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    Supported catalyst, process for its production as well as its use in the oxychlorination of ethylene
    1.
    发明授权
    Supported catalyst, process for its production as well as its use in the oxychlorination of ethylene 失效
    负载催化剂，其生产方法及其在乙烯氧氯化中的应用

    公开(公告)号：US5986152A

    公开(公告)日：1999-11-16

    申请号：US198251

    申请日：1998-11-24

    申请人： Herbert Muller ,  Stefan Bosing ,  Ludwig Schmidhammer ,  Albin Frank ,  Klaus Haselwarter

    发明人： Herbert Muller ,  Stefan Bosing ,  Ludwig Schmidhammer ,  Albin Frank ,  Klaus Haselwarter

    IPC分类号： B01J23/83 ,  B01J27/122 ,  B01J35/02 ,  B01J35/10 ,  C07B61/00 ,  C07C17/08 ,  C07C17/156 ,  C07C19/045 ,  B01J23/72

    CPC分类号： B01J35/026 ,  B01J23/83 ,  B01J27/122 ,  C07C17/156

    摘要： A supported catalyst includes: a) 0.5-15 wt. % of one or more Cu-II compounds, the quantitative amounts referring to copper metal; b) 0.1-8 wt. % of one or more alkali metal compounds, the quantitative amounts referring to alkali metal; c) 0.1-10 wt. % of an oxide mixture including; c1) 80-95 mole % of oxides of cerite rare earths with atomic Nos. 57 to 62, except promethium, and c2) 5-20 mole % of zirconium dioxide, where c1) and c2) must together total 100 mole % and the quantitative amount of c) refers to the oxides of the mixture, and d) the remainder up to 100 wt. % being .gamma. and/or .alpha.-aluminum oxide as support material, wherein e) the support material d) has a total pore volume in the range from 0.65 to 1.2 cm.sup.3 /g, and wherein f) the supported catalyst is present in the form of cylindrical hollow bodies having at least one passage channel, the ratio of height h to external diameter d.sup.e being less than 1.5 for diameters d.sub.e of up to 6 mm, and the ratio h/d.sub.e being less than 0.6 for diameter d.sub.e greater than 6 mm. A process for producing the supported catalyst is also described.

    摘要翻译： 负载催化剂包括：a）0.5-15wt。 ％的一种或多种Cu-II化合物，定量为铜金属; b）0.1-8wt。 ％的一种或多种碱金属化合物，定量为碱金属; c）0.1-10重量％ ％的氧化物混合物包括： c1）80-95摩尔％的原子号为57〜62的铈铈稀土的氧化物，除了碲，和c2）5-20摩尔％的二氧化锆，其中c1）和c2）必须总共为100摩尔％ 定量的c）是指混合物的氧化物，和d）余量高达100wt。 ％为γ和/或α-二氧化铝作为载体材料，其中e）载体材料d）具有在0.65-1.2cm 3 / g范围内的总孔体积，并且其中f）负载型催化剂以 具有至少一个通道的圆柱形空心体，对于直径为d至6mm，高度h与外径之比de小于1.5，直径d大于0.6的比率h / de小于0.6 。 还描述了制备负载型催化剂的方法。