公开(公告)号：US20060238168A1

公开(公告)日：2006-10-26

申请号：US10569210

申请日：2004-08-18

申请人： Hidehito Matsuo ,  Tetsuro Kobayashi ,  Yuichi Itou ,  Yasuhito Kondo ,  Yoshio Ukto ,  Yoshiaki Kikuchi ,  Motoyoshi Okumura

发明人： Hidehito Matsuo ,  Tetsuro Kobayashi ,  Yuichi Itou ,  Yasuhito Kondo ,  Yoshio Ukto ,  Yoshiaki Kikuchi ,  Motoyoshi Okumura

IPC分类号： H02J7/00 ,  G01N27/416

CPC分类号： G01R31/3679

摘要： A battery characteristic detecting method according to the invention includes a first step in which constant current discharge from a battery is performed at a predetermined current value, and a voltage during constant current discharge is measured; a second step in which overpotential for mass transfer control in the battery or resistance for the mass transfer control in the battery is calculated based on the voltage measured in the first step; and a third step in which a determination that a characteristic change has occurred in the battery is made, when the overpotential for the mass transfer control in the battery or the resistance for the mass transfer control in the battery calculated in the second step is larger than a predetermined threshold value.

摘要翻译： 根据本发明的电池特性检测方法包括第一步骤，其中以预定电流值执行来自电池的恒流放电，并且测量恒流放电期间的电压; 基于在第一步骤中测量的电压计算电池中的传质控制的过电位或电池中的质量传递控制的电阻的第二步骤; 以及第三步骤，当在第二步骤中计算的电池中的质量传递控制的超电势或电池中的质量传递控制的电阻大于大于电池的特性变化的判定时， 预定的阈值。

公开(公告)号：US07675291B2

公开(公告)日：2010-03-09

申请号：US10569210

申请日：2004-08-18

申请人： Hidehito Matsuo ,  Tetsuro Kobayashi ,  Yuichi Itou ,  Yasuhito Kondo ,  Yoshio Ukyo ,  Yoshiaki Kikuchi ,  Motoyoshi Okumura

发明人： Hidehito Matsuo ,  Tetsuro Kobayashi ,  Yuichi Itou ,  Yasuhito Kondo ,  Yoshio Ukyo ,  Yoshiaki Kikuchi ,  Motoyoshi Okumura

IPC分类号： G01N27/416

CPC分类号： G01R31/3679

摘要： A battery characteristic detecting method according to the invention includes a first step in which constant current discharge from a battery is performed at a predetermined current value, and a voltage during constant current discharge is measured; a second step in which overpotential for mass transfer control in the battery or resistance for the mass transfer control in the battery is calculated based on the voltage measured in the first step; and a third step in which a determination that a characteristic change has occurred in the battery is made, when the overpotential for the mass transfer control in the battery or the resistance for the mass transfer control in the battery calculated in the second step is larger than a predetermined threshold value.

摘要翻译： 根据本发明的电池特性检测方法包括第一步骤，其中以预定电流值执行来自电池的恒流放电，并且测量恒流放电期间的电压; 基于在第一步骤中测量的电压计算电池中的传质控制的过电位或电池中的质量传递控制的电阻的第二步骤; 以及第三步骤，当在第二步骤中计算的电池中的质量传递控制的超电势或电池中的质量传递控制的电阻大于大于电池的特性变化的判定时， 预定的阈值。

公开(公告)号：US20080274405A1

公开(公告)日：2008-11-06

申请号：US11628302

申请日：2005-05-30

申请人： Tetsuro Kobayashi ,  Yasuhito Kondo ,  Hidehito Matsuo ,  Tsuyoshi Sasaki ,  Yuichi Itou ,  Hiroshi Nozaki ,  Takamasa Nonaka ,  Yoshiki Seno ,  Yoshio Ukyo ,  Masanori Ito

发明人： Tetsuro Kobayashi ,  Yasuhito Kondo ,  Hidehito Matsuo ,  Tsuyoshi Sasaki ,  Yuichi Itou ,  Hiroshi Nozaki ,  Takamasa Nonaka ,  Yoshiki Seno ,  Yoshio Ukyo ,  Masanori Ito

IPC分类号： H01M4/52 ,  C01G53/04

CPC分类号： H01M4/32 ,  C01G53/04 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/52 ,  H01M4/808 ,  H01M10/30 ,  H01M2004/021 ,  H01M2004/028

摘要： The present invention is to provide a cathode active material for an alkaline battery with a lamellar crystal structure including nickel oxyhydroxide. The cathode active material has a diffraction peak at a position that ranges from 8.4 degrees to 10.4 degrees in diffraction angle 2θ by X-ray diffraction using CuKα-rays. In addition, the present invention provides an alkaline battery having a cathode having a cathode active material, an anode having an anode active material, and an alkaline water solution as an electrolytic solution. Furthermore, the present invention provides a manufacturing method for a cathode active material for an alkaline battery with a lamellar crystal structure including nickel oxyhydroxide. The manufacturing method has an oxidation process for manufacturing the cathode active material by oxidizing a starting material made from β-type nickel hydroxide with a lamellar crystal structure in an airstream including alkaline water solution or alkali.

摘要翻译： 本发明提供一种具有包括羟基氧化镍的层状晶体结构的碱性电池用正极活性物质。 阴极活性物质通过使用CuKα射线的X射线衍射，在衍射角2θ的范围为8.4〜10.4度的位置具有衍射峰。 此外，本发明提供一种具有阴极的碱性电池，其具有正极活性物质，具有负极活性物质的阳极和作为电解液的碱性水溶液。 此外，本发明提供一种具有包括氢氧化正镍的层状晶体结构的碱性电池用正极活性物质的制造方法。 该制造方法具有通过在包括碱性水溶液或碱的气流中以层状晶体结构氧化由β型氢氧化镍制成的起始材料来制造正极活性物质的氧化方法。

公开(公告)号：US20080254366A1

公开(公告)日：2008-10-16

申请号：US11628191

申请日：2005-05-30

申请人： Tetsuro Kobayashi ,  Yasuhito Kondo ,  Hidehito Matsuo ,  Tsuyoshi Sasaki ,  Yuichi Itou ,  Hiroshi Nozaki ,  Takamasa Nonaka ,  Yoshiki Seno ,  Yoshio Ukyo ,  Masanori Ito

发明人： Tetsuro Kobayashi ,  Yasuhito Kondo ,  Hidehito Matsuo ,  Tsuyoshi Sasaki ,  Yuichi Itou ,  Hiroshi Nozaki ,  Takamasa Nonaka ,  Yoshiki Seno ,  Yoshio Ukyo ,  Masanori Ito

IPC分类号： H01M4/00

CPC分类号： H01M4/32 ,  H01M4/52 ,  H01M4/62 ,  H01M10/30 ,  Y02E60/124

摘要： An alkaline storage battery 1 has: a cathode 2 containing β-type nickel hydroxide and/or β-type nickel oxyhydroxide as a cathode active material; an anode 3 containing an anode active material; and an alkaline aqueous solution as an electrolytic solution 4. The alkaline storage battery 1 is configured to restrain at least part of a crystal structure of the cathode active material from changing due to charging or discharging and to restrain the cathode active material from exhibiting a new diffraction peak at a position that ranges from 8.4 degrees to 10.4 degrees in X-ray diffraction angle 2θ by X-ray diffraction using CuKα-rays. It is preferable that an anion-exchange membrane layer 25 should be provided on a surface of the cathode 2.

摘要翻译： 碱性蓄电池1具有：含有β型氢氧化镍和/或β型氢氧化正镍作为正极活性物质的阴极2; 含有负极活性物质的阳极3; 和作为电解液4的碱性水溶液。碱性蓄电池1被配置为抑制正极活性物质的晶体结构的至少一部分由于充电或放电而变化，并且抑制正极活性物质显示新的 通过X射线衍射使用CuKalpha射线，X射线衍射角2θ在8.4〜10.4度的范围内的衍射峰。 阴极2的表面优选设置阴离子交换膜层25。

公开(公告)号：US20110239446A1

公开(公告)日：2011-10-06

申请号：US13139319

申请日：2009-12-11

申请人： Ryuta Morishima ,  Hitoshi Sakai ,  Hiroaki Ikeda ,  Hiroyuki Akita ,  Hidehito Matsuo

发明人： Ryuta Morishima ,  Hitoshi Sakai ,  Hiroaki Ikeda ,  Hiroyuki Akita ,  Hidehito Matsuo

IPC分类号： H01M4/1393

CPC分类号： H01M10/0525 ,  H01M4/0404 ,  H01M4/131 ,  H01M4/133 ,  H01M4/1393 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/621 ,  H01M4/75 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49108 ,  Y10T29/49115

摘要： A method is provided for manufacturing an electrode that has a porous inorganic layer on the surface of an active material layer and is suitable for constructing a nonaqueous secondary battery with excellent input-output performance. In this manufacturing method, an electrode perform, which has an active material layer (344) consisting primarily of active material particles (42) and supported on a collector (342), is prepared. The water concentration of at least the surface (344a) of the active material layer (344) is adjusted to 100 ppm to 500 ppm. A slurry (S) containing inorganic particles (44), a binder and an organic solvent is coated on the surface (344a) of the active material layer with the water concentration thus adjusted, to form a porous inorganic layer.

摘要翻译： 提供一种制造在活性物质层的表面具有多孔无机层的电极的方法，适用于构成输出输出性能优良的非水二次电池。 在该制造方法中，准备具有主要由活性物质粒子（42）构成并负载在集电体（342）上的活性物质层（344）的电极。 将至少活性物质层（344）的表面（344a）的水浓度调整为100ppm〜500ppm。 将含有无机颗粒（44），粘合剂和有机溶剂的浆料（S）以如此调节的水浓度涂覆在活性物质层的表面（344a）上，形成多孔无机层。

公开(公告)号：US09083056B2

公开(公告)日：2015-07-14

申请号：US13139319

申请日：2009-12-11

申请人： Ryuta Morishima ,  Hitoshi Sakai ,  Hiroaki Ikeda ,  Hiroyuki Akita ,  Hidehito Matsuo

发明人： Ryuta Morishima ,  Hitoshi Sakai ,  Hiroaki Ikeda ,  Hiroyuki Akita ,  Hidehito Matsuo

IPC分类号： H01M4/133 ,  H01M10/0525 ,  H01M4/04 ,  H01M4/131 ,  H01M4/1393 ,  H01M4/587 ,  H01M4/62 ,  H01M4/75 ,  H01M4/505 ,  H01M4/525

CPC分类号： H01M10/0525 ,  H01M4/0404 ,  H01M4/131 ,  H01M4/133 ,  H01M4/1393 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/621 ,  H01M4/75 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49108 ,  Y10T29/49115

摘要： A method is provided for manufacturing an electrode that has a porous inorganic layer on the surface of an active material layer and is suitable for constructing a nonaqueous secondary battery with excellent input-output performance. In this manufacturing method, an electrode perform, which has an active material layer (344) consisting primarily of active material particles (42) and supported on a collector (342), is prepared. The water concentration of at least the surface (344a) of the active material layer (344) is adjusted to 100 ppm to 500 ppm. A slurry (S) containing inorganic particles (44), a binder and an organic solvent is coated on the surface (344a) of the active material layer with the water concentration thus adjusted, to form a porous inorganic layer.

摘要翻译： 提供一种制造在活性物质层的表面具有多孔无机层的电极的方法，适用于构成输出输出性能优良的非水二次电池。 在该制造方法中，准备具有主要由活性物质粒子（42）构成并负载在集电体（342）上的活性物质层（344）的电极。 将至少活性物质层（344）的表面（344a）的水浓度调整为100ppm〜500ppm。 将含有无机颗粒（44），粘合剂和有机溶剂的浆料（S）以如此调节的水浓度涂覆在活性物质层的表面（344a）上，形成多孔无机层。

公开(公告)号：US20110281161A1

公开(公告)日：2011-11-17

申请号：US13146034

申请日：2009-02-09

申请人： Hiroaki Ikeda ,  Hitoshi Sakai ,  Ryuta Morishima ,  Hiroyuki Akita ,  Hidehito Matsuo

发明人： Hiroaki Ikeda ,  Hitoshi Sakai ,  Ryuta Morishima ,  Hiroyuki Akita ,  Hidehito Matsuo

IPC分类号： H01M10/052 ,  H01M4/13

CPC分类号： H01M4/62 ,  H01M4/13 ,  H01M4/366 ,  H01M4/621 ,  H01M4/622 ,  H01M10/0525 ,  Y02T10/7011

摘要： The lithium secondary battery provided by the present invention includes an electrode provided with an insulating particle-containing layer (34) having a configuration in which an active material layer (344) is retained on a current collector (342), and an insulating particle-containing layer (346), containing insulating particles (44) and a binder (46), is provided on the active material layer (344). A portion (346A) of the insulating particle-containing layer (346) facing the active material layer contains the binder (46) at a higher weight content than a portion (346B) facing an outer surface thereof.

摘要翻译： 本发明提供的锂二次电池包括：具有绝缘粒子的层（34）的电极，其具有在集电体（342）上保持活性物质层（344）的构造， 在活性物质层（344）上设置含有绝缘粒子（44）和粘合剂（46）的含氧层（346）。 面向活性物质层的绝缘颗粒含有层（346）的部分（346A）含有比面向其外表面的部分（346B）更高的重量含量的粘合剂（46）。