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99 条记录 (耗时 0.019 秒)

    Continuous production of polypyrrole films
    1.
    发明授权
    Continuous production of polypyrrole films 失效
    连续生产聚吡咯薄膜

    公开(公告)号：US4468291A

    公开(公告)日：1984-08-28

    申请号：US508144

    申请日：1983-06-27

    申请人： Herbert Naarmann ,  Gernot Kohler ,  Johannes Schlag

    发明人： Herbert Naarmann ,  Gernot Kohler ,  Johannes Schlag

    IPC分类号： C08F34/00 ,  C08G61/00 ,  C08G61/10 ,  C08G61/12 ,  C09D5/44 ,  C25B3/10 ,  C25D1/12 ,  H01B1/12 ,  H01M4/60 ,  C25B3/02

    CPC分类号： H01B1/127 ,  C08G61/124 ,  C09D5/4476 ,  C25D1/12 ,  H01M4/60

    摘要： Polypyrrole films are produced by electrochemical polymerization of a pyrrole, or a mixture of a pyrrole with other comonomers, in an electrolyte solvent in the presence of a conductive salt, by a continuous process wherein the pyrrole polymer is deposited in the form of a film on anodic material which has a sheet-like structure and is passed continuously through the electrolyte solution.As shown in FIG. 1, this procedure can be carried out in an electrolysis vessel (1) which contains the electrolyte solution (2), a cathode (3) which dips into this solution, and, as the anode, a rotating cylindrical roller (4) which is partially or completely immersed in the electrolyte solution (2); the polypyrrole film (6) is deposited on the anodic surface (5) of the cylindrical roller (4), and is subsequently removed therefrom.

    摘要翻译： 聚吡咯膜是通过吡咯或吡咯与其它共聚单体的混合物在导电盐存在下在电解质溶剂中电化学聚合而制得的，其中吡咯聚合物以膜的形式沉积在 具有片状结构并连续通过电解质溶液的阳极材料。 如图所示。 如图1所示，该方法可以在包含电解液（2）的电解槽（1），浸入该溶液中的阴极（3）和作为阳极的电解槽（1）中进行旋转的圆柱滚子（4） 部分或完全浸入电解质溶液（2）中; 聚吡咯膜（6）沉积在圆柱形辊（4）的阳极表面（5）上，随后从其中取出。

    Preparation of electrically conductive polymers
    7.
    发明授权
    Preparation of electrically conductive polymers 失效
    导电聚合物的制备

    公开(公告)号：US4407739A

    公开(公告)日：1983-10-04

    申请号：US344020

    申请日：1982-01-29

    申请人： Herbert Naarmann ,  Klaus Penzien ,  Johannes Schlag

    发明人： Herbert Naarmann ,  Klaus Penzien ,  Johannes Schlag

    IPC分类号： C08F8/00 ,  C08F8/30 ,  C08F8/42 ,  C08G61/00 ,  C08L65/00 ,  H01B1/12 ,  H01L51/00 ,  H01L51/30 ,  H01L51/42 ,  H01B1/02

    CPC分类号： H01L51/0036 ,  C08F8/42 ,  C08G61/00 ,  H01B1/125 ,  H01L51/0035 ,  H01L51/0041 ,  H01L51/007 ,  H01L51/42 ,  Y02E10/549

    摘要： A process for the preparation of electrically conductive polymers which have conductivities greater than 10.sup.-2 S/cm and possess improved stability to oxygen, comprising treating an organic unsaturated polymer of the series of the polyphenylenes, heterophenylenes and polyacetylenes, in the absence of moisture and of oxygen, first with an organic nitroso compound and then with a conventional dopant, the latter being, in particular H.sub.2 SO.sub.4, AsF.sub.5, SbF.sub.5, UF.sub.6, SbCl.sub.5, AlCl.sub.3, BF.sub.3, CF.sub.3 SO.sub.3 H, VOCl.sub.3, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ AsF.sub.6, NO.sup.+ PF.sub.6.sup.-, I.sub.2, Br.sub.2, ICl, PF.sub.5, CrO.sub.2 Cl.sub.2, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, NbF.sub.5, TaF.sub.5, WF.sub.6, FeCl.sub.3, CdCl.sub.2, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid or 2,4,6-trinitrophenylcarboxylic acid or lithium, sodium, potassium, calcium, barium, radium or an amide of these metals.

    摘要翻译： 一种制备导电聚合物的方法，其导电率大于10-2S / cm并且具有改善的对氧气的稳定性，包括在没有水分的情况下处理一系列聚苯，异亚苯基和聚乙炔的有机不饱和聚合物，以及 的氧，首先用有机亚硝基化合物，然后与常规掺杂剂，后者特别是H 2 SO 4，AsF 5，SbF 5，UF 6，SbCl 5，AlCl 3，BF 3，CF 3 SO 3 H，VOCl 3，HClO 4，NO + SbF 6 - ，NO 2 + SbF 6 - ，NO + AsF6，NO + PF6-，I2，Br2，ICl，PF5，CrO2Cl2，NO2 + PF6-，NO + BF4-，NO + ClO4-，（CF3）2SO4，NbF5，TaF5，WF6，FeCl3，CdCl2 ，2,4,6-三硝基苯酚，2,4,6-三硝基苯磺酸或2,4,6-三硝基苯基羧酸或这些金属的锂，钠，钾，钙，钡，镭或酰胺。

    Preparation of electrically conductive soluble heteropolyphenylenes
    9.
    发明授权
    Preparation of electrically conductive soluble heteropolyphenylenes 失效
    导电性可溶性多聚苯乙烯的制备

    公开(公告)号：US4395497A

    公开(公告)日：1983-07-26

    申请号：US273688

    申请日：1981-06-15

    申请人： Herbert Naarmann ,  Dieter Naegele ,  Klaus Penzien ,  Johannes Schlag

    发明人： Herbert Naarmann ,  Dieter Naegele ,  Klaus Penzien ,  Johannes Schlag

    IPC分类号： C08G61/12 ,  C08L65/00 ,  H01B1/12 ,  H01L51/30 ,  C08L77/02

    CPC分类号： H01B1/128 ,  C08G61/123 ,  C08L65/00 ,  H01B1/127 ,  H01L51/0035 ,  C08G2261/312 ,  Y02E10/549

    摘要： A process for the preparation of electrically conductive heteropolyphenylenes, wherein from 0.5 to 5 per cent by weight of an activating additive is introduced, in the absence of moisture and of oxygen, into a heteropolyphenylene of the general formula ##STR1## where X is O, S, Se, SO or SO.sub.2 and Y has one of the meanings given for X or is NH, CH.sub.2, CO or C.sub.6 H.sub.4, and n is from 2 to 250. The activating additive is preferably one of the compounds AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, SbCl.sub.5, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid and 2,4,6-trinitrophenylcarboxylic acid, or is sodium, potassium, rubidium, cesium, calcium or barium or one of their amides, the latter being added, if appropriate, in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene. The conductive heteropolyphenylenes may be used in the electrical industry for the production of solar cells, for conversion and fixing of radiation and for the production of electrical and magnetic switches, or may be used for the antistatic treatment of plastics.

    摘要翻译： 一种用于制备导电杂多苯基苯的方法，其中将0.5-5重量％的活化添加剂在没有水分和氧气的情况下引入通式为“IMAGE”的杂多亚苯基，其中X为O， S，Se，SO或SO 2，Y具有对X给出的含义之一或为NH，CH 2，CO或C 6 H 4，n为2至250.活化添加剂优选为化合物AsF5，SbF5，UF6， HClO4，NO + SbF6-，NO2 + SbF6-，NO + PF6-，SbCl5，NO2 + PF6-，NO + BF4-，NO + ClO4-，（CF3）2SO4,2,4,6-三硝基苯酚 ，6-三硝基苯磺酸和2,4,6-三硝基苯基羧酸，或者是钠，钾，铷，铯，钙或钡或它们的酰胺之一，如果合适，将其加入四氢呋喃，二甲氧基乙二醇，蒽，萘 或2-甲基苯乙烯。 导电杂多亚苯基可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及用于电气和磁性开关的生产，或可用于塑料的抗静电处理。

    Preparation of electrically conductive polymers
    10.
    发明授权
    Preparation of electrically conductive polymers 失效
    导电聚合物的制备

    公开(公告)号：US4412942A

    公开(公告)日：1983-11-01

    申请号：US373158

    申请日：1982-04-29

    申请人： Herbert Naarmann ,  Klaus Penzien ,  Johannes Schlag ,  Petr Simak

    发明人： Herbert Naarmann ,  Klaus Penzien ,  Johannes Schlag ,  Petr Simak

    IPC分类号： C08F8/00 ,  C08F8/30 ,  C08F8/42 ,  H01B1/12 ,  H01L51/30 ,  H01L51/42 ,  H01B1/06

    CPC分类号： H01B1/125 ,  C08F8/42 ,  H01L51/0041 ,  H01L51/42 ,  Y02E10/549

    摘要： A process for the preparation of stable electrically conductive polymers, having conductivities greater than 10.sup.-2 S/cm, wherein a polyacetylene is reacted with from 1 to 100, preferably from 10 to 33, % by weight of tosylmethyl isocyanide and from 0.1 to 70, preferably from 5 to 35, % by weight of an alkali metal or its amide, or of a Lewis acid. The polymers obtained can be used in electrical engineering for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches and electrical storage devices, and can also be used for the antistatic treatment of plastics.

    摘要翻译： 用于制备电导率大于10-2S / cm的稳定导电聚合物的方法，其中聚乙炔与1至100重量比，优选10至33重量％的甲苯磺酰甲基异氰化物和0.1至70重量％ ，优选5至35重量％的碱金属或其酰胺或路易斯酸。 获得的聚合物可用于生产太阳能电池的电气工程，用于辐射的转换和固定以及用于生产电磁开关和电存储装置，并且也可用于塑料的抗静电处理。