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    Method for production propylene from a flow containing c4 to c8 olefins
    2.
    发明申请
    Method for production propylene from a flow containing c4 to c8 olefins 有权
    从含有c4至c8烯烃的流程生产丙烯的方法

    公开(公告)号：US20050234282A1

    公开(公告)日：2005-10-20

    申请号：US10522498

    申请日：2003-06-05

    申请人： Hermann Bach ,  Harald Kompel ,  Bernd Ahlers ,  Peter Trabold ,  Frank Hoper

    发明人： Hermann Bach ,  Harald Kompel ,  Bernd Ahlers ,  Peter Trabold ,  Frank Hoper

    IPC分类号： C07B61/00 ,  C07C4/06 ,  C07C11/06 ,  C07C4/02

    CPC分类号： C07C4/06 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P30/48 ,  C07C11/06

    摘要： In a method for the production of propylene, a charge stream containing C4 to C6 olefins is evaporated, superheated, mixed with hot water vapor, the olefins vapor mixture converted on a zeolite catalyst, the reaction mixture formed thereby cooled, and then partially condensed. In order to increase the yield of propylene, the gaseous phase containing ethylene, propylene, C4 to C8 olefins, and additional hydrocarbons that is accumulated during the partial condensation is compressed, the gaseous and liquid phase containing propylene, ethylene, and other light hydrocarbons that exit from the compression step is separated into a gaseous phase containing propylene, ethylene, and other light hydrocarbons and a liquid phase containing C4+ olefins, and the liquid phase is separated into a fraction containing C4 to C6 olefins and a fraction containing C7+ olefins.

    摘要翻译： 在制备丙烯的方法中，将含有C 4 -C 6烯烃的电荷流蒸发，过热，与热水蒸气混合，将烯烃蒸气混合物转化为 沸石催化剂，由此形成的反应混合物冷却，然后部分冷凝。 为了提高丙烯的产率，含有乙烯，丙烯，C 4 -C 8烯烃的气相和在部分冷凝期间积聚的其它烃被压缩 含有丙烯，乙烯和从压缩步骤出来的其它轻烃的气相和液相被分离成含有丙烯，乙烯和其它轻质烃的气相和含有C 4 +烯烃，并将液相分离成含有C 4 O 6至C 6 O 6烯烃的馏分和含有C 7+烯烃的级分。

    Method for production propylene from a flow containing C4 to C8 olefins
    3.
    发明授权
    Method for production propylene from a flow containing C4 to C8 olefins 有权
    从含有C4〜C8烯烃的流程生产丙烯的方法

    公开(公告)号：US07425663B2

    公开(公告)日：2008-09-16

    申请号：US10522498

    申请日：2003-06-05

    申请人： Hermann Bach ,  Harald Kömpel ,  Bernd Ahlers ,  Peter Trabold ,  Frank Höper

    发明人： Hermann Bach ,  Harald Kömpel ,  Bernd Ahlers ,  Peter Trabold ,  Frank Höper

    IPC分类号： C07C4/02 ,  C10G11/00 ,  C10G9/36

    CPC分类号： C07C4/06 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P30/48 ,  C07C11/06

    摘要： In a method for the production of propylene, a charge stream containing C4 to C6 olefins is evaporated, superheated, mixed with hot water vapor, the olefins vapor mixture converted on a zeolite catalyst, the reaction mixture formed thereby cooled, and then partially condensed. In order to increase the yield of propylene, the gaseous phase containing ethylene, propylene, C4 to C8 olefins, and additional hydrocarbons that is accumulated during the partial condensation is compressed, the gaseous and liquid phase containing propylene, ethylene, and other light hydrocarbons that exit from the compression step is separated into a gaseous phase containing propylene, ethylene, and other light hydrocarbons and a liquid phase containing C4+ olefins, and the liquid phase is separated into a fraction containing C4 to C6 olefins and a fraction containing C7+ olefins.

    摘要翻译： 在制备丙烯的方法中，将含有C 4 -C 6烯烃的电荷流蒸发，过热，与热水蒸气混合，将烯烃蒸气混合物转化为 沸石催化剂，由此形成的反应混合物冷却，然后部分冷凝。 为了提高丙烯的产率，含有乙烯，丙烯，C 4 -C 8烯烃的气相和在部分冷凝期间积聚的其它烃被压缩 含有丙烯，乙烯和从压缩步骤出来的其它轻烃的气相和液相被分离成含有丙烯，乙烯和其它轻质烃的气相和含有C 4 +烯烃，并将液相分离成含有C 4 O 6至C 6 O 6烯烃的馏分和含有C 7+烯烃的级分。

    Supported catalyst for the preparation of monocarboxylic anhydrides
    5.
    发明授权
    Supported catalyst for the preparation of monocarboxylic anhydrides 失效
    用于制备单羧酸酐的负载型催化剂

    公开(公告)号：US4965234A

    公开(公告)日：1990-10-23

    申请号：US319138

    申请日：1989-03-03

    申请人： Gerhard Luft ,  Peter Trabold

    发明人： Gerhard Luft ,  Peter Trabold

    IPC分类号： C07B61/00 ,  B01J31/16 ,  B01J31/24 ,  B01J31/28 ,  C07C51/00 ,  C07C51/36 ,  C07C51/54 ,  C07C51/56 ,  C07C53/12 ,  C07C67/00 ,  C07F15/00

    CPC分类号： C07C51/36 ,  B01J31/1633 ,  B01J31/2409 ,  B01J2531/822

    摘要： In a supported catalyst for the preparation of monocarboxylic anhydrides by carbonylation of the appropriate esters or ethers, where, in the supported catalyst, an organosilicon compound is bonded, as a polyfunctional coupling agent, on the one hand to a support material and on the other hand to a noble-metal compound from group VIII of the Periodic Table of the Elements, the coupling agent is a chelate-forming organosilicon compound of the general formula ##STR1## where X=Cl, Br or --OR.sup.2 ;Y=--NR.sub.2.sup.4, a nitrogen-containing aryl radical, --PR.sub.2.sup.4, AsR.sub.2.sup.4, --SR.sup.4 or --SH;Z=zero, arylene or phenylene (optionally ortho-, meta- or para-substituted),R.sup.1 =C.sub.1 to C.sub.5 -alkyl;R.sup.2 =C.sub.1 to C.sub.5 -alkyl or --C.sub.6 H.sub.5 ;R.sup.3 =--H or C.sub.1 to C.sub.3 -alkyl;R.sup.4 =C.sub.1 to C.sub.6 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl or --C.sub.6 H.sub.5 or --CH.sub.2 C.sub.6 H.sub.5, which are optionally substituted by halogen, methoxy, ethoxy or C.sub.1 to C.sub.3 -alkyl groups;n=0 or 1 or 2;m=2 to 6, preferably 2 to 4.

    摘要翻译： 在通过合适的酯或醚的羰基化制备单羧酸酐的负载型催化剂中，其中在负载型催化剂中有机硅化合物作为多官能偶联剂一方面结合到载体材料上，另一方面 由元素周期表第Ⅷ族赋予贵金属化合物，偶联剂是通式为（a）或（IMA）（b）的螯合形成有机硅化合物，其中X = Cl， Br或-OR2; Y = -NR24，含氮芳基，-PR24，AsR24，-SR4或-SH; Z =零，亚芳基或亚苯基（任选邻 - ，间 - 或对 - 取代），R1 = C1-C5-烷基; R2 = C1-C5-烷基或-C6H5; R3 = -H或C1至C3-烷基; R4 = C1至C6-烷基，C5或C6-环烷基或-C6H5或-CH2C6H5，其任选被卤素，甲氧基，乙氧基或C1至C3-烷基取代; n = 0或1或2; m = 2〜6，优选为2〜4。

    Process for the preparation of monocarboxylic anhydrides
    8.
    发明授权
    Process for the preparation of monocarboxylic anhydrides 失效
    制备单羧酸酐的方法

    公开(公告)号：US4959498A

    公开(公告)日：1990-09-25

    申请号：US326607

    申请日：1989-03-17

    申请人： Gerhard Luft ,  Peter Trabold

    发明人： Gerhard Luft ,  Peter Trabold

    IPC分类号： B01J31/24 ,  B01J31/26 ,  C07B61/00 ,  C07C51/00 ,  C07C51/54 ,  C07C51/56 ,  C07C53/12 ,  C07C67/00

    CPC分类号： C07C51/56

    摘要： The process for the preparation of monocarboxylic anhydrides of the general formula (RCO).sub.2 O is carried out by reacting a carboxylic ester or a dialkyl ether of the general formula RCOOR or ROR, in which R in each case denotes the same alkyl radical having 1 to 4 carbon atoms, with carbon monoxide in the gas phase in the presence of a supported catalyst. The reaction takes place by means of bromine or iodine or compounds thereof as reaction promoter. The support material in the catalyst supports a noble metal chelate compound which is formed by a noble metal compound from group VIII of the periodic table and a chelating agent containing organonitrogen, organophosphorus, organoarsenic, organosulfur or mercapto groups and substituted in its basic structure with alkyl, aryl or aralkyl groups. The reaction is carried out at temperatures from 130.degree. to 400.degree. C. and pressures from 1 to 150 bar.

    摘要翻译： 制备通式（RCO）2 O的单羧酸酐的方法通过使通式RCOOR或ROR的羧酸酯或二烷基醚反应来进行，其中R在每种情况下表示相同的具有1〜 4个碳原子，在负载催化剂存在下，气相中的一氧化碳。 反应通过溴或碘或其化合物作为反应促进剂进行。 催化剂中的载体材料是由元素周期表第Ⅷ族的贵金属化合物和含有机氮，有机磷，有机砷，有机硫或巯基的螯合剂形成的贵金属螯合物，其基本结构与烷基取代 ，芳基或芳烷基。 该反应在130℃至400℃的温度和1至150巴的压力下进行。

    Process for the preparation of monocarboxylic anhydrides
    9.
    发明授权
    Process for the preparation of monocarboxylic anhydrides 失效
    制备单羧酸酐的方法

    公开(公告)号：US4952727A

    公开(公告)日：1990-08-28

    申请号：US318679

    申请日：1989-05-03

    申请人： Gerhard Luft ,  Peter Trabold

    发明人： Gerhard Luft ,  Peter Trabold

    IPC分类号： C07B61/00 ,  B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  C07C51/00 ,  C07C51/54 ,  C07C51/56 ,  C07C53/00 ,  C07C53/12 ,  C07C67/00 ,  C07F15/00

    CPC分类号： B01J31/1633 ,  B01J31/18 ,  B01J31/2409 ,  C07C51/54 ,  C07C51/56 ,  B01J2531/60 ,  B01J2531/80 ,  B01J2531/822

    摘要： In the process for the preparation of monocarboxylic anhydrides of the general formula (RCO).sub.2 O by reacting a carboxylic acid ester of dialkyl ether of the general formula RCOOR or ROR, where R in each case denotes the same alkyl radical having 1 to 4 carbon atoms, with carbon monoxide in the gas phase in the presence of iodine or bromine or compounds thereof as reaction promoter, and in the presence of a supported catalyst, at temperatures of from 130.degree. to 400.degree. C. and pressures of from 1 to 150 bar, where, in the supported catalyst, an organosilicon compound is bonded, as a polyfunctional coupling agent, on the one hand to a support material and on the other hand to a noble-metal compound from group VIII of the Periodic Table, a chelate-forming organosilicon compound of the general formula ##STR1## is employed as the polyfunctional coupling agent, where X=Cl, Br or --OR.sup.2 ;Y=-NR.sub.2.sup.4, a nitrogen-containing aryl radical, --PR.sub.2.sup.4, AsR.sub.2.sup.4, --SR.sup.4 or --SH;Z=zero, arylene or phenylene (optionally ortho-, meta-or para-substituted),R.sup.1 =C.sub.1 to C.sub.5 -alkyl;R.sup.2 =C.sub.1 to C.sub.5 -alkyl or --C.sub.6 H.sub.5 ;R.sup.3 =--H or C.sub.1 to C.sub.3 -alkyl;R.sup.4 =C.sub.1 to C.sub.5 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl or --C.sub.6 H.sub.5 or --CH.sub.2 C.sub.6 H.sub.5, which are optionally substutited by halogen, methoxy, ethoxy or C.sub.1 to C.sub.3 -alkyl groups;n=0 or 1 or 2;m=2 to 6, preferably 2 to 4.

    摘要翻译： 通过使通式RCOOR或ROR的二烷基醚的羧酸酯反应制备通式（RCO）2 O的一元羧酸酐的方法，其中每种情况下的R表示相同的具有1至4个碳原子的烷基 ，在碘或溴的存在下的气相中的一氧化碳或其化合物作为反应促进剂，并且在负载催化剂存在下，在130-400℃的温度和1-150巴的压力下 其中，在载体催化剂中，有机硅化合物作为多官能偶联剂一方面结合到载体材料上，另一方面与元素周期表第VIII族的贵金属化合物键合， 使用通式为“IMAGE”的有机硅化合物作为多官能偶联剂，其中X = Cl，Br或-OR2; Y = -NR24，含氮芳基，-PR24，AsR24，-SR4或-SH; Z =零，亚芳基或亚苯基（任选是邻位，间位或对位取代的），R1 = C1至C5-烷基; R2 = C1-C5-烷基或-C6H5; R3 = -H或C1-C3-烷基; R4 = C1至C5-烷基，C5或C6-环烷基或-C6H5或-CH2C6H5，其任选地被卤素，甲氧基，乙氧基或C1至C3-烷基取代; n = 0或1或2; m = 2〜6，优选为2〜4。