公开(公告)号：US09353310B2

公开(公告)日：2016-05-31

申请号：US12716728

申请日：2010-03-03

申请人： Hiroki Iwanaga ,  Takahiro Sato

发明人： Hiroki Iwanaga ,  Takahiro Sato

IPC分类号： C09K11/06 ,  H01J1/62 ,  H01J63/04 ,  H05B33/14

CPC分类号： C09K11/06 ,  C09K2211/1096 ,  C09K2211/182 ,  H05B33/14

摘要： An amorphous luminous material, which is substantially composed of only rare earth complex compounds, wherein the compounds are two or more kinds of rare earth complexes, and rare earth metal ions, which are center ions of the two or more kinds of rare earth complexes, are different ions.

摘要翻译： 一种无机发光材料，其基本上仅由稀土配合物组成，其中化合物为两种或多种稀土配合物，稀土金属离子为两种或多种稀土络合物的中心离子， 是不同的离子。

公开(公告)号：US20090050851A1

公开(公告)日：2009-02-26

申请号：US12178199

申请日：2008-07-23

申请人： Takahiro Sato ,  Hiroki Iwanaga ,  Akio Amano ,  Shinji Murai

发明人： Takahiro Sato ,  Hiroki Iwanaga ,  Akio Amano ,  Shinji Murai

IPC分类号： C09K11/02

CPC分类号： C09K11/06 ,  C09K2211/1491 ,  H05B33/14

摘要： The present invention provides a fluorescent substance excellent in emission intensity and in emission efficiency. The substance can be excited by light at a longer wavelength than ever. The present invention also provides a luminous composition comprising the fluorescent substance and a light-emitting element using the substance. The fluorescent substance comprises a rare earth metal and a phosphine oxide ligand which coordinates to said rare earth metal and said ligand containing at least one siloxane bond in its structure. The fluorescent substance can be produced from a reaction between a compound having a siloxane bond and a rare earth complex coordinated by a phosphine oxide ligand. The luminous composition comprises the fluorescent substance.

摘要翻译： 本发明提供发光强度和发光效率优异的荧光物质。 该物质可以用比以前更长波长的光激发。 本发明还提供了包含荧光物质和使用该物质的发光元件的发光组合物。 荧光物质包括稀土金属和氧化膦配体，其与所述稀土金属和所述配体在其结构中含有至少一个硅氧烷键配位。 荧光物质可以由具有硅氧烷键的化合物与通过氧化膦配体配位的稀土络合物之间的反应产生。 发光组合物包含荧光物质。

公开(公告)号：US20080303426A1

公开(公告)日：2008-12-11

申请号：US12124786

申请日：2008-05-21

申请人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

发明人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

IPC分类号： H01L51/52 ,  C07F19/00

CPC分类号： C07F9/5345 ,  H01L51/004 ,  H01L51/0071 ,  H01L51/0089 ,  H01L51/5012 ,  Y10S428/917

摘要： The present invention provides a fluorescent rare earth complex having high solubility to a medium, showing fluorescence of high intensity and possessing excellent durability, and also provides a light-emitting element using that complex. The rare earth complex comprises a rare earth ion and a phosphine oxide ligand, and the phosphine oxide ligand contains a phosphorus atom connecting to at least one phenyl group. In the phenyl group, at least one of the meta-positions is substituted. It is also necessary that the para-position of the phenyl group be not substituted.

摘要翻译： 本发明提供了一种对介质具有高溶解性的荧光稀土配合物，显示出高强度的荧光并且具有优异的耐久性，并且还提供了使用该复合物的发光元件。 稀土配合物包含稀土离子和氧化膦配体，氧化膦配体含有连接至少一个苯基的磷原子。 在苯基中，至少一个间位被取代。 苯基的对位也不是取代的。

公开(公告)号：US08080173B2

公开(公告)日：2011-12-20

申请号：US12178199

申请日：2008-07-23

申请人： Takahiro Sato ,  Hiroki Iwanaga ,  Akio Amano ,  Shinji Murai

发明人： Takahiro Sato ,  Hiroki Iwanaga ,  Akio Amano ,  Shinji Murai

IPC分类号： C09K11/06

CPC分类号： C09K11/06 ,  C09K2211/1491 ,  H05B33/14

摘要： The present invention provides a fluorescent substance excellent in emission intensity and in emission efficiency. The substance can be excited by light at a longer wavelength than ever. The present invention also provides a luminous composition comprising the fluorescent substance and a light-emitting element using the substance. The fluorescent substance comprises a rare earth metal and a phosphine oxide ligand which coordinates to said rare earth metal and said ligand containing at least one siloxane bond in its structure. The fluorescent substance can be produced from a reaction between a compound having a siloxane bond and a rare earth complex coordinated by a phosphine oxide ligand. The luminous composition comprises the fluorescent substance.

摘要翻译： 本发明提供发光强度和发光效率优异的荧光物质。 该物质可以用比以前更长波长的光激发。 本发明还提供了包含荧光物质和使用该物质的发光元件的发光组合物。 荧光物质包括稀土金属和氧化膦配体，其与所述稀土金属和所述配体在其结构中含有至少一个硅氧烷键配位。 荧光物质可以由具有硅氧烷键的化合物与通过氧化膦配体配位的稀土络合物之间的反应产生。 发光组合物包含荧光物质。

公开(公告)号：US08173271B2

公开(公告)日：2012-05-08

申请号：US12124786

申请日：2008-05-21

申请人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

发明人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

IPC分类号： C09K11/06 ,  H01L51/54

CPC分类号： C07F9/5345 ,  H01L51/004 ,  H01L51/0071 ,  H01L51/0089 ,  H01L51/5012 ,  Y10S428/917

摘要： The present invention provides a fluorescent rare earth complex having high solubility to a medium, showing fluorescence of high intensity and possessing excellent durability, and also provides a light-emitting element using that complex. The rare earth complex comprises a rare earth ion and a phosphine oxide ligand, and the phosphine oxide ligand contains a phosphorus atom connecting to at least one phenyl group. In the phenyl group, at least one of the meta-positions is substituted. It is also necessary that the para-position of the phenyl group be not substituted.

摘要翻译： 本发明提供了一种对介质具有高溶解性的荧光稀土配合物，显示出高强度的荧光并且具有优异的耐久性，并且还提供了使用该复合物的发光元件。 稀土配合物包含稀土离子和氧化膦配体，氧化膦配体含有连接至少一个苯基的磷原子。 在苯基中，至少一个间位被取代。 苯基的对位也不是取代的。

公开(公告)号：US07575253B2

公开(公告)日：2009-08-18

申请号：US11221736

申请日：2005-09-09

申请人： Hiroki Iwanaga

发明人： Hiroki Iwanaga

IPC分类号： B42D15/00 ,  C09D11/00

CPC分类号： B41M3/144 ,  B44F1/10 ,  C09B57/10 ,  C09D11/50 ,  Y10S428/913 ,  Y10S428/916 ,  Y10T428/24802

摘要： A fluorescent image-printed article including a substrate, and an image formed on the substrate, wherein the image is formed from a fluorescent ink containing a binder, and a fluorescent substance which is dispersed in the binder, is capable of emitting fluorescence when irradiated with ultraviolet rays, and is substantially transparent to visible light, the fluorescent substance being formed of a rare earth complex containing, as a ligand, a compound represented by the following formula (1):

摘要翻译： 一种荧光图像印刷品，其特征在于，包括基板和形成在基板上的图像，其中，所述图像由含有粘合剂的荧光墨水和分散在所述粘合剂中的荧光物质形成，所述荧光物质能够在被照射时发出荧光 紫外线，对可见光基本透明，荧光物质由含有下式（1）表示的化合物作为配体的稀土配合物形成：

公开(公告)号：US20080001515A1

公开(公告)日：2008-01-03

申请号：US11678999

申请日：2007-02-26

申请人： Hiroki Iwanaga ,  Akio Amano ,  Fumihiko Aiga

发明人： Hiroki Iwanaga ,  Akio Amano ,  Fumihiko Aiga

IPC分类号： H01J1/62 ,  C07F5/00

CPC分类号： C07F9/65685 ,  C07F9/5304 ,  C07F9/5329 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/182

摘要： This invention provides a fluorescent complex possessing excellent durability and luminous intensity, and a lighting system utilizing the same. The fluorescent complex comprises a rare earth ion and a β-diketone ligand. In the fluorescent complex, the β-diketone ligand comprises a β-diketone skeleton, a fluoroalkyl group, and an electron donative linking group for linking the β-diketone skeleton to the fluoroalkyl group. The fluorescent complex can be utilized in a lighting system. The rare earth ion is preferably a lanthanoid ion, particularly preferably a europium or terbium ion. When the β-diketone ligand further comprises an aromatic group, the luminous intensity can be further improved.

摘要翻译： 本发明提供具有优异的耐久性和发光强度的荧光复合体，以及利用该荧光体的照明系统。 荧光复合物包括稀土离子和β-二酮配体。 在荧光复合物中，β-二酮配体包含β-二酮骨架，氟代烷基和用于将β-二酮骨架与氟代烷基连接的给电连接基团。 荧光复合物可用于照明系统。 稀土离子优选为镧系离子，特别优选为铕或铽离子。 当β-二酮配体还包含芳族基团时，可以进一步提高发光强度。

公开(公告)号：US20070228932A1

公开(公告)日：2007-10-04

申请号：US11685416

申请日：2007-03-13

申请人： Akio Amano ,  Hiroki Iwanaga

发明人： Akio Amano ,  Hiroki Iwanaga

IPC分类号： H05B33/14 ,  H05B33/18 ,  H05B33/10 ,  B05D5/06 ,  B05D5/12

CPC分类号： C09K11/883 ,  C09K11/06 ,  C09K11/7734 ,  C09K2211/182 ,  H01L33/504 ,  H01L2224/48091 ,  H01L2924/3025 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00

摘要： A light-emitting device assured of high reliability, high efficiency and high color rendering, is provided. The light-emitting device includes a frame, an LED chip provided on the frame, and a fluorescent layer containing an inorganic fluorescent material and an organic fluorescent material and being provided on the LED chip. In the fluorescent layer, the concentration of the inorganic fluorescent material is decreased toward the top from the bottom of the fluorescent layer, and the concentration of the organic fluorescent material is decreased toward the bottom from the top of the fluorescent layer.

摘要翻译： 提供确保高可靠性，高效率和高显色性的发光装置。 发光装置包括框架，设置在框架上的LED芯片和包含无机荧光材料和有机荧光材料并设置在LED芯片上的荧光层。 在荧光层中，无机荧光体的浓度从荧光层的底部向顶部减少，有机荧光体的浓度从荧光层的顶部向底部减少。

公开(公告)号：US07250117B2

公开(公告)日：2007-07-31

申请号：US10873282

申请日：2004-06-23

申请人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

发明人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

IPC分类号： C09K11/06 ,  H01L51/50

CPC分类号： C09K11/06 ,  C09K2211/182 ,  H01L51/0089 ,  H05B33/14 ,  Y10S428/917

摘要： A light emitting device includes a light emitting element and a luminescent medium. The luminescent medium contains a rare earth complex wherein a compound represented by the following formula (1) is employed as a ligand: wherein X and Y are the same or different and are individually O, S or Se; R1, R2, R3 and R4 are the same or different, excluding a situation where R1, R2, R3 and R4 are all the same as each other, and are individually an alkyl or alkoxy group of a linear or branched structure having not more than 20 carbon atoms, a phenyl group, a biphenyl group, a naphthyl group, a heterocyclic group or a substitution product of any of these groups; n is an integer ranging from 2 to 20; and Z and W are the same or different and are individually a hydrogen atom, a deuterium atom, a halogen atom or an alkyl group.

摘要翻译： 发光器件包括发光元件和发光介质。 发光介质含有稀土配合物，其中使用由下式（1）表示的化合物作为配体：其中X和Y相同或不同，分别为O，S或Se; R 1，R 2，R 3和R 4相同或不同，不包括其中R 1，R 2，R 3和R 4彼此相同的情况，并且分别为直链或支链结构的烷基或烷氧基， 20个碳原子，苯基，联苯基，萘基，杂环基或任何这些基团的取代产物; n为2〜20的整数; Z和W相同或不同，分别为氢原子，氘原子，卤素原子或烷基。

公开(公告)号：US20060214578A1

公开(公告)日：2006-09-28

申请号：US11348412

申请日：2006-02-07

申请人： Hiroki Iwanaga ,  Akio Amano ,  Kenji Shimomura ,  Kazuaki Otsuka

发明人： Hiroki Iwanaga ,  Akio Amano ,  Kenji Shimomura ,  Kazuaki Otsuka

IPC分类号： H05B33/00

CPC分类号： C09K11/7734 ,  C09K11/7718 ,  C09K11/7731 ,  C09K11/7774 ,  H01L25/0753 ,  H01L33/504 ,  H01L2224/48091 ,  H01L2924/00014

摘要： A lighting device including a supporting member, a light emitting element disposed on the supporting member, and emitting light from an upper and side surfaces thereof, a first fluorescent layer containing an organic phosphor and disposed on the supporting member, and a second fluorescent layer containing only an inorganic phosphor and disposed on the supporting member, wherein the second fluorescent layer is disposed to cover the upper and side surfaces of the light emitting element, and the first fluorescent layer is disposed on at least side surface of the light emitting element with the second fluorescent layer being interposed between the light emitting element and the first fluorescent layer.