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公开(公告)号：US20060079624A1
公开(公告)日：2006-04-13
申请号：US10961862
申请日：2004-10-08
Applicant: Hildeberto Nava , Aaron Small
Inventor： Hildeberto Nava , Aaron Small
CPC classification number: C08L25/08 , C08F299/00 , C08K5/098 , C08L25/14 , C08L67/06 , C08L2666/14 , C08L2666/06
Abstract: The present invention provides a crosslinkable polymer system that can be crosslinked to form a wide variety of polymeric, copolymeric and oligomeric compounds. The crosslinkable system comprises (a) product Q formed from an aromatic ethylenically unsaturated moiety and a first reactive ethylenically unsaturated moiety, and (b) a second reactive ethylenically unsaturated moiety at least partially reacted with the first reactive ethylenically unsaturated moiety.
Abstract translation: 本发明提供可交联以形成多种聚合物，共聚物和低聚物的交联性聚合物体系。 可交联体系包含（a）由芳族烯属不饱和部分和第一反应性烯属不饱和部分形成的产物Q，和（b）至少部分与第一反应性烯属不饱和部分反应的第二反应性烯属不饱和部分。
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公开(公告)号：US5998568A
公开(公告)日：1999-12-07
申请号：US231192
申请日：1999-01-14
Applicant: Hildeberto Nava , Karin F. Nelson-Baron
Inventor： Hildeberto Nava , Karin F. Nelson-Baron
CPC classification number: C08G63/42
Abstract: A method for making a polyester resin comprises reacting a first polyfunctional alcohol or polyfunctional thiol and a carbonate in the presence of a catalyst to form an alkoxylated intermediate. The catalyst comprises: (1) a metal, a salt of a metal, or mixtures thereof and (2) a quaternary ammonium salt, a tertiary amine, an imidazole, or mixtures thereof. The alkoxylated intermediate is then reacted with a polyfunctional organic acid or anhydride thereof to form the polyester resin.
Abstract translation: 制备聚酯树脂的方法包括在催化剂存在下使第一多官能醇或多官能硫醇和碳酸酯反应形成烷氧基化中间体。 催化剂包括：（1）金属，金属盐或其混合物，和（2）季铵盐，叔胺，咪唑或其混合物。 然后将烷氧基化中间体与多官能有机酸或其酸酐反应以形成聚酯树脂。
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公开(公告)号：US08110650B2
公开(公告)日：2012-02-07
申请号：US13185816
申请日：2011-07-19
Applicant: Hildeberto Nava , Lianzhou Chen
Inventor： Hildeberto Nava , Lianzhou Chen
IPC: C08G63/48
CPC classification number: C08G63/48 , C08K5/32 , C08K5/3435 , C08L67/08
Abstract: Methods of making unsaturated polyester compositions are provided and include reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers and reinforcements.
Abstract translation: 提供制备不饱和聚酯组合物的方法，包括：（i）植物和动物油甘油三酸酯，饱和或不饱和脂肪酸的烷基酯或其混合物; （ii）双官能或多官能二醇或其混合物; （iii）双官能或多官能酸，它们的酸酐或烷基酯及其混合物; （iv）应变环烯; （v）作为能够在高温下引发聚合并在室温下稳定的化合物起作用的组分; 和（vi）低调添加剂，填料和增强剂。
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公开(公告)号：US20110207950A1
公开(公告)日：2011-08-25
申请号：US13024547
申请日：2011-02-10
Applicant: Hildeberto Nava , Yongning Liu
Inventor： Hildeberto Nava , Yongning Liu
IPC: C07D303/16
Abstract: The present invention provides a process for forming vinyl-containing compounds including the steps of: a) reacting in a nitrogen atmosphere a dicarboxylic acid and/or anhydride and a functional mono or polyfunctional alcohol to provide a hydroxyl-containing polyester; b) reacting the hydroxyl-containing polyester with a vinyl-containing organic acid in the presence of an esterification catalyst, a polymerization inhibitor and an azeotropic agent; and c) reacting the vinyl functional esterified intermediate, residual esterification catalyst and residual vinyl-containing organic acid with an epoxy to provide the vinyl-containing compound.
Abstract translation: 本发明提供一种形成含乙烯基化合物的方法，包括以下步骤：a）在氮气气氛中使二羧酸和/或酸酐与官能单官能或多官能醇反应，得到含羟基的聚酯; b）在酯化催化剂，阻聚剂和共沸剂的存在下使含羟基的聚酯与含乙烯基的有机酸反应; 和c）使乙烯基官能酯化的中间体，残余酯化催化剂和残留的含乙烯基的有机酸与环氧树脂反应，以提供含乙烯基的化合物。
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公开(公告)号：US06884841B2
公开(公告)日：2005-04-26
申请号：US10771053
申请日：2004-02-03
Applicant: Hildeberto Nava
Inventor： Hildeberto Nava
CPC classification number: B29C70/50 , B29K2033/08 , B29K2063/00 , B29K2067/06 , B32B17/067 , B32B27/12 , D06M17/04 , D06M17/06 , Y10T428/31616 , Y10T428/31645 , Y10T428/31786 , Y10T428/31794 , Y10T428/31855
Abstract: A laminating resin composition is disclosed which comprises an unsaturated polyester resin, a vinyl ester resin, a polyfunctional acrylate, and up to about 15 percent by weight of a vinyl monomer. Preferably, the vinyl ester resin has a molecular weight ranging from about 450 to 1500.
Abstract translation: 公开了一种层压树脂组合物，其包含不饱和聚酯树脂，乙烯基酯树脂，多官能丙烯酸酯和至多约15重量％的乙烯基单体。 优选地，乙烯基酯树脂的分子量范围为约450至1500。
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Patent Agency Ranking
公开(公告)号：US5115072A
公开(公告)日：1992-05-19
申请号：US578064
申请日：1990-09-05
Applicant: Hildeberto Nava , Robert D. Lake , Robert B. Makepeace
Inventor： Hildeberto Nava , Robert D. Lake , Robert B. Makepeace
CPC classification number: C08G18/797 , C08F290/067 , C08G18/025 , C08G18/10 , C08G18/2805 , C08G18/671 , C08G18/6745
Abstract: Saturated and ethylenically unsaturated compounds containing carboxylic, amino or alcohol groups are reacted under mild conditions and in short process times with polycarbodiimides containing free isocyanate units to provide polymers with excellent properties. The unsaturated groups bonded to the polymers are particularly important because these groups provide reactive centers that can be crosslinked, either thermally or in the presence of catalysts that initiate polymerization or by radiation. The polymers can also be crosslinked either alone or by copolymerization with various unsaturated monomers. The resulting crosslinked or cured resins provide excellent properties such as hardness, high elongation, excellent toughness, high heat distortion temperatures and good corrosion resistance.
Abstract translation: 含有羧酸，氨基或醇基的饱和和烯键式不饱和化合物在温和条件下和短时间内与含有游离异氰酸酯单元的聚碳二亚胺反应以提供具有优异性能的聚合物。 结合到聚合物上的不饱和基团是特别重要的，因为这些基团提供反应中心，其可以热或在催化剂存在下引发聚合或通过辐射交联。 聚合物也可以单独交联或通过与各种不饱和单体的共聚合。 所得到的交联或固化树脂具有优异的性能，例如硬度，高伸长率，优异的韧性，高热变形温度和良好的耐腐蚀性。
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公开(公告)号：US20080154002A1
公开(公告)日：2008-06-26
申请号：US11644094
申请日：2006-12-22
Applicant: Hildeberto Nava , Lianzhou Chen
Inventor： Hildeberto Nava , Lianzhou Chen
IPC: C08F2/00
CPC classification number: C08G63/48 , C08K5/32 , C08K5/3435 , C08L67/08
Abstract: Unsaturated polyester compositions are disclosed that are obtainable by reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers and reinforcements.Also disclosed are methods for the preparation of the polyesters and the use of the polyesters in closed and open mold compositions such as sheet molding compounding (SMC), bulk molding compounding (BMC), resin transfer molding (RTM), pultrusion, infusion, filament winding, and spray up.
Abstract translation: 公开了不饱和聚酯组合物，其可通过以下方式获得：（i）植物和动物油甘油三酸酯，饱和或不饱和脂肪酸的烷基酯或其混合物; （ii）双官能或多官能二醇或其混合物; （iii）双官能或多官能酸，它们的酸酐或烷基酯及其混合物; （iv）应变环烯; （v）作为能够在高温下引发聚合并在室温下稳定的化合物起作用的组分; 和（vi）低调添加剂，填料和增强剂。 还公开了制备聚酯的方法和聚酯在封闭和开放模具组合物中的用途，例如片状模塑复合（SMC），散装模塑复合（BMC），树脂传递模塑（RTM），拉挤成型，输注，长丝 缠绕，喷雾。
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公开(公告)号：US20060173142A1
公开(公告)日：2006-08-03
申请号：US11048173
申请日：2005-02-01
Applicant: Hildeberto Nava , Aaron Small
Inventor： Hildeberto Nava , Aaron Small
CPC classification number: C08F8/30 , C08F222/1006 , C08F257/02 , C08F265/04 , C08F290/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/02 , C08L51/003 , C08L53/00 , C08L2666/02
Abstract: The present invention provides a crosslinkable polymer system that can be crosslinked to form a wide variety of polymeric, copolymeric and oligomeric compounds. The crosslinkable system comprises a product Q formed from an aromatic ethylenically unsaturated moiety and a first reactive ethylenically unsaturated moiety, and a second reactive ethylenically unsaturated moiety at least partially reacted with the first reactive ethylenically unsaturated moiety, and a first terminal moiety comprising a covalently bonded nitroxide containing group.
Abstract translation: 本发明提供可交联以形成多种聚合物，共聚物和低聚物的交联性聚合物体系。 可交联体系包含由芳族烯属不饱和部分和第一反应性烯键式不饱和部分形成的产物Q和至少部分与第一反应性烯键式不饱和部分反应的第二反应性烯键式不饱和部分，和包含共价键合的第一末端部分 含氮氧基的基团。
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公开(公告)号：US5925409A
公开(公告)日：1999-07-20
申请号：US919090
申请日：1997-08-27
Applicant: Hildeberto Nava
Inventor： Hildeberto Nava
IPC: B29C35/02 , B29C63/34 , C08G18/09 , C08G18/68 , C08G18/79 , C09D201/02 , F16L55/162 , B05D3/02
CPC classification number: F16L55/162 , B29C63/34 , C08G18/095 , C08G18/68 , C08G18/683 , C08G18/797 , C09D201/02 , B29C35/02
Abstract: A method of lining a surface of a substrate comprises providing a reactive mixture which comprises (1) a resin containing active hydrogens; (2) a polycarbodiimide; and (3) an organic diluent; reacting the resin containing active hydrogens and the polycarbodiimide to chemically bind the resin and the polycarbodiimide; applying the chemically bound resin and polycarbodiimide to the surface of the substrate; and curing the chemically bound resin and polycarbodiimide in the presence of an initiator to form a cured resin material which lines the surface of the substrate.
Abstract translation: 衬底表面的方法包括提供反应性混合物，其包括（1）含有活性氢的树脂; （2）聚碳化二亚胺; 和（3）有机稀释剂; 使含有活性氢的树脂与聚碳化二亚胺反应，使树脂和聚碳化二亚胺化学结合; 将化学结合的树脂和聚碳化二亚胺施加到基材的表面; 并在引发剂的存在下固化化学结合的树脂和聚碳化二亚胺，以形成对基材表面进行排列的固化树脂材料。
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公开(公告)号：US5679871A
公开(公告)日：1997-10-21
申请号：US718978
申请日：1996-09-26
Applicant: Hildeberto Nava
Inventor： Hildeberto Nava
IPC: B01J31/02 , C07B61/00 , C07C41/16 , C07C43/23 , C07C319/12 , C07C319/14 , C07C319/20 , C07C323/12 , C07C323/20 , C07C43/16 , C07C319/02
CPC classification number: C07C319/14 , C07C41/16
Abstract: A process for the production of hydroxyalkylated phenolic or hydroxyalkylated thiophenolic compounds is disclosed. The process comprises providing a phenolic or thiophenolic compound, a cyclic organic carbonate compound, and a catalyst selected from the group consisting of an alkali metal, an alcohol-derived salt of the alkali metal, and mixtures thereof; and reacting the phenolic compound and the cyclic organic carbonate compound in the presence of the catalyst to form the hydroxyalkylated phenolic or hydroxyalkylated thiophenolic compound. Preferably, the alkali metal is selected from sodium, potassium, or lithium.
Abstract translation: 公开了一种制备羟烷基化酚或羟烷基化硫代苯酚化合物的方法。 该方法包括提供酚类或硫代苯酚化合物，环状有机碳酸酯化合物和选自碱金属，碱金属的醇衍生的盐及其混合物的催化剂; 并在催化剂存在下使酚类化合物与环状有机碳酸酯化合物反应，形成羟烷基化酚醛或羟烷基化硫代酚化合物。 优选地，碱金属选自钠，钾或锂。
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