfrum , Erich Klauke , Hans-Gunter Otten
发明人： Gerhard Wolfrum , Erich Klauke , Hans-Gunter Otten
IPC分类号： C09B29/01 , C09B29/30 , C09B43/124 , C09B62/028 , C09B62/47 , C09B29/033 , C09B62/02
CPC分类号： C09B29/0007 , C09B29/30 , C09B43/124 , C09B62/028
摘要： Azo dyestuffs of the formula ##STR1## wherein R.sub.1 denotes acyl,R.sub.2 denotes hydrogen, fluorine, chlorine or trifluoromethyl,R.sub.3 denotes hydrogen, optionally substituted C.sub.1 -C.sub.4 -alkyl, cyclohexyl or optionally substituted phenyl andR.sub.4 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl groupare suitable for dyeing natural and synthetic fibre materials, for example for dyeing wool or polyamide fibres, in level read to violet shades with very good fastnesses to light, wet processing and perspiration, the color yield being good.
摘要翻译： 其中R 1表示酰基，R 2表示氢，氟，氯或三氟甲基，R 3表示氢，任选取代的C 1 -C 4 - 烷基，环己基或任意取代的苯基，R 4表示氢或C 1 -C 4 - 烷基 适用于染色天然和合成纤维材料，例如用于染色羊毛或聚酰胺纤维，水平读成紫罗兰色，具有非常好的耐光牢度，湿润加工和出汗，色泽良好。
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公开(公告)号：US4218373A
公开(公告)日：1980-08-19
申请号：US917572
申请日：1978-06-21
申请人： Gerhard Wolfrum , Erich Klauke , Hans-Gunter Otten
发明人： Gerhard Wolfrum , Erich Klauke , Hans-Gunter Otten
CPC分类号： C09B29/0003 , C09B29/30 , C09B43/24
摘要： A water-soluble monoazo dyestuff which, in the form of the free acid, corresponds to the formula ##STR1## wherein R.sub.1 denotes alkyl which can be mono-substituted by chlorine, hydroxyl, C.sub.1 to C.sub.4 alkoxy, cyano, phenyl or tolyl, cyclohexyl which can be optionally substituted by C.sub.1 -C.sub.4 alkyl, phenyl, C.sub.1 -C.sub.4 -alkyl phenyl, chlorophenyl, bromophenyl, trifluoromethylphenyl or naphthyl, alkenyl or benzenesulphonyl which can be substituted by fluorine, chlorine, bromine, trifluoromethyl, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sub.2 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl which can be substituted by hydroxyl, cyano, formylamino, C.sub.1 -C.sub.4 alkylcarbonylamino or benzoylamino which in turn can be substituted by methyl, chlorine, bromine or trifluoromethyl; cyclohexyl or phenyl which can be substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine, bromine or trifluoromethyl andR.sub.3 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl and a process for the preparation of such water-soluble mono-azo dyestuff. The dyestuffs according to the invention are suitable for dyeing natural and synthetic fibre materials, for example for dyeing wool or polyamide fibres, in level, deep red to violet shades with very good fastness to light, wet processing and perspiration.
摘要翻译： 游离酸形式的水溶性单偶氮染料对应于下式：其中R 1表示可以被氯，羟基，C 1至C 4烷氧基，氰基，苯基或甲苯基， 苯基，C 1 -C 4烷基苯基，氯苯基，溴苯基，三氟甲基苯基或萘基，可被氟，氯，溴，三氟甲基，C 1 -C 4 - 烷基取代的烯基或苯磺酰基， C 1 -C 4烷氧基，R 2表示氢，可被羟基，氰基，甲酰氨基，C 1 -C 4烷基羰基氨基或苯甲酰基氨基取代的C 1 -C 4 - 烷基，其又可被甲基，氯，溴或三氟甲基取代; 可被C 1 -C 4烷基，C 1 -C 4 - 烷氧基，氯，溴或三氟甲基取代的环己基或苯基，R 3表示氢或C 1 -C 4 - 烷基，以及制备这种水溶性单偶氮染料的方法。 根据本发明的染料适用于染色天然和合成纤维材料，例如染色羊毛或聚酰胺纤维，水平，深红色至紫色色调具有非常好的耐光牢度，湿润加工和出汗。
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公开(公告)号：US4000123A
公开(公告)日：1976-12-28
申请号：US546416
申请日：1975-02-03
CPC分类号： C09B62/53 , C09B29/0007 , C09B29/3613
摘要： Monoazo dyestuffs which in the form of the free acid correspond to the general formula ##STR1## wherein R.sub.0, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 have the meaning given in the description and their use for the dyeing of natural and synthetic fibre materials, especially for dyeing polyamide fibres. Dyeings obtained distinguish themselves by very good fastness to light. Dyestuffs are absorbed well on polyamide fibres already in a neutral to weakly acid dye bath. By polyamide fibres there are here especially understood those from synthetic polyamides such as .EPSILON.-polycaprolactam, or condensation products of adipic acid and hexamethylenediamine.
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公开(公告)号：US4119623A
公开(公告)日：1978-10-10
申请号：US713820
申请日：1976-08-12
CPC分类号： C09B43/02 , C09B29/12 , C09B43/28 , C09B62/825 , C09B67/0072
摘要： Dyestuffs, which in the form of the free acid of the formula ##STR1## wherein R.sub.1 denotes hydrogen, nitro, cyano, SO.sub.2 --R.sub.7, CONR.sub.8 R.sub.9, SO.sub.2 NR.sub.8 R.sub.9, SO.sub.2 OR.sub.10, COOR.sub.10, SO.sub.2 --NHSO.sub.2 --R.sub.11, sulpho or alkyl,R.sub.2 denotes hydrogen, nitro, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.3 denotes hydrogen, halogen, SO.sub.2 --R.sub.7, SO.sub.2 --NR.sub.8 R.sub.9 or optionally subsituted alkyl, alkoxy or aryl,R.sub.4 denotes hydrogen, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.5 denotes hydrogen or optionally substituted alkyl,R.sub.6 denotes alkylene,R.sub.7 denotes optionally substituted alkyl, aryl or aralkyl,R.sub.8 and R.sub.9 denote hydrogen, optionally substituted alkyl, cycloalkyl, aryl or aralkyl or the radical of a heterocyclic compound or, together with the N-atom, denote a heterocyclic structure,R.sub.10 denotes hydrogen or optionally substituted alkyl, aryl or aralkyl,R.sub.11 denotes optionally substituted alkyl or aryl or dialkylamino andn denotes 1 or 2 andThe radical O--R.sub.6 --OSO.sub.3 H is in the ortho-position or para-position relative to the azo group, are suitable for the dyeing and printing of the natural and synthetic amide group containing fiber materials.
摘要翻译： 其中R1表示氢，硝基，氰基，SO2-R7，CONR8R9，SO2NR8R9，SO2OR10，COOR10，SO2-NHSO2-R11，磺基或烷基的式（Ⅰ）游离酸形式的染料， R 2表示氢，硝基，卤素或任选取代的烷基，烷氧基或芳基，R 3表示氢，卤素，SO 2 -R 7，SO 2 -NR 8 R 9或任选取代的烷基，烷氧基或芳基，R 4表示氢，卤素或任选取代的烷基，烷氧基或 芳基，R5表示氢或任选取代的烷基，R6表示亚烷基，R7表示任选取代的烷基，芳基或芳烷基，R8和R9表示氢，任选取代的烷基，环烷基，芳基或芳烷基或杂环化合物的基团， N原子表示杂环结构，R 10表示氢或任选取代的烷基，芳基或芳烷基，R 11表示任选取代的烷基或芳基或二烷基氨基，N DENOTES 1 OR 2，并且该自由基O-R6-OSO3H在邻 - 位置或对位r 适用于偶氮基团，适用于天然和合成含酰胺基团的纤维材料的染色和印花。
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5.发明授权Sulfo containing monoazo dyestuffs containing a benzthiazole diazo moiety and an N-benzylamino anilino coupling component 失效含有苯并噻唑重氮部分的含磺酸单偶氮染料和N-苄基氨基苯胺基偶联组分
公开(公告)号：US4041024A
公开(公告)日：1977-08-09
申请号：US294526
申请日：1972-10-03
申请人： Gerhard Wolfrum , Hans-Gunter Otten
发明人： Gerhard Wolfrum , Hans-Gunter Otten
CPC分类号： C09B29/0088 , C09B29/08 , C09B29/0803
摘要： Azo dyestuffs of formula ##STR1## wherein R.sub.1 denotes hydrogen, C.sub.1 --C.sub.4 alkyl, Cl, Br, --OCH.sub.3, --OC.sub.2 H.sub.5, --NO.sub.2, --CN, --SCN, --SO.sub.2 CH.sub.3, --SO.sub.2 C.sub.2 H.sub.5, --SO.sub.3 H, --SO.sub.2 NX.sub.2 (X=H or C.sub.m H.sub.2m.sub.+1 with m = 1-4) or --COOC.sub.n H.sub.2n.sub.+1 (n = 0-4);R.sub.2 represents hydrogen, CH.sub.3, C.sub.2 H.sub.5, --OCH.sub.3, --OC.sub.2 H.sub.5, Cl, Br, or the grouping --NHCOC.sub.n H.sub.2n.sub.+1 (n = 0-4);R.sub.3 denotes hydrogen, OCH.sub.3, OC.sub.2 H.sub.5, CH.sub.3 or C.sub.2 H.sub.5 ;R.sub.4 represents C.sub.n H.sub.2n.sub.+1 (n = o-4), or CH.sub.2 CH.sub.2 SO.sub.3 H;R.sub.5 represents hydrogen or a sulphonic acid group, and p is 1 or 2,With only one of the residues R.sub.1, R.sub.4 and R.sub.5 representing or containing a sulphonic acid group. The dyestuffs are suitable for dyeing nitrogen-containing materials especially for dyeing synthetic polyamide and polyurethane fibers. The dyestuffs are very well absorbed on the polyamide fibers both from an acid dyebath and from a neutral dyebath. In one example synthetic polyamide fibers are dyed in clear shades having good to very good fastness properties.
摘要翻译： 其中R1表示氢，C1-C4烷基，C1，Br，-OCH3，-OC2H5，-NO2，-CN，-SCN，-SO2CH3，-SO2C2H5，-SO3H，-SO2NX2（X = H或CmH2m + 1，m = 1-4）或-COOCnH2n + 1（n = 0-4）; R 2表示氢，CH 3，C 2 H 5，-OCH 3，-OC 2 H 5，Cl，Br或分组-NHCOC n H 2n + 1（n = 0-4）; R3表示氢，OCH3，OC2H5，CH3或C2H5; R4表示C n H 2n + 1（n = o-4）或CH 2 CH 2 SO 3 H; R5代表氢或磺酸基团，p是1或2，只有一个表示或含有磺酸基团的残基R1，R4和R5。 该染料适用于染色含氮材料，特别是染色合成聚酰胺和聚氨酯纤维。 染料在酸性染浴和中性染浴上均聚酰胺纤维非常好地被吸收。 在一个实例中，合成聚酰胺纤维以清晰的色调染色，具有良好至非常好的牢度性能。
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公开(公告)号：US4059402A
公开(公告)日：1977-11-22
申请号：US691869
申请日：1976-06-01
申请人： Gerhard Wolfrum , Werner Kuhnel , Erich Klauke , Gerhard Buttner
发明人： Gerhard Wolfrum , Werner Kuhnel , Erich Klauke , Gerhard Buttner
CPC分类号： D06P5/006 , C09B29/0805 , Y10S8/911 , Y10S8/912
摘要： The invention relates to the transfer printing hydrophobic fibre materials using paper supports which are printed with azo dyestuffs of the formula ##STR1## wherein X.sub.1 and X.sub.2 represent hydrogen or alkyl or cycloalkyl radicals andn represents 1-3, and wherein the benzene ring A can contain non-ionic substituents and the benzene ring B can contain customary non-polar substituents.
摘要翻译： 本发明涉及使用印刷有下式的偶氮染料的纸张载体的转印印刷疏水性纤维材料，其中X1和X2代表氢或烷基或环烷基，N代表1-3，并且苯并环A可以 含有非离子取代基，苯环B可含有常规的非极性取代基。
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7.发明授权Chelatable 4-thienyl imidazole azo dyes, their use in color photographic recording material 失效可螯合的4-噻吩基咪唑偶氮染料，它们用于彩色照相记录材料
公开(公告)号：US4524123A
公开(公告)日：1985-06-18
申请号：US593936
申请日：1984-03-27
摘要： Azo dyes corresponding to the formula (II): ##STR1## wherein G represents a group capable of forming a 5-membered chelate ring and R.sup.5 represents aryl or a thienyl group, combined with metal ions, in particular copper or nickel ions, to form stable azo dye-metal complexes which have advantageous spectral properties. They are therefore particularly suitable for the production of highly light-fast cyan images, e.g. by the Ink-Jet process, in which they may be used directly in the form of colored inks, or by the dye diffusion transfer process, in which they are released image-wise from corresponding dye-releasers in the course of development and transferred to a dye-absorbent layer.
摘要翻译： 对应于式（II）的偶氮染料：其中G表示能够形成5元螯合环的基团，R 5表示芳基或噻吩基，与金属离子，特别是铜或镍离子结合 以形成具有有利的光谱性质的稳定的偶氮染料 - 金属络合物。 因此，它们特别适用于生产高度光快的青色图像，例如， 通过喷墨方法，其可以直接以彩色油墨的形式使用，或通过染料扩散转移方法，在显影过程中它们从相应的染料释放剂成像释放并转移到 染料吸收层。
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8.发明授权Monoazo pyridinol dyes chelated or capable of being chelated with metal ions and their use for image production 失效螯合或能够与金属离子螯合的单偶氮吡啶酚染料及其用于图像生产
公开(公告)号：US4521506A
公开(公告)日：1985-06-04
申请号：US617499
申请日：1984-06-05
CPC分类号： C09B29/3639 , G03C8/10
摘要： Azo dyes corresponding to the formula (I): ##STR1## wherein R.sup.1 represents a releasable group, R.sup.2 represents H, halogen or sulphonyl, R.sup.3 and R.sup.4 represent H or groups not capable of chelate formation, and Q represents a group for completing a phenyl or naphthyl group,combine with nickel ions to form stable azo dye-metal complexes which have advantageous spectral properties. They are therefore particularly suitable for the production of highly light-fast magenta images, e.g. by the ink jet process, in which they may be used directly in the form of colored inks, or by the dye diffusion transfer process, in which they are released imagewise from suitable dye-releasers in the course of development and transferred to a dye-receptive layer.
摘要翻译： 对应于式（I）的偶氮染料：其中R1表示可释放基团，R 2表示H，卤素或磺酰基，R 3和R 4表示H或不能螯合形成的基团，Q表示 完成苯基或萘基，与镍离子结合形成具有有利光谱性质的稳定的偶氮染料 - 金属络合物。 因此，它们特别适用于生产高度光鲜的品红色图像，例如， 通过喷墨方法，其可以直接以彩色油墨的形式使用，或通过染料扩散转移方法使用，其中它们在显影过程中从合适的染料释放剂成像释放并转移到染料 - 接受层
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9.发明授权Photographic recording material with arylazocyanoacetic ester dye releasers 失效具有芳基氮杂乙酸酯染料释放剂的摄影记录材料
公开(公告)号：US4393132A
公开(公告)日：1983-07-12
申请号：US371076
申请日：1982-04-23
摘要： For the production of light-fast yellow images (transfer images and retained images) by the dye diffusion transfer process dye-releasers are useful which on development release diffusible azo dyes which can complex with nickel or copper ions and which in one of their tautomeric forms correspond to the general formula: ##STR1## wherein R.sup.1 represents alkyl, alkenyl or cycloalkyl having up to 8 carbon atoms,Z represents a radical required for completing a benzene or naphthalene ring; andL represents a substituent having a group which results from the splitting from a carrier radical.
摘要翻译： 为了通过染料扩散转移法生产快速黄色图像（转印图像和保留的图像），染料释放剂可用于显影释放可与镍或铜离子复合的可扩散偶氮染料，并且以其互变异构形式之一 对应于以下通式：其中R 1表示具有至多8个碳原子的烷基，烯基或环烷基，Z表示完成苯或萘环所需的基团; L表示具有由载体自由基分裂产生的基团的取代基。
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公开(公告)号：US4369324A
公开(公告)日：1983-01-18
申请号：US256636
申请日：1981-04-23
IPC分类号： C07D277/32 , C07D277/82
CPC分类号： C07D277/82
摘要： 2-Amino-6-nitrobenzothiazole is obtained with a high selectivity if, instead of unprotected 2-aminobenzothiazole, acylation products thereof are nitrated and the acyl groups are then split off. 2-Amino-6-nitrobenzothiazole is an important intermediate product for the preparation of valuable azo dyestuffs.
摘要翻译： 如果代替未保护的2-氨基苯并噻唑，其酰化产物被硝化并且然后将酰基分离，则可以高选择性获得2-氨基-6-硝基苯并噻唑。 2-氨基-6-硝基苯并噻唑是制备有价值偶氮染料的重要中间产物。
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