公开(公告)号：US20120309883A1

公开(公告)日：2012-12-06

申请号：US13586064

申请日：2012-08-15

申请人： Hiroaki INOUE ,  Shuichiro Sugimoto

发明人： Hiroaki INOUE ,  Shuichiro Sugimoto

IPC分类号： C09D133/10 ,  C08K5/06

CPC分类号： C08F220/22 ,  C09D133/16 ,  C08F2220/1891 ,  C08F214/08 ,  C08F220/24 ,  C08F222/14 ,  C08F220/20 ,  C08F222/385

摘要： The present invention provides a release agent composition which can impart moderate adhesion and releasability to the surface of articles such as protective materials for adhesive face of repositional notes, pressure-sensitive adhesive sheets and tapes, release films and release paper, and which has a low environmental burden, and its production process.The release agent composition of the present invention is characterized by comprising a fluorocopolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group and structural units based on a (meth)acrylate (b) having a C18-30 alkyl group, and a medium.

摘要翻译： 本发明提供一种剥离剂组合物，其能够对制品的表面赋予适度的粘合性和脱模性，例如用于复位粘合剂的表面的保护材料，压敏粘合片和带，脱模膜和剥离纸，并且具有低的 环境负担及其生产过程。 本发明的脱模剂组合物的特征在于含有具有基于具有C1-6多氟烷基的单体（a）的结构单元的含氟共聚物和基于具有C18-30烷基的（甲基）丙烯酸酯（b）的结构单元， 组和媒介。

公开(公告)号：US08962751B2

公开(公告)日：2015-02-24

申请号：US13586064

申请日：2012-08-15

申请人： Hiroaki Inoue ,  Shuichiro Sugimoto

发明人： Hiroaki Inoue ,  Shuichiro Sugimoto

IPC分类号： C08F2/32

CPC分类号： C08F220/22 ,  C09D133/16 ,  C08F2220/1891 ,  C08F214/08 ,  C08F220/24 ,  C08F222/14 ,  C08F220/20 ,  C08F222/385

摘要： A release agent composition, which includes a fluorocopolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group and structural units based on monomer (b) having a C18-30 alkyl group, and a medium, where the mass ratio of the structural units based on the monomer (a) to the structural units based on the monomer (b) (the structural units based on the monomer (a)/the structural units based on the monomer (b)) is from 1/1 to 1/10.

摘要翻译： 一种脱模剂组合物，其包含具有基于具有C1-6多氟烷基的单体（a）的结构单元的含氟共聚物和基于具有C18-30烷基的单体（b）的结构单元和介质，其中质量 基于单体（a）的结构单元与基于单体（b）的结构单元（基于单体（a）的结构单元/基于单体（b）的结构单元）的比率为1 / 1到1/10。

公开(公告)号：US08557939B2

公开(公告)日：2013-10-15

申请号：US12622949

申请日：2009-11-20

申请人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

发明人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

IPC分类号： C08F18/20

CPC分类号： D06M15/277 ,  C08F220/24 ,  C08F220/28 ,  D06M2200/11 ,  D06M2200/12

摘要： To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing. An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass % of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass % of polymerized units (b1) having —(C2H4O)— and from 3 to 34 mass % of polymerized units (b2) having —(C4H8O)—, wherein the content of —(C2H4O)— is from 20 to 65 mass %, and the content of —(C4H8O)— is from 2 to 13 mass %.

摘要翻译： 提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其防污性和拒水拒油性优异，耐洗涤性好。 包含含氟共聚物的防污组合物，其含有30〜65质量％的具有C1-6全氟烷基的聚合单元（a），1〜67质量％的具有 - （C 2 H 4 O）的聚合单元（b1） 34质量％的具有 - （C 4 H 8 O） - 的聚合单元（b2），其中 - （C 2 H 4 O）的含量为20〜65质量％， - （C 4 H 8 O）的含量为2〜13质量％。

公开(公告)号：US20120259045A1

公开(公告)日：2012-10-11

申请号：US13530395

申请日：2012-06-22

申请人： Takao HIRONO ,  Yuuichi Oomori ,  Minako Shimada ,  Shuichiro Sugimoto

发明人： Takao HIRONO ,  Yuuichi Oomori ,  Minako Shimada ,  Shuichiro Sugimoto

IPC分类号： C08L33/10 ,  C08J3/205 ,  C08K13/02 ,  B82Y30/00

CPC分类号： D06M15/248 ,  D06M15/256 ,  D06M15/263 ,  D06M15/277 ,  D06M15/33 ,  D06M15/3335 ,  D06M15/353 ,  D06M2200/10 ,  D06M2200/11 ,  D06M2200/12 ,  D21H17/11 ,  D21H17/37 ,  D21H21/16 ,  D21H21/24

摘要： To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency to the surface of an article, has high stability of the particles of the copolymer, and presents a low environmental impact, a method for its production, and a method for treating an article. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group, structural units based on a (meth)acrylate (b) having a C20-30 alkyl group and structural units based on a halogenated olefin (c), a surfactant (B), and a medium (C), wherein the medium (C) comprises water and a propylene glycol type solvent, and the amount of the propylene glycol type solvent is from 35 to 80 parts by mass per 100 parts by mass of the copolymer (A).

摘要翻译： 为了提供能够赋予制品表面足够的动态拒水性的斥水斥油剂组合物，共聚物颗粒的稳定性高，环境影响小，其制造方法和方法 用于处理物品。 一种斥水斥油剂组合物，其含有具有基于具有C 1-6多氟烷基的单体（a）的结构单元的共聚物（A），基于具有C20-30烷基的（甲基）丙烯酸酯（b）的结构单元和 基于卤代烯烃（c），表面活性剂（B）和介质（C）的结构单元，其中介质（C）包含水和丙二醇型溶剂，丙二醇型溶剂的量来自 相对于共聚物（A）100质量份，为35〜80质量份。

公开(公告)号：US08193276B2

公开(公告)日：2012-06-05

申请号：US12695246

申请日：2010-01-28

申请人： Shuichiro Sugimoto ,  Takao Hirono ,  Eiji Morimoto

发明人： Shuichiro Sugimoto ,  Takao Hirono ,  Eiji Morimoto

IPC分类号： C08L27/12

CPC分类号： C09D133/16 ,  C08F214/18 ,  C08F220/06 ,  C08F220/10 ,  C08F220/16 ,  C08F220/24 ,  C08F222/02 ,  C08J3/07 ,  C08J2333/16

摘要： A fluorocopolymer capable of exhibiting excellent water and oil resistance even with its perfluoroalkyl group being a short chain, and a water and oil proofing composition containing it, are provided.A water and oil proofing composition containing a fluorocopolymer (A) comprising from 40 to 98 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 1 to 50 mass % of polymerized units (b′) having an alkylene oxide and from 1 to 10 mass % of polymerized units (c′) based on a monomer represented by CH2═C(COOH)-Q-COOH (wherein Q is a C1-4 alkylene group, etc.).

摘要翻译： 提供即使其全氟烷基为短链也能表现出优异的耐水和耐油性的含氟共聚物，以及含有它的防油防油组合物。 一种含有含氟共聚物（A）的防油防油组合物，其含有40〜98质量％的具有C1-6全氟烷基的聚合单元（a'），1〜50质量％的具有亚烷基的聚合单元（b'） 氧化物和1〜10质量％的基于由CH 2 = C（COOH）-Q-COOH（其中Q为C1-4亚烷基等）表示的单体的聚合单元（c'）。

公开(公告)号：US20100076168A1

公开(公告)日：2010-03-25

申请号：US12626739

申请日：2009-11-27

申请人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

发明人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

IPC分类号： C08F220/22

CPC分类号： D06M15/263 ,  C09D5/1637 ,  C09D133/16 ,  C09K3/22 ,  D06M15/267 ,  D06M15/27 ,  D06M15/273 ,  D06M15/277 ,  D06M15/285 ,  D06M16/00 ,  D06M2200/11 ,  D06M2200/12

摘要： To provide an antifouling composition which is an fluorine-type antifouling composition using a short chain perfluoroalkyl group and which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has excellent soil release properties.An antifouling composition comprising a fluorocopolymer which comprises from 30 to 70 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 20 to 69 mass % of polymerized units (b′) having an alkylene oxide chain and from 1 to 10 mass % of polymerized units (c′) having an amino group, and which has anionic groups at its main chain terminals.

摘要翻译： 提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其可以基本上不含挥发性有机溶剂的水性分散体的形式制成，并且具有优异的防污性能。 含有含氟共聚物的防污组合物，其含有30〜70质量％的具有C1-6全氟烷基的聚合单元（a'），20〜69质量％的具有环氧烷烃链的聚合单元（b'）和1 至10质量％的具有氨基的聚合单元（c'），并且在其主链末端具有阴离子基团。

公开(公告)号：US08609795B2

公开(公告)日：2013-12-17

申请号：US11940577

申请日：2007-11-15

申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

IPC分类号： C08F118/00

CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。 作为必要成分的防水斥油剂组合物，其含有含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：含有Rf基的单体，其形成 不含熔点或熔点至多55℃的光聚合物，归因于衍生自Rf基团的微晶，玻璃化转变点至少为20℃。单体（b）：不具有Rf基团的单体 并具有可交联的官能团。

公开(公告)号：US20100069565A1

公开(公告)日：2010-03-18

申请号：US12622949

申请日：2009-11-20

申请人： Hiroyuki HARA ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

发明人： Hiroyuki HARA ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

IPC分类号： C08L27/12 ,  C08F220/22

CPC分类号： D06M15/277 ,  C08F220/24 ,  C08F220/28 ,  D06M2200/11 ,  D06M2200/12

摘要： To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing.An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass % of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass % of polymerized units (b1) having —(C2H4O)— and from 3 to 34 mass % of polymerized units (b2) having —(C4H8O)—, wherein the content of —(C2H4O)— is from 20 to 65 mass %, and the content of —(C4H8O)— is from 2 to 13 mass %.

摘要翻译： 提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其防污性和拒水拒油性优异，耐洗涤性好。 包含含氟共聚物的防污组合物，其含有30〜65质量％的具有C1-6全氟烷基的聚合单元（a），1〜67质量％的具有 - （C 2 H 4 O）的聚合单元（b1） 34质量％的具有 - （C 4 H 8 O） - 的聚合单元（b2），其中 - （C 2 H 4 O）的含量为20〜65质量％， - （C 4 H 8 O）的含量为2〜13质量％。

公开(公告)号：US08598291B2

公开(公告)日：2013-12-03

申请号：US12626739

申请日：2009-11-27

申请人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

发明人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

IPC分类号： C08F18/20

CPC分类号： D06M15/263 ,  C09D5/1637 ,  C09D133/16 ,  C09K3/22 ,  D06M15/267 ,  D06M15/27 ,  D06M15/273 ,  D06M15/277 ,  D06M15/285 ,  D06M16/00 ,  D06M2200/11 ,  D06M2200/12

摘要： Antifouling composition containing a fluorocopolymer which contains from 30 to 70 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 20 to 69 mass % of polymerized units (b′) having an alkylene oxide chain and from 1 to 10 mass % of polymerized units (c′) having an amino group, and which has anionic groups at its main chain terminals. Method of making.

摘要翻译： 含有含有30〜70质量％的具有C1-6全氟烷基的聚合单元（a'），20〜69质量％的具有烯化氧链的聚合单元（b'）和含有1〜 10质量％的具有氨基的聚合单元（c'），并且在其主链末端具有阴离子基团。 制作方法

公开(公告)号：US20080076862A1

公开(公告)日：2008-03-27

申请号：US11940577

申请日：2007-11-15

申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

IPC分类号： C08F18/20

CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水和防油处理。 作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为 至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。