公开(公告)号：US20050150833A1

公开(公告)日：2005-07-14

申请号：US11012334

申请日：2004-12-16

申请人： Hiroshi Funaki ,  Koichi Yanase ,  Hiroki Kamiya ,  Masao Uehara ,  Kenichiro Nagatomo ,  Yasushi Nishimura ,  Shiro Ohno ,  Satoru Hirano

发明人： Hiroshi Funaki ,  Koichi Yanase ,  Hiroki Kamiya ,  Masao Uehara ,  Kenichiro Nagatomo ,  Yasushi Nishimura ,  Shiro Ohno ,  Satoru Hirano

IPC分类号： B01D3/00 ,  B01D3/06 ,  C02F1/04 ,  C02F1/06 ,  C02F1/08 ,  C02F1/26 ,  C08F14/18 ,  C08F2/16

CPC分类号： C08F14/18 ,  B01D3/007 ,  B01D3/06 ,  C02F1/048 ,  C02F1/06 ,  C02F1/08 ,  C02F1/26 ,  C02F2101/14 ,  C02F2101/325 ,  C02F2103/18 ,  C02F2103/38 ,  C02F2301/063 ,  C02F2303/16 ,  C08F2/16 ,  C08F2/22

摘要： An aqueous solution containing a fluorine-containing emulsifier in a low concentration of at least 1 ppm by mass and at most 1% by mass (e.g., coagulation waste water after an emulsion polymerization of a fluoropolymer and/or an aqueous solution obtained by washing with an aqueous solution a waste gas from a drying process and/or a heat treating process of the fluoropolymer) is subjected to vacuum concentration under a pressure of at most 100 kPa and a temperature of the aqueous solution of at most 100° C. by means of a heating tube surface evaporation type concentrator equipped with a heat pump or the like, and the fluorine-containing emulsifier is recovered from a highly concentrated aqueous solution containing the fluorine-containing emulsifier in a higher concentration of at least 5% by mass. According to the present method, the fluorine-containing emulsifier can be recovered with a high yield from a low-concentration liquid such as coagulation waste water of a fluoropolymer.

摘要翻译： 含有低浓度至少为1质量ppm且至多1质量％的含氟乳化剂的水溶液（例如，通过用含氟聚合物和/或通过用 来自干燥方法的废气和/或含氟聚合物的热处理工艺的水溶液）在至多100kPa的压力和水溶液的温度至多为100℃的条件下进行真空浓缩 的具有热泵等的加热管表面蒸发型浓缩器，并且从含有至少5质量％浓度的含氟乳化剂的高浓度水溶液中回收含氟乳化剂。 根据本方法，可以从低浓度液体如含氟聚合物的凝结废水中以高产率回收含氟乳化剂。

公开(公告)号：US07351342B2

公开(公告)日：2008-04-01

申请号：US11012334

申请日：2004-12-16

申请人： Hiroshi Funaki ,  Koichi Yanase ,  Hiroki Kamiya ,  Masao Uehara ,  Kenichiro Nagatomo ,  Yasushi Nishimura ,  Shiro Ohno ,  Satoru Hirano

发明人： Hiroshi Funaki ,  Koichi Yanase ,  Hiroki Kamiya ,  Masao Uehara ,  Kenichiro Nagatomo ,  Yasushi Nishimura ,  Shiro Ohno ,  Satoru Hirano

IPC分类号： C02F1/58

CPC分类号： C08F14/18 ,  B01D3/007 ,  B01D3/06 ,  C02F1/048 ,  C02F1/06 ,  C02F1/08 ,  C02F1/26 ,  C02F2101/14 ,  C02F2101/325 ,  C02F2103/18 ,  C02F2103/38 ,  C02F2301/063 ,  C02F2303/16 ,  C08F2/16 ,  C08F2/22

摘要： An aqueous solution containing a fluorine-containing emulsifier in a low concentration of at least 1 ppm by mass and at most 1% by mass (e.g., coagulation waste water after an emulsion polymerization of a fluoropolymer and/or an aqueous solution obtained by washing with an aqueous solution a waste gas from a drying process and/or a heat treating process of the fluoropolymer) is subjected to vacuum concentration under a pressure of at most 100 kPa and a temperature of the aqueous solution of at most 100° C. by means of a heating tube surface evaporation type concentrator equipped with a heat pump or the like, and the fluorine-containing emulsifier is recovered from a highly concentrated aqueous solution containing the fluorine-containing emulsifier in a higher concentration of at least 5% by mass. According to the present method, the fluorine-containing emulsifier can be recovered with a high yield from a low-concentration liquid such as coagulation waste water of a fluoropolymer.

摘要翻译： 含有低浓度至少为1质量ppm且至多1质量％的含氟乳化剂的水溶液（例如，通过用含氟聚合物和/或通过用 来自干燥方法的废气和/或含氟聚合物的热处理工艺的水溶液）在至多100kPa的压力和水溶液的温度至多为100℃的条件下进行真空浓缩 的具有热泵等的加热管表面蒸发型浓缩器，并且从含有至少5质量％浓度的含氟乳化剂的高浓度水溶液中回收含氟乳化剂。 根据本方法，可以从低浓度液体如含氟聚合物的凝结废水中以高产率回收含氟乳化剂。

公开(公告)号：US07053237B2

公开(公告)日：2006-05-30

申请号：US10619784

申请日：2003-07-16

申请人： Takashi Okazoe ,  Kunio Watanabe ,  Shin Tatematsu ,  Hidenobu Murofushi ,  Masakuni Sato ,  Masahiro Ito ,  Koichi Yanase ,  Yasuhiro Suzuki

发明人： Takashi Okazoe ,  Kunio Watanabe ,  Shin Tatematsu ,  Hidenobu Murofushi ,  Masakuni Sato ,  Masahiro Ito ,  Koichi Yanase ,  Yasuhiro Suzuki

IPC分类号： C07C69/63 ,  C07C41/00

CPC分类号： C07C67/287 ,  C07C41/24 ,  C07C51/60 ,  C07C67/03 ,  C07C67/14 ,  C07C59/135 ,  C07C69/708 ,  C07C69/63 ,  C07C43/17

摘要： A process for producing a fluorinated ester through a small number of steps, is presented. The process for producing a fluorinated ester, comprises a transesterification step in which RAF—COOCF2—RAF and RA—CH2OH are subjected to a transesterification reaction to obtain RAF—COOCH2—RA, and a fluorination step in which the obtained compound is fluorinated to obtain a reaction product containing RAF—COOCF2—RAF. Here, in the formulae, RA is a monovalent organic group, and RAF is the same group as RA or a monovalent organic group obtained by fluorination of RA.

摘要翻译： 提出了通过少量步骤生产氟化酯的方法。 氟化酯的制备方法包括酯交换步骤，其中R AF -OCOCF 2 -R AF和R A A < / O 2 CH 2 OH进行酯交换反应，得到R AF-COOCH 2 -R A A / O >和氟化步骤，其中所得化合物被氟化以获得含有R AF -OCOCF 2 -R AF的反应产物。 这里，在式中，R A A为一价有机基团，R AF为与R A A或单价有机基团相同的基团 通过R A A的氟化获得。

公开(公告)号：US08530710B2

公开(公告)日：2013-09-10

申请号：US13167145

申请日：2011-06-23

申请人： Hirokazu Takagi ,  Hidekazu Okamoto ,  Satoshi Kawaguchi ,  Yu Takeuchi ,  Kunio Watanabe ,  Koichi Yanase ,  Shingo Nomura

发明人： Hirokazu Takagi ,  Hidekazu Okamoto ,  Satoshi Kawaguchi ,  Yu Takeuchi ,  Kunio Watanabe ,  Koichi Yanase ,  Shingo Nomura

IPC分类号： C07C19/08

CPC分类号： C07C17/23 ,  B01J21/18 ,  B01J23/44 ,  B01J35/002 ,  B01J35/1023 ,  C07C21/18

摘要： The object is to provide a process whereby it is possible to produce 2,3,3,3-tetrafluoropropene at a high conversion ratio constantly for a long period of time.A process for producing 2,3,3,3-tetrafluoropropene, which comprises reacting a raw material compound of at least one of 1,1-dichloro-2,3,3,3-tetrafluoropropene and 1-chloro-2,3,3,3-tetrafluoropropene, and hydrogen, in the presence of a noble metal catalyst supported on active carbon having an ash content of at most 3% as measured in accordance with ASTM D2866.

摘要翻译： 本发明的目的是提供一种能够长时间恒定地以高转化率制备2,3,3,3-四氟丙烯的方法。 一种制备2,3,3,3-四氟丙烯的方法，其包括使1,1-二氯-2,3,3,3-四氟丙烯和1-氯-2,3中的至少一种的原料化合物反应， 3,3-四氟丙烯和氢气，在负载在活性炭上的贵金属催化剂的存在下，其灰分含量至多为3％，根据ASTM D2866测量。

公开(公告)号：US07071272B2

公开(公告)日：2006-07-04

申请号：US10307388

申请日：2002-12-02

申请人： Takashi Okazoe ,  Kunio Watanabe ,  Shin Tatematsu ,  Masakuni Sato ,  Hidenobu Murofushi ,  Koichi Yanase ,  Yasuhiro Suzuki

发明人： Takashi Okazoe ,  Kunio Watanabe ,  Shin Tatematsu ,  Masakuni Sato ,  Hidenobu Murofushi ,  Koichi Yanase ,  Yasuhiro Suzuki

IPC分类号： C08F16/24

CPC分类号： C07C43/17 ,  C07C41/18 ,  C07C41/28 ,  C07C43/172 ,  C07C2601/14

摘要： The present invention provides a method for preparing a compound of CF3CF2CF2OCF═CF2 by pyrolyzing a compound expressed by CF3CF2CF2OCF(CF3)COOCF2CF(CF3)OCF2CF2CF3 in a gas phase at a temperature of from 200° C. to 500° C.

摘要翻译： 本发明提供了通过以下方法制备CF 3 CF 2 CF 2 OCF-CF 2的化合物的方法： 热解由CF 3 CF 2 CO 2 CF 2（CF 3）COOCF 2表示的化合物， / CF 2 CF 3 CF 3 CF 3 CF 3 CF 3 CF 3在气相中在温度为 从200℃至500℃

公开(公告)号：US5220084A

公开(公告)日：1993-06-15

申请号：US914590

申请日：1992-07-20

申请人： Keiichi Ohnishi ,  Hidekazu Okamoto ,  Toshihiro Tanuma ,  Koichi Yanase ,  Toru Kawasaki ,  Ryutaro Takei

发明人： Keiichi Ohnishi ,  Hidekazu Okamoto ,  Toshihiro Tanuma ,  Koichi Yanase ,  Toru Kawasaki ,  Ryutaro Takei

IPC分类号： C07C17/278

CPC分类号： C07C17/278

摘要： A method for producing a dichloropentafluoropropane, which comprises reacting dichlorofluoromethane (R21) with tetrafluoroethylene (4F) in the presence of a Lewis acid catalyst for addition reaction to obtain dichloropentafluoropropane, wherein a halide containing at least one element selected from the group consisting of Sb, Nb, Ta, B, Ga, In, Zr, Hf and Ti, or AlBr.sub.3, or AlI.sub.3, is used as the Lewis acid.

摘要翻译： 一种二氯五氟丙烷的制造方法，其特征在于，在路易斯酸催化剂存在下，使二氯氟甲烷（R21）与四氟乙烯（4F）反应进行加成反应，得到二氯五氟丙烷，其中，含有选自Sb， 使用Nb，Ta，B，Ga，In，Zr，Hf和Ti，或AlBr 3或AlI 3作为路易斯酸。

公开(公告)号：US08530711B2

公开(公告)日：2013-09-10

申请号：US13167254

申请日：2011-06-23

申请人： Satoshi Kawaguchi ,  Hidekazu Okamoto ,  Yu Takeuchi ,  Hirokazu Takagi ,  Kunio Watanabe ,  Koichi Yanase

发明人： Satoshi Kawaguchi ,  Hidekazu Okamoto ,  Yu Takeuchi ,  Hirokazu Takagi ,  Kunio Watanabe ,  Koichi Yanase

IPC分类号： C07C19/08

CPC分类号： C07C17/23 ,  C07C21/18

摘要： The object is to provide a process for producing highly pure 2,3,3,3-tetrafluoropropene, whereby formation of 3,3,3-trifluoropropene is suppressed.A process for producing 2,3,3,3-tetrafluoropropene, which comprises reacting a raw material compound composed of 1,1-dichloro-2,3,3,3-tetrafluoropropene and/or 1-chloro-2,3,3,3-tetrafluoropropene, and hydrogen in a gas phase in a reactor having a catalyst layer packed with a catalyst-supporting carrier, while maintaining the maximum temperature of the catalyst layer to be at most 130° C., to obtain formed gas containing 2,3,3,3-tetrafluoropropene, and then, contacting the formed gas discharged from the reactor, with alkali at a temperature of at most 100° C.

摘要翻译： 本发明的目的是提供一种制备高纯度2,3,3,3-四氟丙烯的方法，从而抑制3,3,3-三氟丙烯的形成。 一种制备2,3,3,3-四氟丙烯的方法，包括使由1,1-二氯-2,3,3,3-四氟丙烯和/或1-氯-2,3,3,3-四氟丙烯组成的原料化合物 ，3-四氟丙烯和氢气，在具有催化剂载体的催化剂层的反应器中，同时保持催化剂层的最高温度为至多130℃，得到含有2个 ，3,3,3-四氟丙烯，然后使从反应器排出的形成的气体与最多100℃的碱接触。

公开(公告)号：US07371899B2

公开(公告)日：2008-05-13

申请号：US11763483

申请日：2007-06-15

申请人： Yuuki Mitsui ,  Koichi Yanase

发明人： Yuuki Mitsui ,  Koichi Yanase

IPC分类号： C07C51/58 ,  C07C53/38

CPC分类号： B01J4/004 ,  B01J10/002 ,  B01J2219/00094 ,  B01J2219/0013 ,  C01B32/80

摘要： To provide a method for producing carbonyl fluoride by employing carbon monoxide and fluorine as starting materials, without such a problem as vigorous heat generation or a decrease in the reaction yield due to a side reaction.

摘要翻译： 提供一氧化碳和氟作为起始原料生产碳酰氟的方法，而不会产生剧烈的发热或由于副反应引起的反应产率的降低。

公开(公告)号：US20070249863A1

公开(公告)日：2007-10-25

申请号：US11763483

申请日：2007-06-15

申请人： Yuuki MITSUI ,  Koichi Yanase

发明人： Yuuki MITSUI ,  Koichi Yanase

IPC分类号： C07C51/58 ,  C07C53/38

CPC分类号： B01J4/004 ,  B01J10/002 ,  B01J2219/00094 ,  B01J2219/0013 ,  C01B32/80

摘要： To provide a method for producing carbonyl fluoride by employing carbon monoxide and fluorine as starting materials, without such a problem as vigorous heat generation or a decrease in the reaction yield due to a side reaction. A method for producing carbonyl fluoride, which comprises introducing carbon monoxide gas and fluorine gas into a liquid, and letting carbon monoxide and fluorine react with each other to obtain carbonyl fluoride.

摘要翻译： 提供一氧化碳和氟作为起始原料生产碳酰氟的方法，而不会产生剧烈的发热或由于副反应引起的反应产率的降低。 一种生产碳酰氟的方法，其包括将一氧化碳气体和氟气引入液体中，并使一氧化碳和氟彼此反应以获得碳酰氟。

公开(公告)号：US5434321A

公开(公告)日：1995-07-18

申请号：US229126

申请日：1994-04-18

申请人： Keiichi Ohnishi ,  Hidekazu Okamoto ,  Toshihiro Tanuma ,  Koichi Yanase ,  Toru Kawasaki ,  Ryutaro Takei

发明人： Keiichi Ohnishi ,  Hidekazu Okamoto ,  Toshihiro Tanuma ,  Koichi Yanase ,  Toru Kawasaki ,  Ryutaro Takei

IPC分类号： C07C17/278 ,  C07C17/266

CPC分类号： C07C17/278

摘要： A method for producing a dichloropentafluoropropane, which comprises reacting dichlorofluoromethane (R21) with tetrafluoroethylene (4F) in the presence of a Lewis acid catalyst for addition reaction to obtain dichloropentafluoropropane, wherein a halide containing at least one element selected from the group consisting of Sb, Nb, Ta, B, Ga, In, Zr, Hf and Ti, or AlBr.sub.3, or AlI.sub.3, is used as the Lewis acid.

摘要翻译： 一种二氯五氟丙烷的制造方法，其特征在于，在路易斯酸催化剂存在下，使二氯氟甲烷（R21）与四氟乙烯（4F）反应进行加成反应，得到二氯五氟丙烷，其中，含有选自Sb， 使用Nb，Ta，B，Ga，In，Zr，Hf和Ti，或AlBr 3或AlI 3作为路易斯酸。