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公开(公告)号：US06096488A
公开(公告)日：2000-08-01
申请号：US304837
申请日：1999-05-05
CPC分类号： G03C7/413 , G03C7/3022 , G03C2200/47
摘要： Processing a silver halide color photographic material comprising color developing, desilvering and water washing and/or stabilizing. In this process, a photographic material which has at least one emulsion layer containing a high silver chloride content, and at least one emulsion layer containing a monodisperse emulsion, is continuously processed with a color developing solution containing a water-soluble high polymer compound. The coated amount of silver in the photographic material is preferably 0.75 g/m.sup.2 or less. The color developing solution preferably has a chloride ion content of 0.035 mol/l or more. The water soluble high polymer compound can be a polyester, polyamide, polyurethane, polyether, polycarbonate or a natural high polymer compound, or their derivatives. It is obtained by polymerizing or copolymerizing a monomer containing a copolymerizable ethylene type unsaturated group. The high polymer compound is preferably added in the amount of 0.001-10 g per liter of the color developing solution. By using this process, fluctuations in photographic properties is remarkably reduced, uniformity in developed density is remarkably improved, and the prevention of deposits on the processing tank wall surface is improved.
摘要翻译： 加工卤化银彩色照相材料，包括彩色显影，脱色和水洗和/或稳定化。 在该方法中，使用含有高氯化银含量的至少一种乳剂层和至少一种含有单分散乳液的乳剂层，用含有水溶性高分子化合物的显色液连续地进行处理。 照相材料中的银的涂布量优选为0.75g / m 2以下。 显色溶液的氯离子含量优选为0.035mol / l以上。 水溶性高分子化合物可以是聚酯，聚酰胺，聚氨酯，聚醚，聚碳酸酯或天然高分子化合物或它们的衍生物。 通过聚合或共聚含有可共聚的乙烯型不饱和基团的单体获得。 高分子化合物的添加量优选为每升显色液0.001-10g。 通过使用该方法，显着降低了照相特性的波动，显着提高了显影浓度的均匀性，提高了防止处理罐壁面上的沉积。
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公开(公告)号：US06376162B1
公开(公告)日：2002-04-23
申请号：US08232339
申请日：1994-04-22
IPC分类号： G03C7413
CPC分类号： G03C7/413 , G03C7/3022 , G03C2200/47
摘要： In a processing method wherein, after a silver halide color photographic material is subjected to color development, the silver halide color photographic material is desilvered and then washed and/or stabilized, a photographic material that has at least one high-silver chloride emulsion layer, and in which at least one emulsion layer contains a monodisperse emulsion, is rapidly processed with a color developer having a water-soluble high polymer compound. The coating amount of silver of the said silver halide color photographic material is preferably 0.75 g/m2 or less, and the color developer contains chloride ions in an amount of 0.035 mol/liter or more. In continuous and rapid processing, fluctuations of photographic properties (particularly changes in sensitivity and gradation) are remarkably reduced, the ununiformity of developed density is remarkably improved, and the occurrence of a deposit on a processing tank wall surface is prevented.
摘要翻译： 在其中，在卤化银彩色照相材料进行显色后，将卤化银彩色照相材料脱溶剂洗涤和/或稳定的处理方法中，具有至少一种高氯化银乳剂层的照相材料， 并且其中至少一个乳剂层含有单分散乳液，用具有水溶性高分子化合物的显色剂快速加工。 所述卤化银彩色照相材料的银的涂布量优选为0.75g / m 2以下，彩色显影剂含有0.035mol / l以上的氯离子。 在连续和快速的处理中，照相特性（特别是灵敏度和灰度变化）的波动显着降低，显影浓度的不均匀性显着提高，并且防止了在处理罐壁表面上的沉积。
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公开(公告)号：US5573893A
公开(公告)日：1996-11-12
申请号：US295155
申请日：1994-08-24
摘要： There is disclosed a method for processing a silver halide color photographic material. The method comprises processing a silver halide color photographic material having a photographic layer, the degree of swelling of which is 1.2 to 3.0, by a color developer containing at least one compound represented by formula (I) in an amount of 0.01 to 10 g per liter of said color developer. ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 each represent a hydrogen atom, or an alkyl group, an alkoxy group, or an alkenyl group, which may be substituted, n is an integer of 1 to 3, and M represents a hydrogen atom or a counter cation.
摘要翻译： 公开了一种处理卤化银彩色照相材料的方法。 该方法包括通过含有至少一种式（I）表示的化合物的显色剂，其量为0.01至10g的含有照相层，其溶胀度为1.2至3.0的卤化银彩色照相材料，其量为0.01至10g 升所述彩色显影剂。 式（I）其中R 1，R 2，R 3和R 4各自表示氢原子，或可以被取代的烷基，烷氧基或烯基，n为1〜3的整数， M表示氢原子或抗衡阳离子。
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公开(公告)号：US5147766A
公开(公告)日：1992-09-15
申请号：US578370
申请日：1990-09-06
IPC分类号： G03C7/44
CPC分类号： G03C7/44
摘要： A method for continuously processing an image-wise exposed silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer containing 95 mol % or more of silver chloride is disclosed, which comprises the steps of developing the silver halide color photographic material in a color developer and supplying a replenisher to the color developer, the replenisher comprising used color developer and a regenerant wherein components accumulated to the color developer during the continuous processing are not removed from the replenisher. This method does not require a large scale apparatus and provides stable photographic properties without substantially producing waste water and without causing crystallization of chemicals in a replenisher even after repeated regeneration, particularly when varying the amount of light-sensitive material being processed per unit time.
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5.发明授权
公开(公告)号：US5153111A
公开(公告)日：1992-10-06
申请号：US645447
申请日：1991-01-24
申请人： Kazuaki Yoshida , Takatoshi Ishikawa , Tadashi Ogawa , Hiroshi Fujimoto , Junichi Yamanouchi , Tomokazu Yasuda
发明人： Kazuaki Yoshida , Takatoshi Ishikawa , Tadashi Ogawa , Hiroshi Fujimoto , Junichi Yamanouchi , Tomokazu Yasuda
摘要： A composition for color-development of a silver halide color photographic material and a method for processing such using the same wherein the composition comprises an aromatic primary amine color developing agent, a hydroxylamine compound represented by formula (I) or a hydrazine compound represented by formula (II) and at least one polymer selected from the group consisting of a vinyl alcohol homopolymer, a vinyl alcohol copolymer, a vinylpyrrolidone homopolymer, and a vinylpyrrolidone copolymer, being free from sulfite ion, providing a color photographic image high in maximum density and good in whiteness without causing problems by tarry substance in the color developer.
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公开(公告)号：US4956267A
公开(公告)日：1990-09-11
申请号：US200268
申请日：1988-05-31
申请人： Shinji Ueda , Tatsuo Heki , Noriyuki Inoue , Takatoshi Ishikawa , Nobutaka Ohki , Morio Yagihara , Kiyoshi Morimoto , Hiroshi Fujimoto , Kazuto Andoh
发明人： Shinji Ueda , Tatsuo Heki , Noriyuki Inoue , Takatoshi Ishikawa , Nobutaka Ohki , Morio Yagihara , Kiyoshi Morimoto , Hiroshi Fujimoto , Kazuto Andoh
CPC分类号： G03C7/413 , G03C1/48538
摘要： A method for forming a direct positive color image by image-wise exposing to light a light-sensitive material having at least one internal latent image type silver halide emulsion layer which is unfogged and color image-forming couplers on a support; either (1) subjecting the resulting material to fogging exposure to light and/or processing it with a nucleating agent before development, and then developing the resulting material with a surface developing solution containing an aromatic primary amine type color developing agent, or (2) developing the material after the image-wise exposure with a surface developing solution containing an aromatic primary amine type color developing agent under fogging exposure and/or in the presence of a nucleating agent; and bleach-fixing the resulting material, wherein the color developing solution contains at least one compound selected from the group consisting of compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X represents --CO--, --SO.sub.2 -- or ##STR2## and R.sup.1 and R.sup.2 represents various familiar group; ##STR3## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent various familiar groups; ##STR4## wherein R.sup.7 and R.sup.8 represent various familiar groups; ##STR5## wherein Y represents a trivalent atomic group necessary for completing a condensed ring, m represents an integer of 0 to 4, and n represents an integer of 1 to 5.Stability of the color developing solutions with time lapse is excellent, which makes stable continuous process of color photographic light-sensitive materials possible over a long period.
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7.发明授权
公开(公告)号：US4853318A
公开(公告)日：1989-08-01
申请号：US15647
申请日：1987-02-17
IPC分类号： G03C7/413
CPC分类号： G03C7/413
摘要： A process for processing color photographic papers using a color developer substantially free from benzyl alcohol and containing a compound represented by formula (I) ##STR1## wherein Z represents an atomic group forming an aromatic nucleus is disclosed. In the process, the formation of color stains is greatly reduced even in the case of shortening the processing times for the blix step and the wash and/or stabilization step after color development.
摘要翻译： 公开了一种使用基本上不含苄醇并含有式（I）表示的化合物的成像处理彩色相纸的方法，其中Z表示形成芳香核的原子团。 在该过程中，即使在缩短彩色显影之后的双色步骤和洗涤和/或稳定步骤的处理时间的情况下，颜色斑的形成也大大降低。
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公开(公告)号：US4842993A
公开(公告)日：1989-06-27
申请号：US164368
申请日：1988-03-04
CPC分类号： G03C7/413
摘要： A method for processing a silver halide color photographic material is described, which comprises treating said material after imagewise exposure with a color developer containing an aromatic primary amine developing agent and at least one compound represented by formula (I) ##STR1## in which X.sub.1 and X.sub.2 each represents a divalent organic group. In accordance with this method, the stability and color-forming capacity of the color developer are remarkably improved, the increment of fog during continuous processing of photographic material is greatly reduced, and the color developer need not substantially contain benzyl alcohol.
摘要翻译： 描述了一种用于处理卤化银彩色照相材料的方法，其包括用含有芳族伯胺显影剂和至少一种由式（I）表示的化合物（I）的显色剂在成像曝光后处理所述材料 其中X1和X2各自表示二价有机基团。 根据该方法，彩色显影剂的稳定性和着色能力显着提高，大大降低了连续处理照相材料期间雾的增加，显色剂基本上不含苄醇。
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9.发明授权
公开(公告)号：US4837132A
公开(公告)日：1989-06-06
申请号：US54176
申请日：1987-05-26
摘要： A method is described for processing a silver halide color photographic material after imagewise exposure, comprising color developing, desilvering, and at least one of washing and stabilizing a silver halide color photographic material, wherein a color developer which does not substantially contain benzyl alcohol but comprises at least one compound represented by formula (I) ##STR1## wherein M.sup.1, M.sup.2, M.sup.3 and M.sup.4 each represents a hydrogen atom, an alkali metal ion, an ammonium ion, or 1/n of an n-valent cation is used for the color development.
摘要翻译： 描述了一种用于在成像曝光之后处理卤化银彩色照相材料的方法，包括彩色显影，脱色，以及洗涤和稳定卤化银彩色照相材料中的至少一种，其中基本不含苯甲醇但包含 由式（I）表示的至少一种化合物其中M1，M2，M3和M4各自表示氢原子，碱金属离子，铵离子或n价阳离子的1 / n为 用于颜色开发。
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10.发明授权Method for processing a silver halide color photographic material using a color developer containing a chelating agent in the absence of benzyl alcohol 失效使用含有螯合剂的着色显影剂在不存在苄醇的情况下处理卤化银彩色照相材料的方法
公开(公告)号：US4835092A
公开(公告)日：1989-05-30
申请号：US15408
申请日：1987-02-17
CPC分类号： G03C7/413
摘要： A novel method for processing a silver halide color photographic material is provided, which comprises processing a silver halide color photographic material having at least one silver halide emulsion layer on a reflective support with a color-developing solution substantially free of benzyl alcohol and containing at least one compound represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, --CH.sub.2 COOH, or ##STR2## R.sub.2 represents a hydrogen atom or --COOH; n represents an integer of 0 or 1; and Z represents atoms necessary for the formation of an aromatic ring.
摘要翻译： 提供了一种用于处理卤化银彩色照相材料的新方法，其包括在反射性载体上处理具有至少一个卤化银乳剂层的卤化银彩色照相材料，其显色溶液基本上不含苄醇，并至少含有 一种由式（I）表示的化合物其中R 1表示氢原子，-CH 2 COOH或R 2表示氢原子或-COOH; n表示0或1的整数; Z表示形成芳环所需的原子。
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