公开(公告)号：US20120225300A1

公开(公告)日：2012-09-06

申请号：US13470636

申请日：2012-05-14

申请人： Junsuke KAWANA ,  Shuichiro Sugimoto

发明人： Junsuke KAWANA ,  Shuichiro Sugimoto

IPC分类号： C09D133/14 ,  B32B27/10

CPC分类号： D21H19/20 ,  C08F220/20 ,  C08F220/24 ,  C08F220/36 ,  C08F222/1006 ,  C09K3/18 ,  D21H17/34 ,  D21H21/16 ,  Y10T428/3154

摘要： To provide a water/oil resistant composition which can impart a sufficient water/oil resistance to a base material even though a fluorinated copolymer having an Rf group with at most 6 carbon atoms is used, said water/oil resistance being not substantially influenced by an adjuvant or the pH of dilution water, and which has little odor; an article treated therewith; and processes for their production. A water/oil resistant composition having a fluorinated copolymer dispersed or dissolved in a medium, wherein the fluorinated copolymer is one having one, some or all of amino groups in a fluorinated copolymer comprising structural units based on a monomer (a) having a C1-6 Rf group and structural units based on a monomer (b) having an amino group, converted to form a salt with an organic acid comprising an organic acid having a pKa of from 2.0 to 4.0.

摘要翻译： 即使使用具有至多6个碳原子的Rf基的氟化共聚物，也可以使基础材料赋予充分的耐水/油性的耐油/油性组合物，所以耐水/耐油性基本上不受 佐剂或稀释水的pH值，且气味少; 处理的物品; 和生产过程。 一种具有分散或溶解在介质中的含氟共聚物的防水/耐油组合物，其中所述含氟共聚物是含氟共聚物中具有一个，部分或全部氨基的共聚物，其包含基于具有C1- 6 Rf基团和基于具有氨基的单体（b）的结构单元，转化为与包含pKa为2.0至4.0的有机酸的有机酸形成盐。

公开(公告)号：US20110039975A1

公开(公告)日：2011-02-17

申请号：US12913900

申请日：2010-10-28

申请人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono

发明人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono

IPC分类号： C09D5/16

CPC分类号： D06M15/277 ,  C08F214/06 ,  C08F220/22 ,  C08F220/58 ,  C08F222/14 ,  C08F2220/1891

摘要： To provide a process for efficiently producing a fluorine type antifouling composition employing a short chain Rf group, which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has a good soil release property (SR property).A process for producing an antifouling composition, which comprises a step of subjecting monomer components (Z) comprising from 30 to 80 mass % of a monomer (a) having a polyfluoroalkyl group in which the number of carbon atoms to which fluorine atoms are bonded is from 4 to 6, and from 20 to 70 mass % of a monomer (b) having no polyfluoroalkyl group and having a hydrophilic group, to solution polymerization in a volatile organic solvent having a boiling point of at most 100° C. in the presence of a surfactant (c) comprising an ethylene oxide adduct of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to form a fluorocopolymer (A), and a step of volatilizing the volatile organic solvent after the solution polymerization and adding an aqueous medium to form an aqueous dispersion.

摘要翻译： 为了提供一种能够有效地制造使用短链Rf基的氟型防污组合物的方法，其可以基本上不含挥发性有机溶剂的水性分散体的形式制备并且具有良好的去污性能（SR性能）。 一种防污组合物的制造方法，其特征在于，包括含有30〜80质量％的具有与氟原子键合的碳原子数的多氟烷基的单体（a）的单体成分（Z）的工序是 4〜6质量％，20〜70质量％的不具有多氟烷基且具有亲水性基团的单体（b）在沸点为100℃以下的挥发性有机溶剂中进行溶液聚合， 包含2,4,7,9-四甲基-5-癸炔-4,7-二醇的环氧乙烷加合物以形成含氟共聚物（A）的表面活性剂（c），以及在溶液之后使挥发性有机溶剂挥发的步骤 聚合并加入水性介质以形成水分散体。

公开(公告)号：US20100168319A1

公开(公告)日：2010-07-01

申请号：US12695246

申请日：2010-01-28

申请人： Shuichiro Sugimoto ,  Takao Hirono ,  Eiji Morimoto

发明人： Shuichiro Sugimoto ,  Takao Hirono ,  Eiji Morimoto

IPC分类号： C08L27/12 ,  C08F118/00

CPC分类号： C09D133/16 ,  C08F214/18 ,  C08F220/06 ,  C08F220/10 ,  C08F220/16 ,  C08F220/24 ,  C08F222/02 ,  C08J3/07 ,  C08J2333/16

摘要： A fluorocopolymer capable of exhibiting excellent water and oil resistance even with its perfluoroalkyl group being a short chain, and a water and oil proofing composition containing it, are provided.A water and oil proofing composition containing a fluorocopolymer (A) comprising from 40 to 98 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 1 to 50 mass % of polymerized units (b′) having an alkylene oxide and from 1 to 10 mass % of polymerized units (c′) based on a monomer represented by CH2═C(COOH)-Q-COOH (wherein Q is a C1-4 alkylene group, etc.).

摘要翻译： 提供即使其全氟烷基为短链也能表现出优异的耐水和耐油性的含氟共聚物，以及含有它的防油防油组合物。 一种含有含氟共聚物（A）的防油防油组合物，其含有40〜98质量％的具有C1-6全氟烷基的聚合单元（a'），1〜50质量％的具有亚烷基的聚合单元（b'） 氧化物和1〜10质量％的基于由CH 2 = C（COOH）-Q-COOH（其中Q为C1-4亚烷基等）表示的单体的聚合单元（c'）。

公开(公告)号：US07485688B2

公开(公告)日：2009-02-03

申请号：US11524918

申请日：2006-09-22

申请人： Takashige Maekawa ,  Shuichiro Sugimoto ,  Minako Shimada ,  Kyouichi Kaneko ,  Harutaka Naruse ,  Yuuichi Nakajima

发明人： Takashige Maekawa ,  Shuichiro Sugimoto ,  Minako Shimada ,  Kyouichi Kaneko ,  Harutaka Naruse ,  Yuuichi Nakajima

IPC分类号： C08F118/00

CPC分类号： D06M15/263 ,  C08F214/18 ,  C08L27/00 ,  C08L35/00 ,  C09D133/00 ,  D06M15/267 ,  D06M15/27 ,  D06M15/277 ,  D06M15/333 ,  D06M15/3568 ,  D06M2200/11 ,  D06M2200/12 ,  D21H19/20 ,  D21H21/16 ,  C08L2666/06

摘要： The present invention provides a water and oil proofing composition which imparts excellent water and oil resistance and comprises a fluorocopolymer comprising polymerized units of (Z-Y)nX (wherein Z: a C1-6 perfluoroalkyl group or the like, Y: an alkylene group or the like, n: 1 or 2, X: a polymerizable unsaturated group), polymerized units of CH2═CR1-G-(R2O)q—R3 (wherein R1: a hydrogen atom or the like, R2: a C2-4 alkylene group or the like, q: an integer of from 1 to 50, G: —COO(CH2)r— (r: an integer of from 0 to 4), R3: a hydrogen atom or the like, and polymerized units of CH2═CR4-M-Q-NR5R6 (wherein R4: a hydrogen atom or the like, Q: a C2-4 alkylene group or the like, R5 and R6: C1-8 alkyl groups or the like) and an aqueous medium.

摘要翻译： 本发明提供一种具有优异耐水耐油性的防油防油组合物，其含有含有（ZY）nX（其中Z：C1-6全氟烷基等）的聚合单元的含氟共聚物，Y：亚烷基或 类似于n：1或2，X：可聚合不饱和基团），CH2-CR1-G-（R2O）q-R3的聚合单元（其中R1：氢原子等，R2：C2-4亚烷基 q：1〜50的整数，G：-COO（CH 2）r - （r：0〜4的整数），R 3：氢原子等， CR4-MQ-NR5R6（其中R4：氢原子等，Q：C2-4亚烷基等，R5和R6：C1-8烷基等）和水性介质。

公开(公告)号：US06716944B2

公开(公告)日：2004-04-06

申请号：US10317991

申请日：2002-12-13

申请人： Takashige Maekawa ,  Minako Shimada ,  Shuichiro Sugimoto ,  Ryuji Seki

发明人： Takashige Maekawa ,  Minako Shimada ,  Shuichiro Sugimoto ,  Ryuji Seki

IPC分类号： C08F11800

CPC分类号： C09K3/18

摘要： A water and oil repellent composition which can impart an excellent water and oil repellency to an object, even if it is processed at a low temperature, and which can achieve a water and oil repellent treatment providing a soft hand. The water and oil repellent composition which has as an essential component a copolymer consisting essentially of polymerized units of the following monomer (a) and polymerized units of the following monomer (b). monomer (a): an Rf monomer wherein the melting point of fine crystals derived from the Rf groups of the homopolymer does not exist or is at most 50° C. monomer (b): a monomer having no Rf group, wherein the melting point of fine crystals derived from the side chains of the homopolymer is at least 30° C.

摘要翻译： 即使在低温下进行处理也能够使物品具有优异的拒水拒油性的斥水斥油剂组合物，能够实现提供软手的拒水拒油处理。 具有以下单体（a）的聚合单元和以下单体（b）单体的聚合单元共聚物作为基本组分的斥水斥油剂组合物。单体（a）：R f单体，其中 衍生自均聚物的R f基团的细晶体的熔点不存在或至多为50℃。单体（b）：不具有R f基团的单体，其中衍生的细晶体的熔点 来自均聚物的侧链为至少30℃

公开(公告)号：US08962751B2

公开(公告)日：2015-02-24

申请号：US13586064

申请日：2012-08-15

申请人： Hiroaki Inoue ,  Shuichiro Sugimoto

发明人： Hiroaki Inoue ,  Shuichiro Sugimoto

IPC分类号： C08F2/32

CPC分类号： C08F220/22 ,  C09D133/16 ,  C08F2220/1891 ,  C08F214/08 ,  C08F220/24 ,  C08F222/14 ,  C08F220/20 ,  C08F222/385

摘要： A release agent composition, which includes a fluorocopolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group and structural units based on monomer (b) having a C18-30 alkyl group, and a medium, where the mass ratio of the structural units based on the monomer (a) to the structural units based on the monomer (b) (the structural units based on the monomer (a)/the structural units based on the monomer (b)) is from 1/1 to 1/10.

摘要翻译： 一种脱模剂组合物，其包含具有基于具有C1-6多氟烷基的单体（a）的结构单元的含氟共聚物和基于具有C18-30烷基的单体（b）的结构单元和介质，其中质量 基于单体（a）的结构单元与基于单体（b）的结构单元（基于单体（a）的结构单元/基于单体（b）的结构单元）的比率为1 / 1到1/10。

公开(公告)号：US08598291B2

公开(公告)日：2013-12-03

申请号：US12626739

申请日：2009-11-27

申请人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

发明人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

IPC分类号： C08F18/20

CPC分类号： D06M15/263 ,  C09D5/1637 ,  C09D133/16 ,  C09K3/22 ,  D06M15/267 ,  D06M15/27 ,  D06M15/273 ,  D06M15/277 ,  D06M15/285 ,  D06M16/00 ,  D06M2200/11 ,  D06M2200/12

摘要： Antifouling composition containing a fluorocopolymer which contains from 30 to 70 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 20 to 69 mass % of polymerized units (b′) having an alkylene oxide chain and from 1 to 10 mass % of polymerized units (c′) having an amino group, and which has anionic groups at its main chain terminals. Method of making.

摘要翻译： 含有含有30〜70质量％的具有C1-6全氟烷基的聚合单元（a'），20〜69质量％的具有烯化氧链的聚合单元（b'）和含有1〜 10质量％的具有氨基的聚合单元（c'），并且在其主链末端具有阴离子基团。 制作方法

公开(公告)号：US20080076862A1

公开(公告)日：2008-03-27

申请号：US11940577

申请日：2007-11-15

申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

IPC分类号： C08F18/20

CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水和防油处理。 作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为 至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。

公开(公告)号：US06933338B2

公开(公告)日：2005-08-23

申请号：US10692691

申请日：2003-10-27

申请人： Shuichiro Sugimoto ,  Takashige Maekawa

发明人： Shuichiro Sugimoto ,  Takashige Maekawa

IPC分类号： C08F220/12 ,  C08F220/22 ,  C08F220/24 ,  C08F220/36 ,  C08K5/00 ,  C08L33/06 ,  C08L33/14 ,  C08L33/16 ,  C09K3/18 ,  D06M15/263 ,  D06M15/277 ,  D06M15/356 ,  D06M15/576 ,  D06M23/10 ,  C08K5/06

CPC分类号： D06M15/3562 ,  C08F220/24 ,  C09K3/18 ,  D06M15/263 ,  D06M15/277 ,  D06M15/576 ,  D06M23/10

摘要： To provide a water- and oil-repellent composition excellent in durability and excellent in safety and preservation of the environment. A water- and oil-repellent composition which comprises (A) a polymer, (B) an aqueous medium and (C) a surfactant in a mass ratio of (A)/(B)/(C)=100/100-500/1-10, the polymer (A) containing a polymerization unit based on a (meth)acrylate having a polyfluoroalkyl group, a polymerization unit based on an alkyl(meth)acrylate having a C1-C12 alkyl group, a polymerization unit based on an alkyl(meth)acrylate having a C16-C22 alkyl group and a polymerization unit based on a specific compound having a blocked isocyanate group.

摘要翻译： 提供耐久性优异且安全性和环境保护性优异的拒水拒油剂组合物。 一种拒水拒油剂组合物，其包含（A）聚合物，（B）水性介质和（C）质量比为（A）/（B）/（C）= 100 / 100-500的表面活性剂 / 1-10，含有基于具有多氟烷基的（甲基）丙烯酸酯的聚合单元的聚合物（A），具有C 1 -C 3烷基的（甲基）丙烯酸烷基酯的聚合单元， 基于具有C 16 -C 22烷基的（甲基）丙烯酸烷基酯的聚合单元和基于聚合单元的聚合单元 具有封端异氰酸酯基的具体化合物。

公开(公告)号：US06177531B1

公开(公告)日：2001-01-23

申请号：US09120880

申请日：1998-07-23

申请人： Toyomichi Shimada ,  Kyoichi Kaneko ,  Shuichiro Sugimoto ,  Takashige Maekawa

发明人： Toyomichi Shimada ,  Kyoichi Kaneko ,  Shuichiro Sugimoto ,  Takashige Maekawa

IPC分类号： C08F1820

CPC分类号： D06M15/277 ,  C03C17/32 ,  C03C25/1095 ,  C08F220/24 ,  C08G18/672 ,  C08G18/8141 ,  D06M15/248 ,  D06M15/263 ,  D06M2101/06 ,  D06M2101/12 ,  D06M2101/22 ,  D06M2101/24 ,  D06M2101/28 ,  D06M2101/32 ,  D06M2101/34 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/31551

摘要： A water and oil repellent composition containing, as an effective component, a copolymer comprising the following polymeric units (a), (b) and at least one member selected from (c) and (d): polymeric units (a): Polymeric units of a (meth)acrylate having a polyfluoroalkyl group; Polymeric units (b): Polymeric units of 2-isocyanate ethyl (meth)acrylate with the isocyanate group blocked; Polymeric units (c): Polymeric units of vinyl chloride; and Polymeric units (d): Polymeric units of an alkyl (meth)acrylate.

摘要翻译： 含有以下聚合单元（a），（b）和至少一种选自（c）和（d）的成分的聚合物单元（a）的共聚物作为有效成分的拒水拒油剂组合物：聚合单元 具有多氟烷基的（甲基）丙烯酸酯;聚合单元（b）：（异氰酸酯基）封端的（甲基）丙烯酸2-异氰酸乙酯的聚合单元;聚合单元（c）：氯乙烯的聚合单元; 和聚合单元（d）：（甲基）丙烯酸烷基酯的聚合单元。