公开(公告)号：US20120259045A1

公开(公告)日：2012-10-11

申请号：US13530395

申请日：2012-06-22

申请人： Takao HIRONO ,  Yuuichi Oomori ,  Minako Shimada ,  Shuichiro Sugimoto

发明人： Takao HIRONO ,  Yuuichi Oomori ,  Minako Shimada ,  Shuichiro Sugimoto

IPC分类号： C08L33/10 ,  C08J3/205 ,  C08K13/02 ,  B82Y30/00

CPC分类号： D06M15/248 ,  D06M15/256 ,  D06M15/263 ,  D06M15/277 ,  D06M15/33 ,  D06M15/3335 ,  D06M15/353 ,  D06M2200/10 ,  D06M2200/11 ,  D06M2200/12 ,  D21H17/11 ,  D21H17/37 ,  D21H21/16 ,  D21H21/24

摘要： To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency to the surface of an article, has high stability of the particles of the copolymer, and presents a low environmental impact, a method for its production, and a method for treating an article. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group, structural units based on a (meth)acrylate (b) having a C20-30 alkyl group and structural units based on a halogenated olefin (c), a surfactant (B), and a medium (C), wherein the medium (C) comprises water and a propylene glycol type solvent, and the amount of the propylene glycol type solvent is from 35 to 80 parts by mass per 100 parts by mass of the copolymer (A).

摘要翻译： 为了提供能够赋予制品表面足够的动态拒水性的斥水斥油剂组合物，共聚物颗粒的稳定性高，环境影响小，其制造方法和方法 用于处理物品。 一种斥水斥油剂组合物，其含有具有基于具有C 1-6多氟烷基的单体（a）的结构单元的共聚物（A），基于具有C20-30烷基的（甲基）丙烯酸酯（b）的结构单元和 基于卤代烯烃（c），表面活性剂（B）和介质（C）的结构单元，其中介质（C）包含水和丙二醇型溶剂，丙二醇型溶剂的量来自 相对于共聚物（A）100质量份，为35〜80质量份。

公开(公告)号：US08609795B2

公开(公告)日：2013-12-17

申请号：US11940577

申请日：2007-11-15

申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

IPC分类号： C08F118/00

CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。 作为必要成分的防水斥油剂组合物，其含有含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：含有Rf基的单体，其形成 不含熔点或熔点至多55℃的光聚合物，归因于衍生自Rf基团的微晶，玻璃化转变点至少为20℃。单体（b）：不具有Rf基团的单体 并具有可交联的官能团。

公开(公告)号：US20080076862A1

公开(公告)日：2008-03-27

申请号：US11940577

申请日：2007-11-15

申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

IPC分类号： C08F18/20

CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水和防油处理。 作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为 至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。

公开(公告)号：US20100069565A1

公开(公告)日：2010-03-18

申请号：US12622949

申请日：2009-11-20

申请人： Hiroyuki HARA ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

发明人： Hiroyuki HARA ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

IPC分类号： C08L27/12 ,  C08F220/22

CPC分类号： D06M15/277 ,  C08F220/24 ,  C08F220/28 ,  D06M2200/11 ,  D06M2200/12

摘要： To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing.An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass % of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass % of polymerized units (b1) having —(C2H4O)— and from 3 to 34 mass % of polymerized units (b2) having —(C4H8O)—, wherein the content of —(C2H4O)— is from 20 to 65 mass %, and the content of —(C4H8O)— is from 2 to 13 mass %.

摘要翻译： 提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其防污性和拒水拒油性优异，耐洗涤性好。 包含含氟共聚物的防污组合物，其含有30〜65质量％的具有C1-6全氟烷基的聚合单元（a），1〜67质量％的具有 - （C 2 H 4 O）的聚合单元（b1） 34质量％的具有 - （C 4 H 8 O） - 的聚合单元（b2），其中 - （C 2 H 4 O）的含量为20〜65质量％， - （C 4 H 8 O）的含量为2〜13质量％。

公开(公告)号：US20070015867A1

公开(公告)日：2007-01-18

申请号：US11524918

申请日：2006-09-22

申请人： Takashige Maekawa ,  Shuichiro Sugimoto ,  Minako Shimada ,  Kyouichi Kaneko ,  Harutaka Naruse ,  Yuuichi Nakajima

发明人： Takashige Maekawa ,  Shuichiro Sugimoto ,  Minako Shimada ,  Kyouichi Kaneko ,  Harutaka Naruse ,  Yuuichi Nakajima

IPC分类号： C08L27/12

CPC分类号： D06M15/263 ,  C08F214/18 ,  C08L27/00 ,  C08L35/00 ,  C09D133/00 ,  D06M15/267 ,  D06M15/27 ,  D06M15/277 ,  D06M15/333 ,  D06M15/3568 ,  D06M2200/11 ,  D06M2200/12 ,  D21H19/20 ,  D21H21/16 ,  C08L2666/06

摘要： The present invention provides a water and oil proofing composition which imparts excellent water and oil resistance. A composition which comprises a fluorocopolymer comprising polymerized units of (Z-Y)nX (wherein Z: a C1-6 perfluoroalkyl group or the like, Y: an alkylene group or the like, n: 1 or 2, X: a polymerizable unsaturated group), polymerized units of CH2═CR1-G-(R2O)q—R3 (wherein R1: a hydrogen atom or the like, R2: a C2-4 alkylene group or the like, q: an integer of from 1 to 50, G: —COO(CH2)r— (r: an integer of from 0 to 4), R3: a hydrogen atom or the like) and polymerized units of CH2═CR4-M-Q-NR5R6 (wherein R4: a hydrogen atom or the like, Q: a C2-4 alkylene group or the like, R5 and R6: C1-8 alkyl groups or the like) and an aqueous medium.

摘要翻译： 本发明提供赋予耐油和耐油性优异的防油防油组合物。 一种组合物，其包含含有（ZY）N X的聚合单元的含氟共聚物（其中Z：C 1-6烷基全氟烷基等，Y：亚烷基或 类似物，n = 1或2，X为可聚合不饱和基团），CH 2 2 -CR 1 -G-（R 2）2的聚合​​单元， 其中R 1是氢原子等，R 2，R 2，R 3，R 3， ：C 2-4亚烷基等，q：1〜50的整数，G：-COO（CH 2）2， （R：0〜4的整数），R 3，氢原子等）和CH 2的基团的聚合单元 4其中R 4为氢原子等，Q为C 1 -C 6烷基， 亚> 2-4个亚烷基等，R 5和R 6：C 1-8烷基或 类似物）和水性介质。

公开(公告)号：US20050267241A1

公开(公告)日：2005-12-01

申请号：US11106641

申请日：2005-04-15

申请人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

发明人： Shuichiro Sugimoto ,  Minako Shimada ,  Toyomichi Shimada ,  Ryuji Seki ,  Takashige Maekawa

IPC分类号： C09K3/18 ,  C08F18/20

CPC分类号： D06M15/256 ,  C08F218/08 ,  C08F220/18 ,  C08F220/22 ,  C08F220/24 ,  C08F220/34 ,  C08F220/36 ,  C08F230/08 ,  C09K3/18 ,  D06M15/263 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/12 ,  D06M2200/50

摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.

摘要翻译： 具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。 作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为 至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。

公开(公告)号：US07485688B2

公开(公告)日：2009-02-03

申请号：US11524918

申请日：2006-09-22

申请人： Takashige Maekawa ,  Shuichiro Sugimoto ,  Minako Shimada ,  Kyouichi Kaneko ,  Harutaka Naruse ,  Yuuichi Nakajima

发明人： Takashige Maekawa ,  Shuichiro Sugimoto ,  Minako Shimada ,  Kyouichi Kaneko ,  Harutaka Naruse ,  Yuuichi Nakajima

IPC分类号： C08F118/00

CPC分类号： D06M15/263 ,  C08F214/18 ,  C08L27/00 ,  C08L35/00 ,  C09D133/00 ,  D06M15/267 ,  D06M15/27 ,  D06M15/277 ,  D06M15/333 ,  D06M15/3568 ,  D06M2200/11 ,  D06M2200/12 ,  D21H19/20 ,  D21H21/16 ,  C08L2666/06

摘要： The present invention provides a water and oil proofing composition which imparts excellent water and oil resistance and comprises a fluorocopolymer comprising polymerized units of (Z-Y)nX (wherein Z: a C1-6 perfluoroalkyl group or the like, Y: an alkylene group or the like, n: 1 or 2, X: a polymerizable unsaturated group), polymerized units of CH2═CR1-G-(R2O)q—R3 (wherein R1: a hydrogen atom or the like, R2: a C2-4 alkylene group or the like, q: an integer of from 1 to 50, G: —COO(CH2)r— (r: an integer of from 0 to 4), R3: a hydrogen atom or the like, and polymerized units of CH2═CR4-M-Q-NR5R6 (wherein R4: a hydrogen atom or the like, Q: a C2-4 alkylene group or the like, R5 and R6: C1-8 alkyl groups or the like) and an aqueous medium.

摘要翻译： 本发明提供一种具有优异耐水耐油性的防油防油组合物，其含有含有（ZY）nX（其中Z：C1-6全氟烷基等）的聚合单元的含氟共聚物，Y：亚烷基或 类似于n：1或2，X：可聚合不饱和基团），CH2-CR1-G-（R2O）q-R3的聚合单元（其中R1：氢原子等，R2：C2-4亚烷基 q：1〜50的整数，G：-COO（CH 2）r - （r：0〜4的整数），R 3：氢原子等， CR4-MQ-NR5R6（其中R4：氢原子等，Q：C2-4亚烷基等，R5和R6：C1-8烷基等）和水性介质。

公开(公告)号：US06716944B2

公开(公告)日：2004-04-06

申请号：US10317991

申请日：2002-12-13

申请人： Takashige Maekawa ,  Minako Shimada ,  Shuichiro Sugimoto ,  Ryuji Seki

发明人： Takashige Maekawa ,  Minako Shimada ,  Shuichiro Sugimoto ,  Ryuji Seki

IPC分类号： C08F11800

CPC分类号： C09K3/18

摘要： A water and oil repellent composition which can impart an excellent water and oil repellency to an object, even if it is processed at a low temperature, and which can achieve a water and oil repellent treatment providing a soft hand. The water and oil repellent composition which has as an essential component a copolymer consisting essentially of polymerized units of the following monomer (a) and polymerized units of the following monomer (b). monomer (a): an Rf monomer wherein the melting point of fine crystals derived from the Rf groups of the homopolymer does not exist or is at most 50° C. monomer (b): a monomer having no Rf group, wherein the melting point of fine crystals derived from the side chains of the homopolymer is at least 30° C.

摘要翻译： 即使在低温下进行处理也能够使物品具有优异的拒水拒油性的斥水斥油剂组合物，能够实现提供软手的拒水拒油处理。 具有以下单体（a）的聚合单元和以下单体（b）单体的聚合单元共聚物作为基本组分的斥水斥油剂组合物。单体（a）：R f单体，其中 衍生自均聚物的R f基团的细晶体的熔点不存在或至多为50℃。单体（b）：不具有R f基团的单体，其中衍生的细晶体的熔点 来自均聚物的侧链为至少30℃

公开(公告)号：US08557939B2

公开(公告)日：2013-10-15

申请号：US12622949

申请日：2009-11-20

申请人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

发明人： Hiroyuki Hara ,  Shuichiro Sugimoto ,  Takao Hirono ,  Takashige Maekawa

IPC分类号： C08F18/20

CPC分类号： D06M15/277 ,  C08F220/24 ,  C08F220/28 ,  D06M2200/11 ,  D06M2200/12

摘要： To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing. An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass % of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass % of polymerized units (b1) having —(C2H4O)— and from 3 to 34 mass % of polymerized units (b2) having —(C4H8O)—, wherein the content of —(C2H4O)— is from 20 to 65 mass %, and the content of —(C4H8O)— is from 2 to 13 mass %.

摘要翻译： 提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其防污性和拒水拒油性优异，耐洗涤性好。 包含含氟共聚物的防污组合物，其含有30〜65质量％的具有C1-6全氟烷基的聚合单元（a），1〜67质量％的具有 - （C 2 H 4 O）的聚合单元（b1） 34质量％的具有 - （C 4 H 8 O） - 的聚合单元（b2），其中 - （C 2 H 4 O）的含量为20〜65质量％， - （C 4 H 8 O）的含量为2〜13质量％。

公开(公告)号：US08193276B2

公开(公告)日：2012-06-05

申请号：US12695246

申请日：2010-01-28

申请人： Shuichiro Sugimoto ,  Takao Hirono ,  Eiji Morimoto

发明人： Shuichiro Sugimoto ,  Takao Hirono ,  Eiji Morimoto

IPC分类号： C08L27/12

CPC分类号： C09D133/16 ,  C08F214/18 ,  C08F220/06 ,  C08F220/10 ,  C08F220/16 ,  C08F220/24 ,  C08F222/02 ,  C08J3/07 ,  C08J2333/16

摘要： A fluorocopolymer capable of exhibiting excellent water and oil resistance even with its perfluoroalkyl group being a short chain, and a water and oil proofing composition containing it, are provided.A water and oil proofing composition containing a fluorocopolymer (A) comprising from 40 to 98 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 1 to 50 mass % of polymerized units (b′) having an alkylene oxide and from 1 to 10 mass % of polymerized units (c′) based on a monomer represented by CH2═C(COOH)-Q-COOH (wherein Q is a C1-4 alkylene group, etc.).

摘要翻译： 提供即使其全氟烷基为短链也能表现出优异的耐水和耐油性的含氟共聚物，以及含有它的防油防油组合物。 一种含有含氟共聚物（A）的防油防油组合物，其含有40〜98质量％的具有C1-6全氟烷基的聚合单元（a'），1〜50质量％的具有亚烷基的聚合单元（b'） 氧化物和1〜10质量％的基于由CH 2 = C（COOH）-Q-COOH（其中Q为C1-4亚烷基等）表示的单体的聚合单元（c'）。