Alicyclic diepoxy compound, epoxy resin composition comprising the same, and cured article therefrom
    1.
    发明授权
    Alicyclic diepoxy compound, epoxy resin composition comprising the same, and cured article therefrom 有权
    脂环式二环氧化合物,包含该环氧化合物的环氧树脂组合物及其固化物

    公开(公告)号:US07989523B2

    公开(公告)日:2011-08-02

    申请号:US12305906

    申请日:2007-06-29

    摘要: Disclosed is an alicyclic diepoxy compound which gives a cured article suffering from no deterioration in properties even when used in hot and humid surroundings or used under such conditions as to give a strong acid, which is highly reactive upon curing, and which gives a cured article superior typically in thermal stability. Specifically, the alicyclic diepoxy compound includes a 3,4,3′,4′-diepoxybicyclohexyl compound represented by following Formula (1): wherein R1 to R18 each represent a hydrogen atom, a halogen atom, a hydrocarbon group which may have an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group, in which the alicyclic diepoxy compound contains isomers of the 3,4,3′,4′-diepoxybicyclohexyl compound in a content of less than 20% based on the total of the 3,4,3′,4′-diepoxybicyclohexyl compound and the isomers thereof in terms of peak area ratio as determined by gas chromatography.

    摘要翻译: 公开了一种脂环式二环氧化合物,即使在热湿环境下使用也不会劣化的固化物,或者在固化时具有高反应性的强酸的条件下使用,得到固化物 优良的热稳定性。 具体地,脂环族二环氧化合物包括由下式(1)表示的3,4,3',4'-二环氧双环己基化合物:其中R 1至R 18各自表示氢原子,卤素原子,可具有氧的烃基 原子或卤素原子或取代或未取代的烷氧基,其中脂环式二环氧化合物含有3,4,3',4'-二环氧基双环己基化合物的异构体,其含量小于20% 3,4,3',4'-二环氧双环己基化合物及其异构体,以气相色谱法测定的峰面积比。

    Electrophotographic photosensitive member, process cartridge including
same and electrophotographic apparatus
    3.
    发明授权
    Electrophotographic photosensitive member, process cartridge including same and electrophotographic apparatus 失效
    电子照相感光构件,包括其的处理盒和电子照相设备

    公开(公告)号:US5543257A

    公开(公告)日:1996-08-06

    申请号:US345707

    申请日:1994-11-22

    IPC分类号: G03G5/06

    CPC分类号: G03G5/0681

    摘要: An electrophotographic photosensitive member is constituted by an electroconductive support and a photosensitive layer disposed on the electroconductive support. The photosensitive layer contains a specific disazo pigment having a 2,2'-bis-1,3-benzdithiolene-diyl skeleton or a thiophene-diyl skeleton. The photosensitive member is effective for providing a process cartridge and an electrophotographic apparatus respectively including the photosensitive member with an excellent photosensitivity and a stable electric potential in repetitive use.

    摘要翻译: 电子照相感光构件由导电载体和设置在导电载体上的感光层构成。 感光层含有具有2,2'-双-1,3-苯并二硫戊烯 - 二基骨架或噻吩 - 二基骨架的特定双偶氮颜料。 感光构件有效地提供分别包括感光构件的处理盒和电子照相装置,其具有优异的光敏性和重复使用的稳定的电位。

    Electrophotographic photosensitive member and electrophotographic
apparatus, device unit and facsimile machine using the same
    4.
    发明授权
    Electrophotographic photosensitive member and electrophotographic apparatus, device unit and facsimile machine using the same 失效
    电子照相感光构件和电子照相设备,设备单元和使用其的传真机

    公开(公告)号:US5466550A

    公开(公告)日:1995-11-14

    申请号:US329381

    申请日:1994-10-25

    IPC分类号: G03G5/05 C08G5/14

    CPC分类号: G03G5/0542

    摘要: An electrophotographic photosensitive member has a conductive support, and a charge generating layer and a charge transporting layer. The charge generating layer contains an acetal resin obtained from a reaction of polyvinyl alcohol, alkyl aldehyde having a structure shown in Formula (1) below, and aryl aldehyde having a structure shown in Formula (2) below:R--CHO (1)wherein R is a substituted or unsubstituted, chain or cyclic alkyl group, andAr--CHO (2)wherein Ar is a substituted or unsubstituted aryl group. The electrophotographic photosensitive member is used in electrophotographic apparatus, device units and facsimile machines, while ensuring superior electrophotographic characteristics and an excellent image free from fog.

    摘要翻译: 电子照相感光构件具有导电性支持体,电荷产生层和电荷输送层。 电荷产生层含有通过聚乙烯醇,具有下述通式(1)所示结构的烷基醛与下式(2)所示结构的芳基醛的反应获得的缩醛树脂:R-CHO(1)其中 R是取代或未取代的链或环状烷基,Ar-CHO(2)其中Ar是取代或未取代的芳基。 电子照相感光构件用于电子照相设备,设备单元和传真机,同时确保优异的电子照相特性和优异的图像无雾。

    Composition containing cycloaliphatic epoxide, polyol oligomer, curing agent and curing accelerator
    8.
    发明授权
    Composition containing cycloaliphatic epoxide, polyol oligomer, curing agent and curing accelerator 有权
    含脂环族环氧化物,多元醇低聚物,固化剂和固化促进剂的组合物

    公开(公告)号:US07825197B2

    公开(公告)日:2010-11-02

    申请号:US11667549

    申请日:2005-12-09

    IPC分类号: C08L63/00 H01L23/29

    摘要: A liquid thermosetting epoxy resin composition contains a base resin in combination with a curing agent and a curing accelerator or with a curing catalyst. The base resin includes a cycloaliphatic epoxy compound having at least one alicyclic skeleton and two or more epoxy groups per molecule, and a polyol oligomer having two or more terminal hydroxyl groups. An optical semiconductor device includes an optical semiconductor element sealed by using the liquid thermosetting epoxy resin composition. The composition yields a cured resinous product which is free from curing failure, is optically homogenous, has a low elastic modulus in bending, a high bending strength, a high glass transition temperature, a high optical transparency and is useful for optical semiconductors.

    摘要翻译: 液态热固性环氧树脂组合物含有与固化剂和固化促进剂或固化催化剂组合的基础树脂。 基础树脂包括每分子具有至少一个脂环骨架和两个或更多个环氧基团的脂环族环氧化合物和具有两个或更多个末端羟基的多元醇低聚物。 光学半导体器件包括通过使用液态热固性环氧树脂组合物密封的光学半导体元件。 该组合物产生无固化失效的固化树脂产品,光学上均匀,弯曲时具有低弹性模量,高弯曲强度,高玻璃化转变温度,高光学透明度,并且可用于光学半导体。

    Process for preparation of alicyclic diepoxy compounds, curable epoxy resin compositions, epoxy resin compositions for the encapsulation of electronic parts, stabilizers for electrical insulating oils, and casting epoxy resin compositions for electrical insulation
    9.
    发明申请
    Process for preparation of alicyclic diepoxy compounds, curable epoxy resin compositions, epoxy resin compositions for the encapsulation of electronic parts, stabilizers for electrical insulating oils, and casting epoxy resin compositions for electrical insulation 有权
    脂环式二环氧化合物的制备方法,可固化环氧树脂组合物,用于电子部件的包封的环氧树脂组合物,用于电绝缘油的稳定剂和用于电绝缘的浇铸环氧树脂组合物

    公开(公告)号:US20090131547A1

    公开(公告)日:2009-05-21

    申请号:US12314222

    申请日:2008-12-05

    IPC分类号: C08G59/14 C08G59/02

    摘要: An alicyclic diepoxy compound (A) represented by formula (I) is produced in high purity and high yield at low cost, by epoxidizing the corresponding alicyclic diolefin compound with an organic percarboxylic acid. The curable epoxy resin composition has high reactivity for various curing agents, low viscosity, and excellent workability. A cured product thereof shows useful physical properties for uses in coatings, inks, adhesives, sealants, and encapsulants, etc. It is of extremely high quality as an epoxy resin composition for the encapsulation of electronic parts. A stabilizer for an electrical insulating oil (the alicyclic diepoxy compound or an electrical insulting oil containing the compound) is low in acid value, and the stabilizer improves the properties of the insulating oil. A cured product obtained by curing a casting epoxy resin composition for electrical insulation has excellent properties such as high bending strength, high Tg, and low permittivity.

    摘要翻译: 通过用有机过羧酸将相应的脂环族二烯烃化合物环氧化,以低成本制备高纯度和高收率的由式(I)表示的脂环族二环氧化合物(A)。 可固化环氧树脂组合物对各种固化剂具有高反应性,低粘度和优异的可加工性。 其固化产物显示出用于涂料,油墨,粘合剂,密封剂和密封剂等中的有用的物理性能。作为用于电子部件的封装的环氧树脂组合物具有极高的质量。 用于电绝缘油(脂环族二环氧化合物或含有该化合物的电绝缘油)的稳定剂的酸值低,稳定剂改善了绝缘油的性能。 通过固化用于电绝缘的铸塑环氧树脂组合物获得的固化产物具有优异的性能,例如高弯曲强度,高Tg和低介电常数。

    Method for Producing Cyclic Olefin Compound
    10.
    发明申请
    Method for Producing Cyclic Olefin Compound 有权
    生产环烯烃化合物的方法

    公开(公告)号:US20090062580A1

    公开(公告)日:2009-03-05

    申请号:US12226356

    申请日:2007-04-11

    IPC分类号: C07C1/24 C07C13/28

    摘要: Disclosed is a method for producing a cyclic olefin compound having two or more cyclohexene rings per molecule via intramolecular dehydration of an alicyclic alcohol having two or more hydroxylated cyclohexane rings per molecule. The method includes the step (i) of heating the alicyclic alcohol at a temperature of 130° C. to 230° C. and a pressure greater than 20 Torr in an organic solvent in the presence of a dehydration catalyst, to carry out dehydration of the alicyclic alcohol while distilling off by-product water, which dehydration catalyst is liquid or soluble in a liquid reaction mixture under the reaction conditions; and the subsequent step (ii) of heating the resulting reaction mixture at a temperature of 50° C. to 220° C. and a pressure of 200 Torr or less to recover the cyclic olefin compound as a distillate. According to the method, side reactions such as isomerization are suppressed, and high-purity cyclic olefin compounds with less impurities can be simply and efficiently obtained in high yields.

    摘要翻译: 公开了通过每分子具有两个或更多个羟基化环己烷环的脂环醇的分子内脱水来制备每分子具有两个或更多个环己烯环的环状烯烃化合物的方法。 该方法包括在脱水催化剂存在下,在有机溶剂中,在130℃至230℃的温度和大于20托的压力下加热脂环醇的步骤(i),以进行脱水 在反应条件下蒸馏出副产物水的脂环醇,该脱水催化剂为液体或可溶于液体反应混合物; 和随后的步骤(ii)在50℃至220℃的温度和200托或更低的压力下加热所得反应混合物以回收作为馏出物的环状烯烃化合物。 根据该方法,可以抑制异构化等副反应,能够以高收率简单高效地得到杂质较少的高纯度环状烯烃化合物。