摘要:
A multi-stage process and system for formation of a polyarylene sulfide is described. The multi-stage process can include at least three separate formation stages that can take place in three different reactors. The first stage of the formation process can include reaction of an alkali metal sulfide with an organic amide solvent to form a complex including a hydrolysis product of the solvent and an alkali metal hydrogen sulfide. The second stage of the formation process can include reaction of the complex formed in the first stage with a dihaloaromatic monomer to form a prepolymer, and the third stage can include further polymerization of the prepolymer with additional monomers to form the final product.
摘要:
A continuous flow, RD reactor system, that comprises, in combination a reaction column, first means feeding vegetable oil, liquid methanol and catalyst to the upper interior of the column, a condenser reclining methanol vapor for the upper interior of the column, and for producing condensed methanol recycled to the column upper interior, and for delivering a stream of refluxed methanol liquid to the upper interior of the column, and several means for receiving product biodiesel and liquid methanol for the lower interior of the column, and for separating Biodiesel in a primary product stream and returning methanol vapor to the column.
摘要:
The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.
摘要:
The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.
摘要:
Improved process for producing aromatic carboxylic acids by catalytic liquid phase oxidation of a corresponding precursor in a suitable solvent comprising feeding the reactants to a first oxidation reaction zone at high pressure and high solvent ratio, wherein uptake of oxygen is less than that required for full conversion of the precursor to its corresponding carboxylic acid, and then feeding the resulting reaction medium to a second oxidation reaction zone.
摘要:
The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions. The pipe reactor processes and apparatus of the present invention are built and operated at a much lower cost than conventional polyester processes.
摘要:
The present invention relates to a nozzle for the injection of a liquid under pressure (3), comprising a vertical feed pipe (1) surmounted by a hollow head (3), the liquid under pressure being conducted between the outer wall (4) of the vertical feed pipe (1) and an inner tube (5), the upper part of the nozzle comprising at least one lateral orifice (6) for expelling the liquid under pressure (3). This nozzle is characterized in that the upper end of the inner tube (5) of the vertical feed pipe (1) emerges at a height above the lateral orifice(s) (6), thereby making it possible, when stopping the injection of the liquid under pressure (3), to introduce a gas under pressure (8) via the inner tube (5) of the vertical feed pipe (1). which generates an overpressure in the upper part of the nozzle in order, on the one hand, to lower the level of the liquid (9) under pressure (3) below the lateral orifice(s) (6) and, on the other hand, to prevent any backflow of solids, liquids and/or gases, from the medium into which the liquid under pressure (3) is injected. towards the inside of the nozzle.
摘要:
The present invention provides a process for recovering a dihydroxy compound from a fluid stream that results from the preparation of a polyester by use of an adsorption system to selectively recover the dihydroxy compound.
摘要:
The present invention provides a method for substantially continuously polymerizing olefins comprising: introducing into a first reaction zone a fresh olefin polymerization catalyst; contacting said fresh olefin polymerization catalyst in said first reaction zone with a first vent mixture at a first feed rate and under conditions sufficient to form and avoid melting a polyolefin, wherein first vent mixture comprises unreacted olefins and a diluent vented from a second reaction zone; withdrawing a vent product of unreacted olefins and diluent from said first reaction zone; withdrawing from said first reaction zone a first product mixture comprising said catalyst and said polyolefin; passing said first product mixture to said second reaction zone; contacting said first product mixture in said second reaction zone with a second vent mixture at a second feed rate and under conditions sufficient to form and avoid melting said polyolefin, wherein said second vent mixture comprises a material selected from the group consisting of a fresh feed and a mixture comprising unreacted olefins and diluent from a third reaction zone; and, withdrawing from said second reaction zone a second product mixture comprising said catalyst and said polyolefin.
摘要:
A method and system for increasing conversion efficiency of aromatic alkyl reactant to aromatic carboxylic acid product and for improving the quality of the product, are disclosed. The method and system provide for the continuous production of an aromatic carboxylic acid by the liquid phase, exothermic oxidation of an aromatic alkyl in a vaporizable solvent in an oxidation reactor. The reactor makes use of a vented, overhead condenser system and a separator system for condensation of vaporized reactor material, separation of the condensed solvent therefrom, and reflux of separated solvent back into the reactor. The improvement comprises combining the reactor liquid feedstream with the refluxed solvent upstream from the oxidation reactor.