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18 条记录 (耗时 0.017 秒)

    Process for selectively producing para-substituted derivatives of phenols
    1.
    发明授权
    Process for selectively producing para-substituted derivatives of phenols 失效
    选择性生产酚取代对位取代基的方法

    公开(公告)号：US4523037A

    公开(公告)日：1985-06-11

    申请号：US530157

    申请日：1983-09-07

    申请人： Hidefumi Hirai ,  Makoto Komiyama

    发明人： Hidefumi Hirai ,  Makoto Komiyama

    IPC分类号： C07C37/18 ,  C07C39/19 ,  C07C41/16 ,  C07C43/215 ,  C07C45/00 ,  C07C45/51 ,  C07C5/393

    CPC分类号： C07C45/008 ,  C07C45/512

    摘要： By reacting, using as a catalyst a modified or unmodified cyclodextrin, a phenol compound with a haloform in the presence of an alkali metal hydroxide, while maintaining the molar ratio of the cyclodextrin to the haloform at 0.5 to 10, a substituent group derived from the haloform can be introduced to the para-position of the phenol compound with high selectivity, whereby useful para-substituted phenol derivatives can be advantageously obtained.

    摘要翻译： 通过在碱金属氢氧化物存在下使用改性或未改性的环糊精作为催化剂与卤代甲酰胺反应，同时将环糊精与卤素的摩尔比保持在0.5至10，将衍生自 可以高选择性地将卤代甲酚引入酚化合物的对位，由此可以有利地获得有用的对位取代的苯酚衍生物。

    Process for separating carbon monoxide from a gas mixture
    3.
    发明授权
    Process for separating carbon monoxide from a gas mixture 失效
    从气体混合物中分离一氧化碳的方法

    公开(公告)号：US4460384A

    公开(公告)日：1984-07-17

    申请号：US373241

    申请日：1982-04-29

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    IPC分类号： B01D53/14 ,  C01B32/40 ,  B01D19/00

    CPC分类号： C01B31/18 ,  B01D53/1493

    摘要： A process for separating carbon monoxide from a gas mixture is presented. In this process carbon monoxide contained in the gas mixture containing carbon monoxide and up to approximately 40,000 ppm of water can be effectively separated by contacting the gas mixture with an absorbing solution containing (a) at least one copper(I) halide, (b) at least one aluminum(III) halide and (c) at least one compound having at least two benzene nuclei in one molecule thereof. The component (c) is selected from the group consisting of (A) the compounds having the general formula (I): ##STR1## wherein R.sub.1 is hydrogen or an alkyl group, R.sub.2 and R.sub.3 are independently hydrogen, an alkyl group, or an aryl group, i is 0, 1, 2, 3, or 4, and m and n are independently 0, 1, 2, or 3, (B) the oligomers styrene or the derivatives thereof, (C) the polymers of styrene or the derivatives thereof and (D) copolymers of (i) styrene or the derivatives thereof and (ii) ethylene or the derivatives thereof and, optionally, an aromatic solvent, without causing the decrease in the carbon monoxide absorbing and releasing capacities of the absorbing solution.

    摘要翻译： 提出了从气体混合物中分离一氧化碳的方法。 在该方法中，通过使气体混合物与含有（a）至少一种卤化铜（I）的吸收溶液接触，（b）将含有一氧化碳和高达约40,000ppm水的气体混合物中所含的一氧化碳， 至少一种卤化铝（III）和（c）至少一种在其一个分子中具有至少两个苯核的化合物。 组分（c）选自（A）具有通式（I）的化合物：其中R 1是氢或烷基，R 2和R 3独立地是氢，烷基 ，或芳基，i为0,1,2,3或4，m和n分别为0,1,2或3，（B）低聚物苯乙烯或其衍生物，（C）聚合物 的苯乙烯或其衍生物，和（D）（i）苯乙烯或其衍生物和（ii）乙烯或其衍生物和任选的芳族溶剂的共聚物，而不会导致一氧化碳吸收和释放能力的降低 吸收溶液。

    Solid absorbent for unsaturated hydrocarbon and process for separation of unsaturated hydrocarbon from gas mixture
    4.
    发明授权
    Solid absorbent for unsaturated hydrocarbon and process for separation of unsaturated hydrocarbon from gas mixture 失效
    不饱和烃的固体吸收剂和不饱和烃与气体混合物的分离方法

    公开(公告)号：US4747855A

    公开(公告)日：1988-05-31

    申请号：US6343

    申请日：1987-01-21

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    IPC分类号： B01J20/20 ,  C07C7/12 ,  B01D53/04

    CPC分类号： B01J20/20 ,  C07C7/12

    摘要： A solid adsorbent for an unsaturated hydrocarbon including (a) (i) a copper(I) halide or oxide or (ii) a halide, carboxylate, sulfate, basic salt, oxide, or amine complex salt of copper(II) and (b) activated carbon or graphite is described.This solid adsorbent can effectively adsorb an unsaturated hydrocarbon such as ethylene from a gas mixture by being placed in contact with the gas mixture at a temperature of -40.degree. C. to 90.degree. C. under normal pressure.

    摘要翻译： 包括（a）（i）卤化铜（I）或氧化物的铜（I）或（ii）铜（II）和（b）的卤化物，羧酸盐，硫酸盐，碱性盐，氧化物或胺络合物的固体吸附剂 ）活性炭或石墨。 这种固体吸附剂可以在常压下在-40℃至90℃的温度下与气体混合物接触，从气体混合物中有效吸附不饱和烃如乙烯。

    Process for recovery of ethylene from gaseous mixture
    6.
    发明授权
    Process for recovery of ethylene from gaseous mixture 失效
    从气体混合物中回收乙烯的方法

    公开(公告)号：US4525180A

    公开(公告)日：1985-06-25

    申请号：US590417

    申请日：1984-03-15

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Susumu Hara

    IPC分类号： C07C7/11 ,  B01D19/00

    CPC分类号： C07C7/11

    摘要： With application of new liquid absorbent, comprised of a compound selected from a group composed of silver halide and cuprous halide, an aluminium halide, a polymer selected from a group composed of styrene and styrene derivatives, and an aromatic hydrocarbon, it is possible to recover ethylene by absorbing ethylene from gaseous mixture containing ethylene such as FCC off gas, ethylene plant off gas and coke oven gas. In particular, said liquid absorbent is neither diluted nor reduced its capability to absorb ethylene by water or its vapor contained in the said gaseous mixture, so the liquid absorbent can be used repeatedly for the recovery of ethylene from gaseous mixture containing ethylene and water or its vapor, without any pretreatment to reduce the water content of said gaseous mixture.

    摘要翻译： 使用由选自卤化银和卤化亚铜组成的组中的化合物，卤化铝，选自苯乙烯和苯乙烯衍生物的组分的聚合物和芳族烃构成的新的液体吸收剂的应用，可以回收 乙烯通过从含有乙烯的气体混合物如FCC废气，乙烯装置废气和焦炉气体中吸收乙烯。 特别地，所述液体吸收剂既不稀释也不降低其吸收所述气体混合物中所含的水或其蒸汽的乙烯的能力，因此可以重复使用液体吸收剂以从含有乙烯和水的气体混合物回收乙烯或其 蒸气，没有任何预处理以减少所述气体混合物的水含量。

    Method for separating carbon dioxide from mixed gas
    7.
    发明授权
    Method for separating carbon dioxide from mixed gas 失效
    从混合气体中分离二氧化碳的方法

    公开(公告)号：US4587114A

    公开(公告)日：1986-05-06

    申请号：US475258

    申请日：1983-03-14

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    IPC分类号： B01J20/20 ,  C01B32/40 ,  B01J21/18

    CPC分类号： C01B31/18 ,  B01J20/20

    摘要： A solid form adsorbent of carbon monoxide, that is obtained by the process including the following steps. First, copper salts or copper oxide is stirred in a solvent. Then, into the solution or suspension thus obtained, active carbon is added. Finally, the solvent is removed by means of pressure reduction, distillation, etc. The carbon monoxide adsorbent produced according to this invention adsorbs carbon monoxide rapidly when it is brought into contact with a mixed gas. The adsorbed carbon monoxide can be readily separated and discharged through either heating the carbon monoxide adsorbent to above 60.degree. C. or reducing the partial pressure of carbon monoxide. The carbon monoxide obtained in accordance with the present invention is stable relative to the water content in the mixed gas, and it is capable of separating carbon monoxide directly from the mixed gas containing the water. Also, the separated carbon monoxide does not contain the vapor of the solvent from the carbon monoxide adsorbent. Therefore, it is not necessary to provide equipment to collect the solvent vapor. Furthermore, this carbon monoxide adsorbent does not produce corrosive gases, etc. The carbon monoxide adsorbent obtained by using copper (II) salts or copper (II) oxide is also stable relative to sulfur content in the mixed gas.

    摘要翻译： 一氧化碳的固体形式吸附剂，其通过包括以下步骤的方法获得。 首先，将铜盐或氧化铜在溶剂中搅拌。 然后，加入如此获得的溶液或悬浮液中，加入活性炭。 最后，通过减压，蒸馏等除去溶剂。根据本发明生产的一氧化碳吸附剂在与混合气体接触时迅速吸附一氧化碳。 吸附的一氧化碳可以通过将一氧化碳吸附剂加热至60℃以上或者降低一氧化碳的分压来容易地分离和排出。 根据本发明获得的一氧化碳相对于混合气体中的含水量是稳定的，并且能够直接从含有水的混合气体中分离一氧化碳。 此外，分离的一氧化碳不含来自一氧化碳吸附剂的溶剂的蒸气。 因此，不需要提供收集溶剂蒸汽的设备。 此外，该一氧化碳吸附剂不产生腐蚀性气体等。使用铜（II）盐或氧化铜（II））得到的一氧化碳吸附剂相对于混合气体中的硫含量也是稳定的。

    Colloidal metal dispersion, and a colloidal metal complex
    9.
    发明授权
    Colloidal metal dispersion, and a colloidal metal complex 失效
    胶体金属分散体和胶体金属络合物

    公开(公告)号：US5187209A

    公开(公告)日：1993-02-16

    申请号：US745978

    申请日：1991-08-12

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Michitaka Otaki

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Michitaka Otaki

    IPC分类号： A61K9/51 ,  A61K49/00 ,  B01J13/00 ,  B01J35/00 ,  C12N15/02 ,  C12Q1/68

    CPC分类号： C12Q1/6888 ,  A61K49/0002 ,  B01J13/0034 ,  B01J13/0043 ,  C12N15/02 ,  C12Q1/6827 ,  B01J35/0013 ,  Y10T428/2991 ,  Y10T428/2998

    摘要： Thers is disclosed a novel colloidal metal dispersion in which colloidal particles of a metal are protected by specific polymers including hydrazide polymers, acrylic ester polymers and acrylamide polymers. The colloidal metal dispersion is highly stable, and the colloidal metal particles protected by such specific polymers can be easily and strongly bound to various amino group-containing compounds to give stable colloidal metal complexes, which have a wide variety of uses, such as the use as a solid catalyst, the use for the treatment and diagnosis of various diseases, the use for studying tissues of living bodies, the use for inducing mutation of microorganisms, etc.

    摘要翻译： Thers公开了一种新型胶体金属分散体，其中金属的胶体颗粒由包括酰肼聚合物，丙烯酸酯聚合物和丙烯酰胺聚合物的特定聚合物保护。 胶态金属分散体是高度稳定的，由这些特定聚合物保护的胶体金属颗粒可以容易且强烈地结合到各种含氨基的化合物上，得到稳定的胶​​体金属络合物，其具有多种用途，例如使用 作为固体催化剂，用于各种疾病的治疗和诊断，用于研究活体组织的用途，诱导微生物突变的用途等。